Heat-shrinkable polyester films

• US 6,761,966 B2
• Filed: 06/04/2002
• Issued: 07/13/2004
• Est. Priority Date: 06/05/2001
• Status: Expired due to Term

• Current Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Nagano, Hiroshi, Ito, Hideki, Tabota, Norimi
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US10/161,829
• Publication Number:
  US 20030050430A1
• Time in Patent Office: 770 Days
• Field of Search: 525/437, 525/439, 525/445, 428/221, 428/357
• US Class Current: 428/221
• CPC Class Codes: B29D 7/01 Films or sheets
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: Y10T 428/249921 Web or sheet containing structurally defined element or component
• CPC Class Codes: Y10T 428/29 Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Abstract

Heat-shrinkable polyester films, each having a heat shrinkability of 30% or higher after treatment in hot water at 85° C. for 10 seconds in the main shrinkage direction of the film, and 10% or lower after treatment in hot water at 85° C. for 10 seconds in a direction perpendicular to the main shrinkage direction of the film, the resistance to tear propagation in the direction perpendicular to the main shrinkage direction after the film has been shrunk at 10% in the main shrinkage direction of the film being 1500 mN or smaller, exhibit excellent shrinkage finish with only rare occurrence of wrinkles, shrinkage spots and strains by shrinkage and have excellent cut properties along perforations; therefore, these films are suitable for full labels on bottles, particularly for full labels on PET bottles.

Claims

1. A heat-shrinkable polyester film having a heat shrinkability of 30% or higher after treatment in hot water at 85°

C. for 10 seconds in the main shrinkage direction of the film, and 10% or lower after treatment in hot water at 85°

C. for 10 seconds in a direction perpendicular to the main shrinkage direction of the film, the resistance to tear propagation in the direction perpendicular to the main shrinkage direction after the film has been shrunk at 10% in the main shrinkage direction of the film being 1500 mN or smaller.

2. A heat-shrinkable polyester film according to claim 1, wherein the film is made of a polyester comprising a thermoplastic resin incompatible with the polyester resin.

3. The heat-shrinkable polyester film of claim 2 wherein the thermoplastic resin incompatible with the polyester resin has a melt flow rate less than about 20 g/10 mm measured at 260°

C. with a 5 kg load.

4. The heat-shrinkable polyester film of claim 2 wherein the amount of comprises at thermoplastic resin incompatible with the polyester resin is at least about 15 wt-%.

5. The heat shrinkable film of claim 2 wherein the thermoplastic resin incompatible with the polyester resin is selected from the group consisting of α

-olefin resins, polystyrene resins, polymethylpentene resins, ionomer resins, scrylic resins, polycarbonate resins, and polysulfone resins.

6. The heat shrinkable film of claim 5 wherein the α

-olefin resin is selected from polypropylene and polyethylene.