Salt water desalination process using ion selective membranes

• US 6,783,682 B1
• Filed: 08/16/2000
• Issued: 08/31/2004
• Est. Priority Date: 08/20/1999
• Status: Expired due to Fees

• Current Assignee: Let Leading Edge Technologies Limited
• Original Assignee: Let Leading Edge Technologies Limited
• Inventors: Awerbuch, Leon
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US09/641,123
• Time in Patent Office: 1,476 Days
• Field of Search: 210/180, 210/652, 210/651, 210/653, 210/175, 210/767
• US Class Current: 210/652
• CPC Class Codes: B01D 1/26 Multiple-effect evaporating
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/18 pH control
• CPC Class Codes: B01D 2311/268 Water softening
• CPC Class Codes: B01D 3/065 Multiple-effect flash distillation (more than two traps)
• CPC Class Codes: B01D 61/026 comprising multiple reverse osmosis steps
• CPC Class Codes: B01D 61/027 Nanofiltration
• CPC Class Codes: B01D 61/0271 comprising multiple nanofiltration steps
• CPC Class Codes: B01D 61/029 Multistep processes comprising different kinds of membrane processes selected from reverse osmosis, hyperfiltration or nanofiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: C02F 1/04 by distillation or evaporation
• CPC Class Codes: C02F 1/042 Prevention of deposits
• CPC Class Codes: C02F 1/06 Flash evaporation
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02A 20/131 Reverse-osmosis

Abstract

The invention is directed to an improved desalination process to produce potable water. The process represents an improvement of hybrid of membrane and desalination technologies. The improvement of the invention comprises the operation of an ion selective membrane at a variable pressure as a function of the cost of electricity to form a softened salt water that is blended in variable proportions, to increase the top operating temperature of the desalination system and increase recovery of potable water, with untreated salt water.

Claims

1. A desalination process to produce potable water which comprises:

(a) passing a first stream of water containing a high concentration of hardness ions through an ion selective membrane to form a softened water having a reduced content;

of hardness ions;

(b) blending the softened water with a second stream of water containing higher concentration of hardness ions than the softened water to form a feed to a thermal desalination system; and

(c) introducing the feed to the desalination system to form a water product of potable quality, wherein the proportions of the softened and second stream of water forming the feed to the desalination system are varied to the top operating temperature or the system and increase recovery of potable water.

2. The desalination process according to claim 1, wherein the softened water content of the feed is at least 5%.

3. The desalination process according to claim 1, wherein the feed is passed through at least one desalination system selected from the group consisting of multistage flash distillation, multieffect distillation and vapor compressior:

distillation.

4. The desalination process according to claim 1, wherein the desalination system is multistage flash distillation.

5. The desalation process according to claim 4, wherein the multistage flash distillation system is operated at a temperature of 95-180°

C.

6. The desalination process according to any one of claims 1, 4 or 5, wherein the ion selective membrane is operated at a variable pressure of 5-80 bar.

7. The desalination process according to claim 6, wherein the ionic content and quantity of softened water varies with the operating pressure of the ion selective membrane.

8. The desalination process according to claim 1 or 4, wherein the ion selective membrane is a nanofiltration membrane.

9. The desalination process according to claim 8, wherein the first stream of water is subjected to a deaeration pre-treatment cut step after passing through a softening system comprised of one or mole nanofiltration membranes.

10. The desalination process according to claim 9, wherein the first stream of water is pre-heated by the heat of a reject stream of the desalination system before deaeration.

11. The desalination process according to claim 1, wherein the softened water is stored in a buffer system.

12. The desalination process according to claim 11, wherein the softened water stored in the buffer system is blended with the second stream of water to form the feed to the desalination system.

13. The desalination process according to claim 11, wherein the softened water stored in the buffer system is injected into the desalination system.

14. The desalination process according to claim 1, wherein the softened water is fed by a cluster system to two or more desalination systems and blended with the second stream of each system.

15. The desalination process according to claim 1 or 12, wherein the ion selective membrane is operated at a variable pressure as a function of the cost of electricity to form the softened water that is blended in variable proportions with the second stream to increase the operating temperature of the desalination system and increase recovery of potable water.

16. The desalination process according to claim 1, wherein the desalination system produces brine containing water selected from the group consisting of reject, blowdown and recycled brine which is partially subjected to a nanofiltration step and recycled through the desalination system.

17. The desalination pass according to claim 1, wherein a stoichiometric amount of acid is added to the first stream before the stream passes through the ion selective membrane.

18. The desalination process of claim 1, wherein the first stream of water is selected from a group consisting of salt water, seawater, brackish water and impaired water.

19. The desalination process of claim 18, wherein the impaired water contains soluble salts having an ionic content of harness ions in excess of 1,500 mg/liter.