Electrically conductive non-aqueous wellbore fluids

• US 6,770,603 B1
• Filed: 02/05/2002
• Issued: 08/03/2004
• Est. Priority Date: 01/16/1999
• Status: Expired due to Term

• Current Assignee: M-I LLC (SLB)
• Original Assignee: M-I LLC (SLB)
• Inventors: Tehrani, Mostafa, Craddock, Paul, Lawson, Anthony, Sawdon, Christopher
• Primary Examiner(s): Tucker, Philip C.
• Application Number:
  US09/889,364
• Time in Patent Office: 910 Days
• Field of Search: 507/140, 507/128, 507/134, 507/131, 507/136, 507/138, 507/235-238, 507/244, 507/261, 507/265, 507/269, 507/259, 507/925, 166/254.2
• US Class Current: 507/140
• CPC Class Codes: C09K 8/36 Water-in-oil emulsions
• CPC Class Codes: Y10S 507/925 Completion or workover fluid

Abstract

A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity increased by a factor in order of 10⁴ to 10⁷ compared to conventional invert emulsion comprises from about 0.2% to about 10% by volume of carbon black particles and one or more emulsifying surfactant(s) selected from the class including nonionic emulsifiers of Hydrophilic-Lipophilic Balance (HLB) less than about 12, and anionic surfactants wherein the counter-ion (cation) is any of alkali metal, ammonium, or hydrogen ions. This wellbore fluid can be used for drilling or completing a well and can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.

Claims

1. An electrically conductive invert emulsion wellbore fluid comprising:

i) from about 0.2% to about 10% by volume of carbon black particles, and

ii) one or more emulsifying surfactant(s) selected from the group consisting of;

nonionic emulsifiers of Hydrophilic-Lipophilic Balance (HLB) less than about 12, and anionic surfactants wherein the counter-ion is any of alkali metal, ammonium, or hydrogen ions, and

wherein the wellbore fluid is substantially free of polyvalent metal cations and wherein the wellbore fluid has conductivity of at least 10⁴ μ

S/m.

2. A wellbore fluid according to claim 1 wherein the carbon black exhibits a specific surface area of at least 500 m²/g, and preferably of at least 1500 m²/g.

3. A wellbore fluid according to claims 1 or 2 wherein the nonionic emulsifier is selected from the group consisting of:

diethanolamides based on fatty acids of more than 12 carbon atoms, alkoxylated fatty alcohols, alkoxylated alkylphenols, and ethylene oxide propylene oxide block polymers.

4. A wellbore fluid according to claim 1 or 2 wherein the anionic surfactant is selected from the group consisting of:

alkane sulphonates, alpha olefin sulphonates, alkyl arene sulphonates, polyolefin sulphonates and acyl taurates, all characterised by the carbon number of the hydrophobic moiety being at least about 12, and by the counter-ion (cation) being any of alkali metal, ammonium, or hydrogen ions.

5. A wellbore fluid according to claim 1 or 2 wherein the anionic surfactant is selected from the group consisting of:

fatty acids of 12 or more carbon atoms, phosphate esters of ethoxylated alcohols of 12 or more carbon atoms, phosphate esters of ethoxylated alkyl phenols of 14 or more carbon atoms, and alkyl aminomethylene phosphonates wherein the alkylamine precursor contains 12 or more carbon atoms, all characterised by the counter-ion (cation) being any of alkali metal ion, ammonium, or hydrogen ions.

6. A wellbore fluid according to claims 1 or 2 in which the total dose of emulsifier(s) is in the range 0.5% to 10% by weight.

7. A wellbore fluid according to claims 1 or 2 further comprising a material capable of precipitating or complexing polyvalent metal cations.

8. A wellbore fluid according to claim 7 wherein the emulsified brine phase contains dissolved anions which will form insoluble precipitates with the ions of calcium, magnesium or iron cations.

9. A wellbore fluid according to claim 8 wherein the complexing agent is selected from the group consisting of:

the alkali metal or ammonium salts, or the free acids, of citric acid, gluconic acid, glucoheptanoic acid, ascorbic acid, erythorbic acid, nitrolotriacetic acid, ethylene diamine tetraacetic acid, diethylenetriamine pentaacetic acid, hydroxyethylidene diphosphonic acid, nitrolotrismethylenephosphonic acid, aminomethylene phosphonates based on ethylene diamine or diethylene triamine or higher ethyleneamines, and polyphosphates such as tetrasodium pyrophosphate.

10. A method of drilling or completing a well wherein the wellbore fluid used is as in claim 1 or 2.

11. A method of providing enhanced information from electrical logging tools, measurement-while-drilling (MWD), logging while drilling (LWD), geosteering and like wherein the efficiency is enhanced by the improved electrical conductivity of any of the wellbore fluids as in claim 1 or 2.

12. A fluid of claim 8, wherein the dissolved anions include phosphate, carbonate, or silicate.