Encapsulation compositions and process for preparing the same

• US 6,790,453 B2
• Filed: 03/14/2002
• Issued: 09/14/2004
• Est. Priority Date: 03/14/2001
• Status: Active Grant

• Current Assignee: Mccormick & Company Incorporated
• Original Assignee: Mccormick & Company Incorporated
• Inventors: Zasypkin, Dmitriy, Porzio, Michael A.
• Primary Examiner(s): Levy, Neil S.
• Application Number:
  US10/096,665
• Publication Number:
  US 20020189493A1
• Time in Patent Office: 915 Days
• Field of Search: 424/400, 424/401, 424/405, 424/408-410, 424/439-442, 424/484-485, 424/739, 574/774, 574/777-782
• US Class Current: 424/408
• CPC Class Codes: A01N 25/26 in coated particulate form
• CPC Class Codes: A23L 27/72 Encapsulation
• CPC Class Codes: A23V 2002/00 Food compositions, function of food ingredients or processes for food or foodstuffs
• CPC Class Codes: A23V 2200/224 Encapsulating agent
• CPC Class Codes: A23V 2250/5028 Arabic
• CPC Class Codes: A23V 2250/5432 Gelatine
• CPC Class Codes: A23V 2250/61 Glucose, Dextrose
• CPC Class Codes: A23V 2250/616 Maltose
• CPC Class Codes: A23V 2250/6412 Isomaltitol, palatinit
• CPC Class Codes: A23V 2250/6418 Mannitol
• CPC Class Codes: C08L 5/14 Hemicellulose; Derivatives thereof
• CPC Class Codes: C08L 89/06 derived from leather or skin , e.g. gelatin
• CPC Class Codes: Y10T 428/2985 Solid-walled microcapsule from synthetic polymer

Abstract

Encapsulation compositions in which an encapsulate (A) is encapsulated in a matrix (B) may be prepared by:

(i) mixing matrix (B) with a liquid plasticizer and encapsulate (A) in an extruder, to obtain a melted mixture of encapsulate (A) and matrix (B); and

(ii) extruding the melted mixture, to obtain an extruded mixture.

Claims

1. An encapsulation composition, comprising:

(A) an encapsulate, encapsulated in;

(B) a glassy matrix, said matrix comprising;

(a) 50 to 99% by weight, based on the total weight of said matrix (B), of gum arabic and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol;

or

(b) 50 to 99% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol,

wherein said low molecular weight carbohydrate or polyol is selected from the group consisting of glucose, sucrose, maltose, lactose, 42 dextrose equivalent and 36 dextrose eqivalent corn syrup solids, erythritol, lactitol, mannitol, sorbitol, maltitol, isomalt, xylitol, hydrogenated corn syrups, hydrogenated glucose syrups, hydrogenated maltose syrups, hydrogenated lactose syrups, and mixtures thereof.

2. The composition of claim 1, wherein said matrix (B) comprises:

(a) 50 to 99% by weight, based on the total weight of said matrix (B), of gum arabic and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

3. The composition of claim 2, wherein said matrix (B) comprises:

(a) 60 to 80% by weight, based on the total weight of said matrix (B), of gum arabic and 20 to 40% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

4. The composition of claim 1, wherein said matrix (B) comprises:

(b) 50 to 99% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

5. The composition of claim 4, wherein said matrix (B) comprises:

(b) 60 to 80% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 20 to 40% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

6. The composition of claim 1, having a glass transition temperature of at least 35°

C.

7. The composition of claim 1 wherein said encapsulate is selected from the group consisting of medications, pesticides, vitamins, preservatives, and flavoring agents.

8. The composition of claim 1, wherein said encapsulate is a flavoring agent.

9. The composition of claim 8, wherein said flavoring agent is selected from the group consisting of natural extracts, oleoresins, essential oils, protein hydrolysates, aqueous reaction flavors, compounded natural flavors, and artificial flavors.

10. The composition of claim 8, wherein said flavoring agent optionally contains a plasticizer or an emulsifier.

27. The composition of claim 1, wherein said encapsulate is present in an amount of 4 to 18% by weight, based on the total weight of said composition.

28. The composition of claim 1, wherein said encapsulate is present in an amount of 9 to 16% by weight, based on the total weight of said composition.

11. An encapsulation composition, comprising:

(A) an encapsulate, encapsulated in;

(B) a glassy matrix, said matrix comprising;

(a) 50 to 99% by weight, based on the total weight of said matrix (B), of gum arabic and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol;

or

(b) 50 to 99% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol,

wherein said low molecular weight carbohydrate or polyol is selected from the group consisting of glucose, sucrose, maltose, lactose, 42 dextrose equivalent and 36 dextrose equivalent corn syrup solids, erythritol, lactitol, mannitol, sorbitol, maltitol, isomalt, xylitol, hydrogenated corn syrup, hydrogenated glucose syrups, hydrogenated maltose syrups, hydrogenated lactose syrups, and mixtures thereof, and

wherein said composition is prepared by a process comprising;

(i) mixing matrix (B) with a liquid plasticizer and encapsulate (A) in an extruder, to obtain a melted mixture which comprises encapsulate (A) and matrix (B); and

(ii) extruding said melted mixture, to obtain an extruded mixture.

12. The composition of claim 11, wherein said liquid plasticizer is at least one member selected from the group consisting of water;

glycerol;

propylene glycol;

aqueous solutions of glycerol, propylene glycol, monosaccharides, and disaccharides; and

invert and high fructose corn syrups; and

mixtures thereof.

13. The composition of claim 11, wherein said liquid plasticizer is water.

14. The composition of claim 11, further comprising cooling said extruded mixture.

15. The composition of claim 11, wherein said encapsulate is at least one member selected from the group consisting of medications, pesticides, vitamins, preservatives, flavoring agents, and mixtures thereof.

16. The composition of claim 11, wherein said encapsulate is a flavoring agent.

17. The composition of claim 16, wherein said flavoring agent is at least one member selected from the group consisting of natural extracts, oleoresins, essential oils, protein hydrolysates, aqueous reaction flavors, compounded natural flavors, artificial flavors, and mixtures thereof.

18. The composition of claim 16, wherein said flavoring agent comprises a plasticizer or an emulsifier.

19. The composition of claim 11, wherein said extruder is a twin screw extruder.

20. The composition of claim 11, wherein said matrix (B) comprises:

(a) 50 to 99% by weight, based on the total weight of said matrix (B), of gum arabic and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

21. The composition of claim 11, wherein said matrix (B) comprises:

(a) 60 to 80% by weight, based on the total weight of said matrix (B), of gum arabic and 20 to 40% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

22. The composition of claim 11, wherein said matrix (B) comprises:

(b) 50 to 99% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 1 to 50% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

23. The composition of claim 11, wherein said matrix (B) comprises:

(b) 60 to 80% by weight, based on the total weight of said matrix (B), of a mixture of at least two food polymers selected from the group consisting of gum arabic, hydrolyzed gelatin, gelatin, and larch gum and 20 to 40% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol.

24. The composition of claim 11, having a glass transition temperature of at least 35°

C.

25. The composition of claim 11, wherein said encapsulate is present in an amount of 4 to 18% by weight, based on the total weight of said composition.

26. The composition of claim 11, wherein said encapsulate is present in an amount of 9 to 16% by weight, based on the total weight of said composition.