Edge sealing of a laminated transparency

• US 6,791,065 B2
• Filed: 07/24/2002
• Issued: 09/14/2004
• Est. Priority Date: 07/24/2002
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Bartrug, Bruce A., Pinchok, Robert N., Schwartz, James H., Hawk, Allen R.
• Primary Examiner(s): Paik, Sang
• Assistant Examiner(s): FASTOVSKY, LEONID M
• Application Number:
  US10/201,863
• Publication Number:
  US 20040016738A1
• Time in Patent Office: 783 Days
• Field of Search: 219/203, 219/522, 219/219, 219/541, 318/22.R, 318/309, 318/312, 318/314
• US Class Current: 219/203
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 15/088 comprising polyamides
• CPC Class Codes: B32B 15/20 comprising aluminium or copper B32B15/016 and B32B15/017 take precedence
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10302 Edge sealing
• CPC Class Codes: B32B 17/1055 characterized by the resin layer, i.e. interlayer
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/1088 by superposing a plurality of layered products
• CPC Class Codes: B32B 17/10935 as a preformed layer, e.g. formed by extrusion
• CPC Class Codes: B32B 17/10972 Degassing during the lamination B32B17/10816 takes precedence
• CPC Class Codes: B32B 2307/202 Conductive
• CPC Class Codes: B32B 2307/302 Conductive
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2307/7242 Non-permeable
• CPC Class Codes: B32B 2311/12 Copper
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 2329/06 PVB, i.e. polyinylbutyral
• CPC Class Codes: B32B 2377/00 Polyamides
• CPC Class Codes: B32B 2605/006 : Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 2605/08 : Cars
• CPC Class Codes: B32B 27/08 : of synthetic resin
• CPC Class Codes: B32B 27/304 : comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/32 : comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 : comprising polyamides
• CPC Class Codes: B32B 3/10 : characterised by a discontinuous layer, i.e. formed of separate pieces of material
• CPC Class Codes: B32B 5/12 : characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
• CPC Class Codes: B32B 7/12 : using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C03C 27/10 : with the aid of adhesive specially adapted for that purpose
• CPC Class Codes: H05B 2203/013 : Heaters using resistive films or coatings
• CPC Class Codes: H05B 2203/016 : Heaters using particular connecting means
• CPC Class Codes: H05B 3/84 : Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
• CPC Class Codes: H05B 3/86 : the heating conductors being embedded in the transparent or reflecting material H05B3/845 takes precedence
• CPC Class Codes: Y10T 29/49083 : Heater type
• CPC Class Codes: Y10T 29/49085 : Thermally variable

Abstract

A heatable laminate includes a first substrate; an electrically conductive member on a portion of the first substrate; a pair of spaced bus bars each bus bar being in electrical contact with the electrically conductive member; a second substrate overlaying and the electrically conductive member and bus bars; an interlayer positioned between the two substrates; a first leads connected to one of bus bars and a second lead connected to the other bus bar, each lead having an end extending beyond the periphery of the first substrate to provide external electrical access to the bus bars; an electrically non-conductive sleeve over selected portions of each of the lead; and air barriers along selected portions of the sleeve to prevent air from enter between the substrates.

Claims

1. A heatable laminate comprising:

a first substrate having a major surface and a periphery;

an electrically conductive member on a portion of the major surface of the first substrate;

a pair of spaced bus bars each bus bar having a major surface defined as a first surface and an opposite surface defined as a second surface, the first surface of each bus bar in electrical contact with the electrically conductive member;

a second substrate having a major surface, with the major surface of the second substrate over and facing the electrically conductive member and the second surface of the pair of bus bars;

a plastic sheet having opposed major surfaces between the major surface of the second substrate and the second surface of the pair of bus bars, one of the major surfaces of the plastic sheet defined as the first surface adhered to a portion of the conductive member and the second surface of the pair of bus bars and the other major surface of the plastic sheet defined as the second surface of the sheet adhered to surface portions of the major surface of the second substrate;

a pair of electrically conductive leads, one of the leads connected to one of the pair of bus bars and the other lead connected to the other one of the bus bars and each lead having an end extending beyond the periphery of the first substrate to provide external electrical access to the bus bars;

an electrically non-conductive sleeve over a portion of each of the leads, an end portion of the sleeve between the substrates and the other end portion extending beyond periphery of the first and second substrate and terminating short of end of the lead outside the substrates;

a first air barrier between inner surface of the sleeve and the surface portion of the lead within the sleeve, and

a second air barrier between selected outer surface portions of the sleeve and adjacent marginal edge portions of the first substrate.

2. The heatable laminate according to claim 1, wherein each of the bus bars are contiguous with its respective lead and surface of the bus bar and lead facing the conductive member is defined as the first surface of the bus bar and the lead, and the opposite surface of the bus bar and the lead are defined as the second surface of the bus bar and the lead with selected portions of each of the second surface of the bus bars secured to the first surface of the plastic sheet by an adhesive.

3. The heatable laminate according to claim 2, wherein the bus bars and respective lead are made of a metal foil and the adhesive on selected portions of the second surface of the bus bar is on the portion of the lead extending through the protective sleeve and is adhered to the adjacent inner surface of the protective sleeve to provide a portion of the first air barrier.

