Low power gas leak detector

• US 6,792,794 B2
• Filed: 01/23/2003
• Issued: 09/21/2004
• Est. Priority Date: 09/27/2002
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Bauhahn, Paul, Groppetti, Claudio C., Bonne, Ulrich
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): Rogers, David A
• Application Number:
  US10/350,234
• Publication Number:
  US 20040060346A1
• Time in Patent Office: 607 Days
• Field of Search: 73/232, 73/310.7, 73/240.6, 73/250.1, 73/250.5, 73/290.5, 73/310.5, 73/31, 422/88
• US Class Current: 73/25.01
• CPC Class Codes: G01N 1/24 Suction devices G01N1/22 - G01N1/2294 take precedence
• CPC Class Codes: G01N 2001/021 Correlating sampling sites with geographical information, e.g. GPS
• CPC Class Codes: G01N 2030/121 cooling; cold traps
• CPC Class Codes: G01N 2030/123 using more than one trap
• CPC Class Codes: G01N 2030/3015 temperature gradients along column
• CPC Class Codes: G01N 2030/3061 column or associated structural member used as heater
• CPC Class Codes: G01N 2030/3076 using specially adapted T(t) profile
• CPC Class Codes: G01N 2030/642 photoionisation detectors
• CPC Class Codes: G01N 2030/8881 Modular construction, specially adapted therefor
• CPC Class Codes: G01N 2035/00881 network configurations
• CPC Class Codes: G01N 25/18 by investigating thermal conductivity by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18
• CPC Class Codes: G01N 30/08 using an enricher
• CPC Class Codes: G01N 30/12 by evaporation
• CPC Class Codes: G01N 30/30 of temperature
• CPC Class Codes: G01N 30/461 with serial coupling of separation columns
• CPC Class Codes: G01N 30/466 with separation columns in parallel
• CPC Class Codes: G01N 30/468 involving switching between different column configurations
• CPC Class Codes: G01N 30/6095 Micromachined or nanomachined, e.g. micro- or nanosize
• CPC Class Codes: G01N 30/66 Thermal conductivity detectors
• CPC Class Codes: G01N 35/00871 Communications between instruments or with remote terminals

Abstract

A leak detector having a multi-stage concentrator, consisting of an array of heater elements which desorb analytes in a phased manner, in synch with the sample stream, to maximize sensitivity. The heater elements of the concentrator are coated with adsorber material on both sides of the heater elements, i.e., top and bottom sides, and have small anchor points to minimize power dissipation. The concentrated gas mixture output of the concentrator is electronically injected into a separator, which for separates the constituents of the detected analyte-fluid and recognizing the nature or source of the analyte.

Claims

1. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along in a first channel and exposed to the fluid in the first channel, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element, wherein at least two of the interactive elements include the same interactive substance;

two or more interactive elements spaced along in a second channel and exposed to the fluid in the second channel, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element, wherein at least two of the interactive elements include the same interactive substance;

a plurality heater elements, each heater element in thermal communication with a corresponding interactive element in the first channel and a corresponding interactive element in the second channel; and

controller means coupled to the two or more heater elements for allowing the two or more interactive elements in the first channel and in the second channel to become exposed to the fluid in the first and second channels before energizing the heater elements in a time phased sequence.

2. A concentrator according to claim 1, wherein:

the two or more interactive elements comprise different portions of the first channel exposed to and extending along at least part of the fluid; and

the two or more interactive elements comprise different portions of the second channel exposed to and extending along at least part of the fluid.

3. A concentrator according to claim 2, wherein each of the plurality heater elements are in thermal communication with a corresponding portion of the first and second channels.

4. A concentrator according to claim 1, wherein the interactive elements are of equal length.

5. A concentrator according to claim 1, wherein the interactive elements are of unequal length.

6. A concentrator according to claim 1, wherein some of the interactive elements are of equal length and some of the interactive elements are of unequal length.

7. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along a first channel and exposed to the fluid in the first channel, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

two or more interactive elements spaced along a second channel and exposed to the fluid in the second channel, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element in the first channel and a corresponding interactive element in the second channel; and

controller means coupled to the plurality of heater elements for allowing the two or more interactive elements of the first channel and the two or more interactive elements of the second channel to become exposed to the fluid before energizing the heater elements in a time phased sequence, said controller means including first energizing means for energizing a first heater element, second energizing means for energizing a second heater element that is located downstream of the first heater element, and a controller for activating said first energizing means, which causes the corresponding first interactive element of the first channel to become heated and desorb selected constituents into the fluid which produces a first concentration pulse in the first channel that is carried by the fluid downstream toward the second heater element and causes the corresponding first interactive element of the second channel to become heated and desorb selected constituents into the fluid which produces a first concentration pulse in the second channel that is carried by the fluid downstream toward the second heater element, and for activating said second energizing means when the first concentration pulses reach the second heater elements.

