Chlorinated vinyl resin/cellulosic blends: compositions, processes, composites, and articles therefrom

• US 6,784,230 B1
• Filed: 09/14/2000
• Issued: 08/31/2004
• Est. Priority Date: 09/23/1999
• Status: Active Grant

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Dougherty, Eugene Patrick, Patterson, John Robert, Reading, Scott Warren
• Primary Examiner(s): Harlan, Robert D.
• Application Number:
  US09/661,816
• Time in Patent Office: 1,447 Days
• Field of Search: 524/13, 524/16, 524/567, 524/569, 428/338, 428/339
• US Class Current: 524/13
• CPC Class Codes: B29C 48/00 Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor extrusion blow-moulding B29C49/04
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: C08J 2327/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08J 9/0061 characterized by the use of several polymeric components
• CPC Class Codes: C08J 9/0085 Use of fibrous compounding ingredients C08J9/0076 takes precedence
• CPC Class Codes: C08J 9/06 by a chemical blowing agent
• CPC Class Codes: C08K 5/005 Stabilisers against oxidation, heat, light, ozone
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 27/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 27/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

Compositions and processes for preparing extrudable powder blends containing at least one vinyl chloride resin and a cellulosic material are provided. More specifically, compositions and processes for preparing extrudable free-flowing powder blends containing PVC and wood flour (WF) are also provided for preparing foamed or nonfoamed extrudates. The processes provided herein incorporate components which may contain up to a total of 25 weight percent water. Processes for preparing foamed extrudates are also provided wherein a cooling fluid is used to increase the expansion ratio of the foam. Finally provided are composites having an extrudable thermoplastic substrate and at least one capstock layer disposed thereon containing a PVC/WF composition.

Claims

1. A process for preparing an extrudable powder blend comprising the steps of:

(I) blending a mixture comprising the following components;

(a) from 30 to 65 weight percent of at least one chlorinated vinyl resin;

(b) from 0.25 to 5 weight percent of at least one thermal stabilizer;

(c) from 1.5 to 5 weight percent of at least one lubricant;

(d) from 3.5 to 15 weight percent of at least one high molecular weight polymer processing aid; and

(e) from 24 to 65 weight percent of at least one cellulosic material containing moisture, based upon the total weight of the powder blend;

(II) raising the temperature above 50°

C. during the (I) blending step; and

(III) removing water vapor.

2. The process according to claim 1 wherein the total amount of moisture in the extrudable powder blend after step (III) is below three weight percent, based upon the total weight of the powder blend.

3. The process according to claim 2 wherein the (a) at least one chlorinated vinyl resin and the (e) at least one cellulosic material are first blended at a temperature above 80°

C. before adding the (c) at least one lubricant.

4. A process for preparing an extrudable free-flowing powder blend comprising the steps of:

(I) blending a mixture comprising the following components;

(a) from 40 to 55 weight percent of at least one PVC resin;

(b) from 0.5 to 1.5 weight percent of at least one thermal stabilizer;

(c) from 1.5 to 3 weight percent of at least one lubricant;

(d) from 5 to 10 weight percent of at least one high molecular weight polymer processing aid;

(e) from 34 to 52 weight percent of at least one wood flour containing moisture;

(f) from 3 to 15 weight percent of at least one mineral filler; and

(g) up to 3 weight percent of at least one blowing agent, based upon the total weight of the powder blend;

(II) raising the temperature above 80°

C. during the (I) blending step; and

(III) removing water vapor so that the final moisture amount in of the powder blend is below 2.0 weight percent, based upon the total weight of the powder blend.

5. The process according to claim 4 wherein the (a) at least one PVC resin and the (e) at least one wood flour are first blended at a temperature above 80°

C. before adding the (c) at least one lubricant.

6. The process according to claim 4 wherein the final moisture content is below one weight percent, based upon the total weight of the powder blend.

7. The process according to claim 4 wherein the mixture further comprises up to 15 weight percent of at least one impact modifier, based upon the total weight of the powder blend.

8. The process according to claim 4 wherein the total amount of water added during the addition of components (a) through (f) is less than or equal to 25 weight percent, based upon the total weight of the powder blend.

9. The process according to claim 8 wherein at least one of the components (a) through (f) is supplied as a water-based dispersion.

10. A process for preparing a foamed extrudate comprising the steps of:

(I) feeding an extrudable free-flowing powder blend, comprising at least one chlorinated vinyl resin, at least one blowing agent, and from 24 to 65 weight percent of at least one cellulosic material containing moisture, based upon the total weight of the powder blend, into an extruder;

(II) melting the powder blend to form a melt;

(III) extruding the melt from a die to form an expanding extrudate having at least one surface; and

(IV) hardening the surface of the expanding extrudate with a cooling fluid to increase the expansion ratio.

11. The process according to claim 10 wherein the cooling fluid is a gas directed away from the die surface and towards the surface of the extrudate.