Bi-modal ionomers

• US 6,762,246 B2
• Filed: 02/28/2003
• Issued: 07/13/2004
• Est. Priority Date: 08/11/2000
• Status: Expired due to Fees

• Current Assignee: Performance Materials NA, Inc. (Dow, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Chen, John C.
• Primary Examiner(s): Nutter, Nathan M.
• Application Number:
  US10/376,969
• Publication Number:
  US 20030181595A1
• Time in Patent Office: 501 Days
• Field of Search: 525/194
• US Class Current: 525/194
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/0034 Deflection or compression
• CPC Class Codes: A63B 37/0039 characterised by the material
• CPC Class Codes: A63B 37/0046 Deflection or compression
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0065 Deflection or compression
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2205/025 containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
• CPC Class Codes: C08L 2205/035 containing four or more polymers in a blend
• CPC Class Codes: C08L 23/025 Copolymer of an unspecified olefin with a monomer other than an olefin
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0869 Acids or derivatives thereof
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 67/025 containing polyether sequences
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

The present invention relates to compositions and preparative process of partially or fully neutralized mixtures of carboxylate functionalized ethylene high copolymers or terpolymers (Mw between 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (Mw between 2,000 and 30,000) and organic acid salts and injection or compression molded applications such as golf ball components thereof.

Claims

1. A bi-modal composition comprising a thermoplastic composition that is melt processible consisting essentially of (a) E/X/Y copolymers where E is ethylene, X is derived from a C3 to C8 α

,β

ethylenically unsaturated carboxylic acid, and Y is a softening comonomer selected from the group consisting of alkyl acrylates and alkyl methacrylates, wherein the alkyl groups have from 1-8 carbon atoms, or ionomers of the E/X/V copolymers wherein X is about 2-30 wt. % of the E/X/Y copolymer, and Y is 0 to about 35 wt. % of the E/X/Y copolymer, and (b) 5-60 wt. % based on (a)+(b) of one or more E/(M)AA copolymers having 3-25 wt. % (M)AA or salts thereof, wherein the E/X/Y copolymers have an Mw in the range of 80,000 to 500,000, and the E/(M)AA copolymers have an MW between 2,000 and 30,000 and (c) 5-50 wt. % based on (a)+(b) of one or more aliphatic, mono-functional organic acids having fewer than 30 carbon atoms or salt thereof, wherein greater than 80% of all the acid of (a) and of (b) and of (c) is neutralized.

2. The composition of claim 1 wherein a sufficient amount of filler is added to adjust the density to a value ranging between that of said composition without filler and 1.8 gm/cc.

3. A composition comprising a thermoplastic composition that is melt processible consisting essentially of the composition of claim 1, wherein the E/X/Y copolymers have the Mw in the range of 80,000 to 300,000, and wherein greater than 90% of all the acid of (a) and of (b) and of (c) is neutralized.

4. A composition comprising a thermoplastic composition that is melt processible consisting essentially of the composition of claim 3, wherein the E/(M)AA copolymer content ranges from 5 to 30 wt. % based on (a)+(b) and wherein X is about 2 to 20 wt. % of the E/X/Y copolymer and Y is about 15 to 35 wt. % of the E/X/Y copolymer and wherein greater than 90% of all the acid of (a) and of (b) and of (c) is neutralized.

5. The composition of claim 4 wherein about 100% of all the acid of (a) and of (b) is neutralized.

6. The composition of claim 5 wherein the organic acid is one or more C10 to C22 organic acids.

7. The composition of claim 1 further comprising

1-30 wt % based on total weight of composition of thermoplastic elastomeric resin selected from copolyetheramides, copolyetheresters, elastomeric polymerolefins, block polystyrene polydiene copolymers, and thermoplastic urethanes.

8. The composition of claim 7 wherein a sufficient amount of filler is added to adjust the density to a value ranging between that of said composition without filler and 1.8 gm/cc.

9. A process to make the melt processible bi-modal ionomer of claim 1 comprising the steps of (a) melt blending concurrently or sequentially an the E/X/Y copolymer or melt processible ionomer thereof with an the E/(M)AA copolymer or salt thereof, and the organic acid or a salt thereof, and (b) concurrently or subsequently adding sufficient cation source to neutralize greater than 80% of all the acid moieties of E/X/Y copolymer or ionomer thereof, the E/(M)AA copolymer or salt thereof, and the organic acid or salt thereof.

10. The process of claim 9 wherein sufficient cation source is added to neutralize about 95% or higher of the acid moieties.

11. The process of claim 9 wherein sufficient cation source is added to neutralize at least about 100% of the acid moieties.