8. A concentrator according to claim 7, wherein the first heater element and the second heater element include a resistive material.

9. A concentrator according to claim 8, wherein said first energizing means energizes said first heater clement by providing a first voltage, currents, or power pulse, and said second energizing means energizes said second heater element by providing a second voltage, current, or power pulse.

10. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along in a first channel and exposed to the fluid, each of the interactive elements include an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

two or more interactive elements spaced along in a second channel and exposed to the fluid, each of the interactive elements include an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element in the first channel and a corresponding interactive element in the second channel; and

controller means coupled to the plurality of heater elements for energizing the heater elements in a time phased sequence, said controller means including first energizing means for energizing a first heater element with a first energy pulse, second energizing means for energizing a second heater element that is located downstream of the first heater element with a second energy pulse, and a controller for activating said first energizing means, which causes the corresponding interactive element of the first channel to become heated and desorb selected constituents into the fluid which produces a first concentration pulse in the first channel and causes the corresponding interactive element of the second channel to become heated and desorb selected constituents into the fluid which produces a first concentration pulse in the first channel which are carried by the fluid downstream toward the second heater element, and for activating said second energizing means when the first concentration pulses reach the second heater elements, wherein the first energy pulse and the second energy pulse result in triangular shaped temperature pulses of the heater elements.

11. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along in a first channel and exposed to the fluid, each of the interactive elements including an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

two or more interactive elements spaced along in a second channel and exposed to the fluid, each of the interactive elements including an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element of the first channel and a corresponding interactive element of the second channel; and

controller means coupled to the plurality of heater elements for energizing the heater elements in a time phased sequence, said controller means including first energizing means for energizing a first heater element with a first energy pulse, second energizing means for energizing a second heater element that is located downstream of the first heater element with a second energy pulse, and a controller for activating said first energizing means, which causes the corresponding interactive elements to become heated and desorb selected constituents into the fluid which produces first concentration pulses that are carried by the fluid downstream toward the second heater element, and for activating said second energizing means when the first concentration pulses reach the second heater elements, wherein the first energy pulse and the second energy pulse result in square shape temperature pulses of the heater elements.

12. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along a first channel and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

two or more interactive elements spaced along a second channel and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element of the first channel and a corresponding interactive element of the second channel; and

controller means coupled to the plurality of heater elements for energizing the heater elements in a time phased sequence, said controller means including first energizing means for energizing a first heater element with a first energy pulse, second energizing means for energizing a second heater element that is located downstream of the first heater element with a second energy pulse, and a controller for activating said first energizing means, which causes the corresponding interactive elements of the first and second channels, respectively, to become heated and desorb selected constituents into the fluid which produces a first concentration pulse in the first and second channels that is carried by the fluid downstream toward the second heater elements, and for activating said second energizing means when the first concentration pulse reaches the second heater element, wherein the first energy pulse and the second energy pulse result in bell shaped temperature pulses of the heater elements.

13. A concentrator for concentrating one or more constituents of a fluid, comprising:

two or more interactive elements spaced along in a plurality of channels and exposed to the fluid, wherein each of the interactive elements includes an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element wherein each of the interactive elements has a length that is greater than the length of each interactive clement located further upstream in the fluid;

two or more heater elements, each heater element in thermal communication with a corresponding interactive element; and

a controller coupled to the plurality of heater elements for energizing the heater elements in a time phased sequence.

14. A sensor assembly for sensing the enhanced concentration of one or more constituents in a fluid, comprising:

two or more interactive elements spaced along in a first channel and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

two or more interactive elements spaced along in a second channel and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element of the first channel and a corresponding interactive element of the second channel;

controller means coupled to the plurality of heater elements for allowing the two or more interactive elements in each channel to become exposed to the fluid before energizing the heater elements in a time phased sequence such that each of the downstream interactive elements becomes heated and desorbs selected constituents into the fluid at substantially the time that an upstream concentration pulse, produced by one or more upstream interactive elements, reaches the downstream interactive element;

separator means for separating selected constituents of one of the concentration pulses provided by one or more of the interactive elements into individual constituent components; and

detector means for sensing the concentration of one or more of the individual constituent components.

15. A sensor assembly according to claim 14, wherein said detector means includes a thermal conductivity detector.

16. A sensor assembly according to claim 14, further comprising a pump for providing the fluid.

17. A sensor assembly according to claim 16, wherein the pump is an efficient pump that runs only as needed during a concentrator measurement cycle.

