Hydrogen generating cell with cathode

• US 6,787,008 B2
• Filed: 04/02/2002
• Issued: 09/07/2004
• Est. Priority Date: 10/30/2001
• Status: Expired due to Term

• Current Assignee: Microlin LLC
• Original Assignee: Microlin LLC
• Inventors: Zecevic, Strahinja K., Joshi, Ashok V.
• Primary Examiner(s): Nicolas, Wesley A.
• Application Number:
  US10/115,273
• Publication Number:
  US 20030082415A1
• Time in Patent Office: 889 Days
• Field of Search: 204/252, 204/263, 204/266, 204/282, 204/295
• US Class Current: 204/252
• CPC Class Codes: A61L 2209/133 Replaceable cartridges, refills
• CPC Class Codes: A61L 9/12 Apparatus, e.g. holders, therefor
• CPC Class Codes: H01M 10/0427 Button cells
• CPC Class Codes: H01M 10/26 Selection of materials as electrolytes
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 4/244 Zinc electrodes
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 50/109 of button or coin shape
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A storage stable hydrogen cell comprising an anode cap subassembly, cathode can subassembly, and a grommet is disclosed. For one embodiment the cathode in the cathode can subassembly is configured for contact with the electrolyte. The cathode is hydrogen permeable and substantially impermeable to O₂, CO₂ and water. In turn, the cathode can preclude the passage of O₂, CO₂ and water into and out of the cell, and simultaneously can facilitate the permeation of hydrogen through at least one aperture in the cell. In another embodiment, a commercially available Zn-air cell is converted into storage stable H₂ cells by sealing a membrane structure around the apertures of the Zn-air cell. Such membrane precludes the passage of O₂, CO₂ and water into and out of cell but allows the passage of hydrogen generated in the cell through the aperture of the cell and through the membrane.

Claims

1. A storage stable hydrogen generating galvanic cell comprising:

an anode subassembly comprising a metal anode, electrolyte and cap;

a cathode subassembly comprising a substantially non-porous cathode, separator and can, wherein the cathode is configured for contact with the electrolyte, the cathode being hydrogen permeable and substantially impermeable to O₂, CO₂ and water to in turn preclude the passage of O₂, CO₂ and water into and out of the cell, and to facilitate the permeation of hydrogen through at least one aperture of the can; and

a grommet between at least a portion of the anode subassembly and a portion of the cathode subassembly.

2. The hydrogen generating cell of claim 1 wherein the cathode comprises at least one of a conductive non-porous polypropylene;

sintered non-porous composite of carbon, PTFE, and FEP foil;

palladium foil, iron titanium foil, iron magnesium foil, as well as metallic membranes of one or more of palladium, nickel, titanium, and, non-porous polymers, and composites of ceramics and palladium.

3. The hydrogen generating cell of claim 1 wherein the cathode includes a graded porosity from porous to non-porous, wherein the porous portion of the cathode faces the anode and non-porous portion of the cathode faces the aperture of the bottom can.

4. The hydrogen generating cell of claim 3 wherein the cathode comprises a combination of conductive material and polymer, wherein the ratio of conductive material to polymer may be varied within the cathode along the thickness thereof.

5. The hydrogen generating cell of claim 4 wherein the conductive material comprises at least one of graphite, active carbon, conductive ceramics, Reney nickel or other metals suitable for hydrogen generation such as for instance platinum or palladium.

6. The hydrogen generating cell of claim 1 wherein the cathode comprises a non-porous cathode, which is substantially permeable to hydrogen and substantially impermeable to O₂, H₂O, and CO₂.

7. The hydrogen generating cell of claim 1 wherein the at least one aperture of the cathode subassembly compromises a plurality of apertures, each of which has a diameter of more than about 2 microns.

8. The hydrogen generating cell according to claim 1 wherein the metal anode comprises a metal selected from the group consisting of zinc, lead, iron, magnesium, aluminum and mixtures and alloys thereof.

9. The hydrogen generating cell according to claim 1 wherein the anode comprises a zinc alloy.

10. A system comprising:

a galvanic electrochemical hydrogen gas generating cell having at least one aperture in cathode subassembly can for releasing gas; and

a membrane associated with the at least one aperture, the membrane being hydrogen permeable and substantially impermeable to O₂, CO₂ and water, to, in turn, preclude the passage of O₂, CO₂ and water into and out of the cell, and to facilitate the permeation of hydrogen through the at least one aperture of the can.

11. The system of claim 10 wherein the membrane is electrically conductive.

12. The system of claim 11 wherein the membrane is selected from the group consisting of:

conductive non-porous polypropylene or Teflon;

sintered composite of carbon, PTFE, and FEP foil;

palladium foil, iron titanium foil, iron magnesium foil, as well as metallic membranes of one or more of palladium, nickel, titanium, and, non-porous polymers, and composites of ceramics and palladium.

13. A storage stable and efficient hydrogen generating cell comprising:

a commercially available Zn-air cell or hydrogen generating cell comprising a porous cathode; and

a membrane structure associated with an aperture of the cell, wherein the membrane structure is hydrogen permeable and substantially impermeable to O₂, CO₂ and water, to, in turn preclude the passage of O₂, CO₂ and water into and out of the cell, and to facilitate the permeation of hydrogen through the aperture.

14. A hydrogen generating cell of claim 13 where a membrane structure consists of packaging the cell in another enclosure comprising a non-porous membrane permeable to hydrogen but substantially impermeable to H₂O, O₂, and CO₂.

15. A storage-stable hydrogen-generating galvanic cell comprising:

a cell casing including an anode portion disposed at one end of the casing and at least one aperture disposed at an opposing end of the cell casing;

a cathode structure disposed within the casing adjacent to the aperture in the casing and electrically insulated from the anode portion of the casing, the cathode structure substantially impermeable to O₂, CO₂ and water and permeable to hydrogen; and

an electrolyte disposed within the casing and between the cathode structure and the anode portion of the casing.