Particles

• US 6,787,233 B1
• Filed: 04/18/2001
• Issued: 09/07/2004
• Est. Priority Date: 10/19/1998
• Status: Expired due to Term

• Current Assignee: Life Technologies AS (Perspecta, Inc.)
• Original Assignee: Dynal Biotech ASA (Thermo Fisher Scientific Incorporated)
• Inventors: Molteberg, Astrid Evenrod, Berge, Arvid Trygve
• Primary Examiner(s): LE, HOA T
• Application Number:
  US09/807,839
• Time in Patent Office: 1,238 Days
• Field of Search: 428/403, 428/407, 428/323, 428/327, 106/286.7, 106/403, 106/287.18
• US Class Current: 428/403
• CPC Class Codes: C08K 2003/0831 Gold
• CPC Class Codes: C08K 2201/013 Additives applied to the surface of polymers or polymer particles
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C09J 9/02 Electrically-conducting adhesives
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 3/323 by applying an anisotropic conductive adhesive layer over an array of pads
• CPC Class Codes: Y10T 428/2991 Coated

Abstract

The invention provides electroconductive particles comprising a styrene copolymer core and an external gold coating, characterised in that as said copolymer core is used a styrene copolymer comprising less than 50 wt. % styrene residues.

Claims

1. Electroconductive particles comprising a styrene copolymer core and an external gold coating, said styrene copolymer core consisting of a palladium-coated styrene copolymer,

wherein said styrene copolymer is a copolymer of styrene and a functionalized comonomer.

2. Particles as claimed in claim 1 wherein the copolymer core has a styrene content of 0.5 to 98.5 wt %.

3. Particles as claimed in claim 1 wherein the copolymer core comprises less than 50 wt. % styrene monomers.

4. Particles as claimed in claim 1 having a nickel coating interior to said gold coating.

5. Particles as claimed in claim 4 wherein said nickel coating has a thickness of 200 to 1000 Å

.

6. Particles as claimed in claim 1 wherein said gold coating has a thickness of 50 to 600 Å

.

7. Particles as claimed in claim 1 wherein the styrene copolymer is selected from the group consisting of styrene acrylic acid ester, styrene methacrylic acid ester and mixtures thereof.

8. Particles as claimed in claim 1 wherein the gold coating is surface treated with a thiol.

9. Particles as claimed in claim 1 having a mode particle diameter of 0.5 to 500 μ

m.

10. The electroconductive particles as claimed in claim 1 coated with a non-conductive coating.

11. An electroconductive adhesive composition comprising an adhesive matrix material with electroconductive particles disposed therein, said electroconductive particles comprising a styrene copolymer core and an external gold coating, said styrene copolymer core consisting of a palladium-coated styrene copolymer,

wherein said styrene copolymer is a copolymer of styrene and a functionalized comonomer.

12. The use of an adhesive composition as claimed in claim 11 for providing an electrical connection between electronic components.

13. Use as claimed in claim 12 for providing an anisotropic electrical connection between electronic components.

14. The electroconductive adhesive composition as claimed in claim 11, wherein the styrene copolymer core comprises less than 50 wt. % styrene monomers.

15. A formed polymer product comprising electroconductive particles dispersed in a polymer, said electroconductive particles comprising a styrene copolymer core and an external gold coating, said styrene copolymer core consisting of a palladium-coated styrene copolymer,

wherein said styrene copolymer is a copolymer of styrene and a functionalized comonomer.

16. The formed polymer product as claimed in claim 15, wherein the styrene copolymer core comprises less than 50 wt. % styrene monomers.

17. A coating composition comprising electroconductive particles dispersed in a liquid carrier, said electroconductive particles comprising a styrene copolymer core and an external gold coating, said styrene copolymer core consisting of a palladium-coated styrene copolymer,

wherein said styrene copolymer is a copolymer of styrene and a functionalized comonomer.

18. The coating composition as claimed in claim 17, wherein the styrene copolymer core comprises less than 50 wt. % styrene monomers.