Electrochromic display

• US 6,785,036 B1
• Filed: 09/01/2000
• Issued: 08/31/2004
• Est. Priority Date: 02/04/1998
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer Healthcare AG (Bayer AG)
• Inventors: Neigl, Ralf, Claussen, Uwe, Berneth, Horst, Jacobsen, Wolfgang
• Primary Examiner(s): Spector, David N.
• Application Number:
  US09/601,571
• Time in Patent Office: 1,460 Days
• Field of Search: 359/268, 359/269, 359/271, 359/273, 359/274, 359/267, 359/265, 359/266, 252/583, 204/290.07
• US Class Current: 359/271
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/1502 complementary cell

Abstract

The invention describes an electrochromic display element in the form of an electrically dimmable mirror, an optical filter having an electrically alterable transparency or a display element which contains an electrochromic liquid between two electrode sheets, where at least one of the electrode sheets is transparent and has a transparent, electrically conductive layer and the transparent electrode sheet has a pattern of strips or grid made of a material having metallic conductivity in order to produce a uniform coloration of the electrochromic liquid.

Claims

1. An electrochromic display element which comprises:

1) a first electrode comprising;

a first substrate, made of transparent material in the form of a sheet having a smooth flat surface;

a first electrically conductive layer, located on said flat surface of said first substrate and being continuous and transparent; and

a periodic or aperiodic pattern of strips or grid made of metallic conductive material located outside of said first substrate, and above or below said first electrically conductive layer and in continuous electrical contact with the same;

2) a second electrode comprising;

a second substrate, made of material which is the same as or different from that of said first substrate, in the form of a sheet having a smooth flat surface;

a second electrically conductive layer, located on said flat surface of said second substrate and being continuous and optionally transparent; and

optionally, a periodic or aperiodic pattern of strips or grid made of metallic conductive material located outside of said second substrate, and above or below said second electrically conductive layer and in continuous electrical contact with it;

3) an electrochromic medium; and

4) means for maintaining the electrically conductive layers of said first and second electrodes in spaced-apart proximity facing each other, and for holding said electrochromic medium between said first and second electrodes.

2. The electrochromic display element according to claim 1, characterized in that the electrochromic medium is a solution, a gel or a solid.

3. The electrochromic display element according to claim 1 or 2, characterized in that the electrochromic medium contains at least one pair of redox substances of which one is reducible and the other is oxidizable, where both are colourless or only slightly coloured and one substance is reduced and the other is oxidized on application of a voltage to the display element, with at least one becoming coloured, and after switching off the voltage the two original redox substances are formed again and the display element decolorizes.

4. The electrochromic display element according to claim 3, characterized in that

a) the reducible substance has at least two chemically reversible reduction waves in the cyclic voltammogram and the oxidizable substance correspondingly has at least two chemically reversible oxidation waves, or

b) the reducible substance and the oxidizable substance are covalently bound via a bridge, or

c) the reducible and/or oxidizable substances selected are ones in which the reversible transition between the oxidizable form and the reducible form or vice versa is associated with the breaking or the formation of a σ bond, or

d) the reducible substance and the oxidizable substance are metal salts or metal complexes of metals which exist in at least two oxidation states, or

e) the reducible and/or oxidizable substances are selected from the group consisting of_oligomers and polymers which contain at least one of the redox systems mentioned or else pairs of such redox systems as are defined under a) to d), or

f) the reducible and/or oxidizable substances used as mixtures of the substances described in a) to e), provided that these mixtures contain at least one reducible and at least one oxidizable redox system.

5. The electrochromic display element according to claim 1, characterized in that each of said first and second electrodes has a periodic or aperiodic pattern of strips or grids made of metallic conductive material.

6. The electrochromic display element according to claim 5, characterized in that each of said first and second electrodes has a periodic pattern of strips or grids and the lines of the pattern of strips or grids of the two electrodes form an angle with one another.

7. The electrochromic display element according to claim 1, characterized in that the pattern of strips or grid made of metallic conductive material is aperiodic on at least one electrode.

8. The electrochromic display element according to claim 7, characterized in that the periodicity of the pattern of strips or grid on at least one electrode is restricted to a very short distance.

9. display element according to claim 7, characterized in that the arrangement of the aperiodic grid is such that the mean of the distance between two neighboring points of intersection of the grid, taken over all points of intersection of the grid, corresponds to the dot spacing of a periodic dot grid having the same size and the same number of grid points and in that the autocorrelation function of the grid decreases rapidly in all directions for values which are greater than said dot spacing.

10. The electrochromic display element according to claim 1, characterized in that said pattern of strips or grid on the electrode or electrodes is deposited on the transparent, electrically conductive layer.

11. The electrochromic display element according to claim 1, characterized in that the transparent, electrically conductive layer on the electrode is deposited on said pattern of strips or grid.

12. The electrochromic display element according to claim 1, characterized in that said pattern of strips or grid of at least one electrode has a minimum mesh spacing of 3 mm.

13. The electrochromic display element according to claim 1, characterized in that said pattern of strips or grid has a maximum optical density of 0.3.