18. A sensor assembly according to claim 14, wherein the fluid is driven by thermal convection.

19. A sensor assembly according to claim 14, further includes a preheater for preheating at least a portion of the fluid.

20. A sensor assembly according to claim 19, wherein said preheater heats the fluid throughout the sensor assembly.

21. A sensor assembly according to claim 19, wherein said preheater heats the fluid only in the separation means.

22. A sensor assembly according to claim 14, further includes a cooler for cooling at least a portion of the fluid.

23. A sensor assembly according to claim 14, wherein said controller means is in an inactive sleep mode when not energizing the heater elements.

24. A method for concentrating one or more constituents of a fluid, the method comprising:

providing sets of two or more interactive elements, the interactive elements of each set spaced along in a channel of a plurality of channels, respectively, and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element, where at least two of the interactive elements include the same interactive substance;

waiting for the interactive substance to adsorb one or more constituents from the fluid; and

heating the two or more interactive elements of each set in a time phased sequence.

25. A method for concentrating one or more constituents of a fluid, the method comprising:

providing two or more interactive elements spaced along in each channel of a plurality of channels and exposed to the fluid, each of the interactive elements having an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element, where at least two of the interactive elements incorporate the same interactive substance;

waiting for the interactive substance to adsorb one or more constituents from the fluid; and

heating the two or more interactive elements of each channel in a time phased sequence, wherein said heating comprises;

heating an upstream interactive element, which causes the upstream interactive element to desorb selected constituents into the fluid to produce a first concentration pulse that is carried by the fluid downstream toward a downstream interactive element; and

heating the downstream interactive element when the first concentration pulse reaches the downstream interactive element, which causes the downstream interactive element to desorb selected constituents into the fluid and at least partially overlap the first concentration pulse to produce a second concentration pulse that is carried by the fluid downstream.

26. A method for concentrating one or more constituents of a fluid, the method comprising:

providing N interactive elements for each of M channels, wherein N and M are greater than one, each of the N interactive elements being spaced along in each channel, respectively, and exposed to the fluid, each of the N interactive elements including an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element such that, when heated, each of the N interactive elements desorb selected constituents into the fluid to produce a corresponding concentration pulse that is carried by the fluid downstream toward a downstream interactive element;

exposing the N interactive elements of each channel to the fluid;

waiting for the N interactive elements of each channel to adsorb one or more constituents from the fluid; and

heating the N interactive elements of each channel in a time phased sequence whereby each of the downstream interactive elements is heated when the concentration pulse of the respective channel provided by one or more of the upstream interactive elements reaches the downstream interactive element.

27. A method according to claim 26, further comprising separating selected constituents of the concentration pulse provided by the one or more of the N interactive elements of each channel into individual components.

28. A method according to claim 27, further comprising sensing the concentration of individual components present in the concentration pulse provided by one or more of the N interactive elements of each channel.

29. A method for concentrating one or more constituents of a fluid that is flowing through each channel of a plurality of channels, each channel having an interactive substance provided therein, the interactive substance adsorbing and desorbing selected constituents of the fluid depending on the temperature of the interactive substance, the interactive substance having an upstream portion and a downstream portion, the method comprising:

waiting for the interactive substance of each channel of the plurality of channels to adsorb one or more constituents from the fluid;

heating the upstream portion of the interactive substance, causing the upstream portion to desorb selected constituents into the fluid to produce a first concentration pulse in the respective channel, the first concentration pulse is carried by the fluid downstream toward the downstream portion of the interactive substance; and

heating the downstream portion of the interactive substance when the first concentration pulse of the respective channel reaches the downstream portion, causing the downstream portion of the interactive substance to desorb selected constituents into the fluid and at least partially overlap the first concentration pulse to produce a second concentration pulse in the respective channel that is carried by the fluid downstream.

30. A concentrator for concentrating one or more constituents of a fluid, comprising:

a plurality of channels wherein each channel of said plurality has two or more interactive elements spaced along and exposed to the fluid, each of the interactive elements include an interactive substance that adsorbs and desorbs selected constituents of the fluid depending on the temperature of the interactive element, wherein at least two of the interactive elements are disposed within the fluid such that the sample fluid must pass by a first interactive element and then a second interactive element;

a plurality of heater elements, each heater element in thermal communication with a corresponding interactive element in each channel; and

a controller coupled to the plurality of heater elements for allowing the two or more interactive elements of each channel to become exposed to the fluid before energizing the heater elements in a time phased sequence.