Negative electrode for rechargeable battery

• US 6,777,134 B2
• Filed: 07/31/2002
• Issued: 08/17/2004
• Est. Priority Date: 07/31/2001
• Status: Active Grant

• Current Assignee: NEC Corporation
• Original Assignee: NEC Corporation
• Inventors: Yamamoto, Hironori, Utsugi, Koji, Mori, Mitsuhiro, Miura, Tamaki, Iriyama, Jiro, Miyachi, Mariko
• Primary Examiner(s): Chaney, Carol
• Assistant Examiner(s): Martin, Angela J.
• Application Number:
  US10/208,962
• Publication Number:
  US 20030036000A1
• Time in Patent Office: 748 Days
• Field of Search: 429/231.95, 429/231.4, 429/246, 429/213, 429/218.1, 429/236
• US Class Current: 429/231.95
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: H01M 4/602 Polymers
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A negative electrode for a rechargeable battery including: a current collector, a first layer containing a conductive material to occlude and release lithium ion, the first layer formed on the current collector, a second layer containing a metal selected from lithium and lithium alloy, the second layer formed on the first layer, and a third layer containing a lithium ion conductive material, the third layer formed on the second layer. The third layer prevents the lithium and/or the lithium alloy in the second layer from being in contact with the electrolyte and smoothly feeds the lithium to the second layer to improve the efficiency of the negative electrode. The first layer can occlude and release the part of the lithium to be occluded and released, thereby reducing the volume change of the second layer. Such a structure of the negative electrode enables us to enhance cycling efficiency, and to attain long cycle life and good safety.

Claims

1. A negative electrode for a rechargeable battery, comprising:

a current collector;

a first layer containing a conductive material to occlude and release lithium ion, the first layer formed on the current collector;

a second layer containing a metal selected from lithium and lithium alloy, the second layer formed on the first layer, and wherein the second layer is an amorphous layer; and

a third layer containing a lithium ion conductive material, the third layer formed on the second layer.

2. The negative electrode as defined in claim 1, wherein the first layer includes a carbon material as a main component.

3. The negative electrode as defined in claim 2, wherein the carbon material is one selected from a group consisting of graphite and amorphous carbon.

4. The negative electrode as defined in claim 1, wherein the third layer contains at least one compound selected from a group consisting of lithium carbonate, lithium oxide, lithium sulfide and lithium halide.

5. The negative electrode as defined in claim 1, wherein the third layer is an amorphous layer.

6. The negative electrode as defined in claim 1, wherein the third layer is a film formed by one method selected from a group consisting of an evaporation, a sputtering, a chemical vapor deposition, and a sol-gel deposition.

7. A lithium rechargeable battery comprising the negative electrode as defined in claim 1.

8. A negative electrode for a rechargeable battery comprising:

a current collector;

a first layer containing a conductive polymer, the first layer formed on the current collector;

a second layer containing a metal selected from lithium and lithium alloy, the second layer formed on the first layer; and

a third layer containing a lithium ion conductive material, the third layer formed on the second layer.

9. The negative electrode as defined in claim 8, wherein the conductive polymer is selected from a group consisting of polyacetylene, its derivative, polythiophene, its derivative and a condensate of quinone-based compound.

10. The negative as defined in claim 8, wherein the conductive polymer is a mixture of an electron-conductive material and a rubber-like material.

11. The negative electrode as defined in claim 8, wherein the second layer is an amorphous layer.

12. The negative electrode as defined in claim 8, wherein the first layer includes a carbon material as a main component.

13. The negative electrode as defined in claim 12, wherein the carbon material is one selected from a group consisting of graphite and amorphous carbon.

14. The negative electrode as defined in claim 8, wherein the third layer contains at least one compound selected from a group consisting of lithium carbonate, lithium oxide, lithium sulfide and lithium halide.

15. The negative electrode as defined in claim 8, wherein the third layer is an amorphous layer.

16. The negative electrode as defined in claim 8, wherein the third layer is a film formed by one method selected from a group consisting of an evaporation, a sputtering, a chemical vapor deposition and a sol-gel deposition.

17. A lithium rechargeable battery comprising the negative electrode as defined in claim 8.