Application of multi-layer antistatic/antireflective coating to video display screen by sputtering

• US 6,764,580 B2
• Filed: 11/15/2001
• Issued: 07/20/2004
• Est. Priority Date: 11/15/2001
• Status: Expired due to Fees

• Current Assignee: Chunghwa Picture Tubes Limited
• Original Assignee: Chunghwa Picture Tubes Limited
• Inventors: Teng, Yueh-Ming
• Primary Examiner(s): VERSTEEG, STEVEN H
• Application Number:
  US10/002,936
• Publication Number:
  US 20030090195A1
• Time in Patent Office: 978 Days
• Field of Search: 204/192.12, 204/192.22, 204/192.23, 204/298.06, 204/298.07, 445/36
• US Class Current: 204/192.23
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3452 comprising a fluoride
• CPC Class Codes: C23C 14/3464 using more than one target C23C14/56 takes precedence
• CPC Class Codes: H01J 2211/44 Optical arrangements or shielding arrangements, e.g. filters or lenses
• CPC Class Codes: H01J 29/868 Screens covering the input or output face of the vessel, e.g. transparent anti-static coatings, X-ray absorbing layers
• CPC Class Codes: H01J 29/896 Anti-reflection means, e.g. eliminating glare due to ambient light
• CPC Class Codes: H01J 9/20 Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel

Abstract

A multi-layer antistatic/antireflective coating having high electrical conductivity (10³ ohms) and low reflectivity (0.7%) is applied to the outer surface of a video display screen by sputtering. The multi-layer coating includes an inner antistatic layer deposited directly on the video display screen and comprised of ITO, TiO₂, etc., having a light refractive index in the range of 1.8-2.2 and a thickness in the range of 18-35 nm. The outer antireflective layer is comprised of SiO₂, MgO, etc., having a light refractive index in the range of 1.3-1.47 and a thickness in the range of 110-140 nm. The multi-layer coating is applied using a sputtering apparatus having a dual vacuum chamber, a diffusion pump connected to one of the chambers, and plural vacuum pumps connected to the diffusion pump and to the dual vacuum chamber with various gauges and valves for monitoring and controlling the sputtering operation.

Claims

1. A process for forming an antistatic/antireflective coating on an outer surface of a video display screen comprising the steps of:

sputter-depositing on the outer surface of the video display screen an inner metallic antistatic layer having a precisely controlled thickness within a range of 18-35 nm, wherein a light refractive index of said inner antistatic layer is also precisely controlled within a range of 1.8-2.2; and

sputter-depositing on said inner antistatic layer an outer antireflective layer having a precisely controlled thickness within a range of 110-440 nm, wherein a light refractive index of said outer antireflective layer is also precisely controlled within a range of 1.3-1.47.

2. The process of claim 1 wherein said inner antistatic layer is comprised of a doped metallic oxide.

3. The process of claim 2 wherein said doped metallic oxide is ITO, SnO₂:

F, ZnO;

In, ZnO;

F, ZnO;

Al, ZuO;

Sn, or mixtures thereof.

4. The process of claim 2 wherein said antistatic/antireflective coating has an electrical conductivity on the order of 10³ ohms.

5. The process of claim 1 wherein said outer antireflective layer is comprised of Al₂O₃, TiO₂, ZnO, ZrO₂, Cr₂O₃, MgO, SiO₂, or mixtures thereof.

6. The process of claim 5 wherein said antistatic/antireflective coating has a reflectivity on the order of 0.7%.

7. A method for sputter depositing an inner antistatic layer and an outer antireflective layer on the surface of a video display screen, said method comprising the steps of:

providing a first chamber including first and second cathodes respectively comprised of an antistatic material and an antireflective material, wherein said first chamber includes a sealed aperture;

providing a second chamber coupled to said first chamber by means of a valve;

evacuating said second chamber;

connecting a diffusion pump to said second chamber when the pressure in said second chamber and in said diffusion pump reaches a working pressure;

loading a video display screen in the scaled aperture of said first chamber and evacuating said first chamber to the working pressure;

opening the valve to equalize the pressure between said first and second chambers;

directing energetic positive ions on said first cathode for sputter depositing the antistatic material on the video display screen;

directing energetic positive ions on the second cathode for sputter depositing the antireflective material on the antistatic material;

releasing the working pressure from said first and second chambers; and

removing the video display Screen from said first chamber.

8. The method of claim 7 further comprising the step of providing an antistatic material having a doped metallic oxide composition.

9. The method of claim 8 wherein said doped metallic oxide composition is ITO, SnO₂:

F, ZnO;

In, ZnO;

F, ZnO;

Al, ZnO;

Sn, or mixtures thereof.

10. The method of claim 7 further composing the step of providing an antireflective material comprised of Al₂O₃, TiO₂, ZnO, ZrO₂, Cr₂O₃, MgO, SiO₃, or mixtures thereof.

11. The method of claim 7 wherein said antistatic layer has a thickness within a range of 18-35 nm and a light refractive index within a range of 1.8-2.2.

12. The method of claim 7 wherein said antireflective layer has a thickness within a range of 110-140 and a refractive index within a range of 1.3-1.47.

13. The method of claim 12 wherein the combination of said inner antistatic layer and said outer antireflective layer has an electrical conductivity on the order of 10³ ohms and a reflectivity on the order of 0.7%.

14. The method of claim 7 further comprising the step of isolating said first and second chambers from said diffusion pump while said diffusion pump continues in operation for performing maintenance on said first and second chambers.