Retroreflective articles having microcubes, and tools and methods for forming microcubes

• US 6,767,102 B1
• Filed: 12/02/1999
• Issued: 07/27/2004
• Est. Priority Date: 05/30/1996
• Status: Expired

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Couzin, Dennis I., Coman, Liviu A., Heenan, Sidney A., Montalbano, Anthony J.
• Primary Examiner(s): Phan, James
• Application Number:
  US09/453,327
• Time in Patent Office: 1,699 Days
• Field of Search: 359/529-530, 359/531-533, 428/141, 428/156, 428/172
• US Class Current: 359/530
• CPC Class Codes: B29C 2059/023 Microembossing
• CPC Class Codes: B29C 33/301 Modular mould systems [MMS], i.e. moulds built up by stacking mould elements, e.g. plates, blocks, rods B29C33/0088 takes precedence
• CPC Class Codes: B29C 33/3842 Manufacturing moulds, e.g. shaping the mould surface by machining
• CPC Class Codes: B29C 33/42 characterised by the shape of the moulding surface, e.g. ribs or grooves
• CPC Class Codes: B29C 39/00 Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor B29C41/00 takes precedence
• CPC Class Codes: B29C 43/00 Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor by liberation of internal stresses B29C61/006
• CPC Class Codes: B29D 11/00605 Production of reflex reflectors
• CPC Class Codes: B29L 2011/0091 Reflex reflectors
• CPC Class Codes: G02B 5/124 plural reflecting elements forming part of a unitary plate or sheet
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/249921 Web or sheet containing structurally defined element or component

Abstract

A method for tooling a pattern of retroreflective microcubes, which pattern can be subdivided into smaller increments within which there are straight line tooling paths, none of which pass through an otherwise solid part of the incremental pattern. The tooling paths within the various increments need not be parallel to a common plane.

Various adaptions of the method enable the tooling of a number of specific microcube shapes and for modifying such optical properties of the microcubes as entrance angularity, incidence angularity, orientation angularity, observation angularity, percent active aperture and retroreflectance. Specific techniques govern the pre-selection of cube parameters such as cube axis cant, cube apex decentration, and cube boundary proportions, which parameters can be adjusted independently of each other. Designs tooled by the method can have 100% active aperture at near zero degrees entrance angle.

The method involves providing a plurality of plates of micro thickness, each plate having at least one end comprised of a material that can be tooled with polished surfaces by means of an appropriate tool, tooling on said end of each plate an increment of the pattern, and assembling the plates together in various ways to form a master.

Retroreflective articles made by means of this technique are expected to provide superior performance when used in pavement markers, highway signs and other applications.

Claims

1. An article comprising an array of microcubes, at least one of said microcubes being non-hexagonal, such that for every plane in space there are two adjacent microcubes for which at the place of the adjacency none of the face edges is parallel to that plane, said at least one microcube having a projected area of less than 1 mm², said at least one microcube being canted edge-more-parallel.

2. The article of claim 1 wherein said array is retroreflective.

3. The article of claim 2 wherein said article comprises retroreflecfive sheeting.

4. The article of claim 3 wherein at least one microcube of said array has a projected area of about 1 mm² or less.

5. The article of claim 4 wherein at least one microcube of said array has a projected area of about 0.35 mm² or less.

6. The article of claim 5 wherein at least one microcube of said array has a projected area of about 0.04-0.12 mm².

7. The article of claim 3 wherein said sheeting comprises a polymer resin.

8. The article of claim 7 wherein said polymer resin is selected from the group consisting of acrylic, polycarbonate, vinyl, polyester, and polyethylene.

9. The article of claim 7 wherein said microcubes are formed by embossing.

10. The article of claim 7 wherein said microcubes are formed by casing.

11. The article of claim 3 wherein said sheeting is transilluminated.

12. The article of claim 1 in which at least one microcbue of said array is canted.

13. The article of claim 12 in which at least one microcube in said array is edge-more-parallel.

14. The article of claim 13 wherein retroreflectance in the plane of symmetry of the microcubes of said array is substantially constant and is greater than about 50% for all entrance angles less than about 30°

.

15. The article of claim 12 in which not all the cube axes in said array are parallel to each other.

16. The article of claim 15 in which some adjacent cubes are alternately face-more-parallel and edge-more-parallel.

17. The article of claim 12 in which said array is a retroreflective part of a pavement marker.

18. The article of claim 1 wherein said article is a master for use in the production of a tool for making a retroreflective article.

19. The article of claim 1 wherein said article is an electroform for use in the production of a tool for making a retroreflective article.

20. The article of claim 1 wherein said microcubes of said array are of unequal sizes.

21. An article comprising an array of microcubes, at least one of said microcubes being non-hexagonal such that for every plane in space there are two adjacent microcubes for which at the place of the adjacency none of the face edges is parallel to that plane, in which array at least one said microcubes is canted, said array being formed of a material having a refractive index n, and the cant of at least one microcube in said array does not exceed about tan⁻

1{square root over (2)} −

sin<sup>−

1</sup>(1/n).

22. An article comprising an array of rectangular microcubes, at least some of which have no dihedral face-edges collinear with any dihedral faces-edges of any adjacent microcrubes, at least one of said rectangular microcubes having a projected area of less than 1 mm², said at least one microcube being canted edge-more-parallel.

23. A pavement marker for establishing on a finished roadway surface a marking visible from an oncoming vehicle, said pavement marker comprising a base member adapted to be mounted on the finished roadway surface, and a retroreflective signal means, said retroreflective signal means comprising an array of microcubes of claim 22.

24. The pavement marker of claim 23 wherein the retroreflective signal means front surface is sloped about 30°

-40°

with respect to the road surface and comprises an array of canted rectangular microcubes, the cube axis cant being in the range of about −

5°

to −

13°

.

25. The pavement marker of claim 24 having horizontal entrance angularity up to at least about 30°

.

26. An article comprising an array of microcubes in which every region of three by three microcubes is nonrulable and in which at least one microcube in a said region of three by three microcubes is rectangular, said at least microcube having a projected area of less than 1 mm², said at least one microcube being canted edge-more-parallel.