4. The heatable laminate according to claim 3, wherein the heatable laminate is an automotive transparence, the first and second substrates are glass sheets, the metal foil is a copper foil and the adhesive securing potions of the second surface of the bus bars is a pressure sensitive adhesive.

5. The automotive transparence according to claim 4 wherein the transparence is an automotive windshield.

6. The heatable laminate according to claim 1, wherein the electrically conductive member is an electrically conductive coating, the coating defined by a perimeter with the perimeter of the coating spaced from the periphery of the first substrate, and end portion of at least one bus bar extending beyond the perimeter of the coating.

7. The heatable laminate according to claim 6, wherein the heatable laminate is an automotive transparency, the first and second substrates are glass sheets, the coating has at least one conductive film between a pair of dielectric films.

8. The automotive transparency according to claim 7, wherein the area between the perimeter of the coating and the periphery of the first glass sheet is defined as a non-conductive strip and each end portion of each one of the bus bars extends into the non-conductive strip.

9. The automotive transparency according to claim 8, wherein ends of the bus bar terminate short of the periphery of the first sheet.

10. The automotive transparency according to claim 8, wherein the bus bars have different lengths and coating has a top side, a bottom side, a right side and a left side with one of the bus bar extending along the top side and the other one of the bus bars extending along the bottom side and portions of the coating between the bus bars does not extend beyond the ends of the longest bus bar.

11. The automotive transparency according to claim 7, wherein at least one of the major surfaces of the transparency includes a hydrophobic coating.

12. The automotive transparency according to claim 7, wherein at least one of the major surfaces of the transparency includes a photocatalytic coating.

13. The heatable laminate according to claim 1, wherein the adhesive layer on the outer surface potion adjacent the first substrate is a thermo-set adhesive.

14. The heatable laminate according to claim 13, wherein the second barrier is a thermo-set adhesive that is non-tacky at temperatures at or below temperature at which surface of the plastic sheet becomes viscid.

15. The heatable laminate according to claim 1, wherein the plastic sheet is selected from the group consisting of polyvinyl butyral, polyvinyl chloride, polyethylene and combinations thereof.

16. The heatable laminate according to claim 3, wherein at least one of the glass sheets or the plastic sheet has a portion in cross section having a wedged shape.

17. The heatable laminate according to claim 1, wherein the material of the second air barrier is selected from the group consisting of polyvinyl butyral, polyvinyl chloride, polyethylene and combinations thereof.

18. The heatable laminate according to claim 1, wherein the first air barrier includes the inner surfaces of the sleeve adhered by an adhesive to portions of the surfaces of the lead within the sleeve.

19. The heatable laminate according to claim 1, wherein the laminate is a transparency for a vehicle selected from the group consisting of land, air, space above water, below water and combinations thereof.

20. The heatable laminate according to claim 19, wherein the laminate is a transparency for a land vehicle and the land vehicle is an automobile with the transparency selected from the group consisting of windshield, side window, rear window roof window and combinations thereof.

21. The heatable laminate according to claim 6, wherein the transparency is a windshield having a vision area having a top edge and a bottom edge and the coating having a top edge adjacent the top edge of the vision area and a bottom edge adjacent the bottom edge of the vision area with one of the bus bars adjacent the top edge of the coating and the other bus bar adjacent the bottom edge of the coating wherein the bottom edge of the coating spaced a greater distance from the bottom edge of the vision area than the bus bar adjacent the bottom edge of the coating and the top edge of the coating spaced a greater distance from the top edge of the vision area than the bus bar adjacent the top edge of the coating.

22. A laminate comprising:

a first substrate having a major surface and a periphery;

an electrically conductive member responsive to electric stimuli over a potion of the major surface of the first substrate;

a pair of spaced interconnecting activating members, each activating member having a major surface defined as a first surface and an opposite surface defined as a second surface, the first surface in electrical surface contact with the electrically conductive member;

a second substrate having a major surface, with the major surface over and facing the electrically conductive member and the second surface of the pair of activating members;

a plastic sheet between the first and second substrates and second surface of the pair of spaced activating members, the plastic sheet having opposed major surfaces with one of the major surfaces of the plastic sheet defined as the first surface and the opposite surface defined as the second surface wherein the first surface of the plastic sheet is adhered to a portion of the conductive member and the second surface of the pair of activating members and the second surface of the plastic sheet adhered to surface portions of the major surface of the second substrate;

a pair of electrical conductive leads, one of the leads connected to one of the pair of activating members and the other lead connected to the other one of the activating members and each lead having an end extending beyond the periphery of the first substrate to provide external electrical access to the activating members;

a sleeve over a portion of each of the leads, an end portion of the sleeve between the substrates and the other end portion extending beyond the periphery of the first and second substrate and terminating short of the end of the lead outside the substrates;

a first barrier between inner surface of the sleeve and the surface portion of the lead within the sleeve, and

a second air barrier between outer surface portions of the sleeve adjacent the first substrate between the first substrate and the portions of the first substrate.

23. The laminate according to claim 22 wherein the activating members are bus bars.

24. The laminate according to claim 22 wherein the laminate is selected from the group consisting of residential windows, commercial windows, land vehicular windows, space vehicular windows, air vehicular windows, water vehicular windows, widows for doors of refrigerators and combinations thereof.