Gelatinous elastomer

• US 6,797,765 B2
• Filed: 09/11/2001
• Issued: 09/28/2004
• Est. Priority Date: 02/14/1996
• Status: Expired due to Fees

• Current Assignee: Purple Innovation LLC (Global Partner Acquisition Corp.)
• Original Assignee: Edizone LC (Edizone)
• Inventors: Pearce, Tony M.
• Primary Examiner(s): Mulcahy, Peter D.
• Application Number:
  US09/952,035
• Publication Number:
  US 20030092826A1
• Time in Patent Office: 1,113 Days
• Field of Search: 524/505, 524/571, 524/575
• US Class Current: 524/505
• CPC Class Codes: A43B 13/04 Plastics, rubber or vulcanised fibre
• CPC Class Codes: B29C 44/583 for making articles with cavities
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/03 characterised by the shape of the extruded material at extrusion
• CPC Class Codes: C08K 5/0016 Plasticisers
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/006 grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified

Abstract

An improved gelatinous elastomer is disclosed which uses an A-B-A triblock copolymer having a molecular weight in the range of 125,000 to 175,000, or about 150,000, and a plasticizer.

Claims

1. An elastomeric material comprising:

a plasticizer selected from the group consisting of oils and polybutenes, and

a SEEPS triblock copolymer of the general configuration A-B-A;

wherein the plasticizer and copolymer are mixed to form a gel;

wherein A is selected from the group consisting of monoalkenylarene polymers;

wherein B is a hydrogenated polymer including a plurality of hydrogenated isoprene monomers and a plurality of hydrogenated butadiene monomers;

wherein said SEEPS triblock copolymer has a weight average molecular weight of about 125,000 to 175,000

wherein said SEEPS triblock copolymer has a solution viscosity of about 50 to about 150 cps @ 30 degrees C. when in a 7.5% solution in toluene;

wherein said plasticizer associates with said hydrogenated polymer B;

wherein said SEEPS triblock copolymer has a measurable percent elongation at break;

wherein said plasticizer tends to increase the percent elongation at break of said SEEPS triblock copolymer;

wherein said SEEPS triblock copolymer has a rigidity measurable on the Gram Bloom scale; and

wherein said plasticizer tends to decrease the Gram Bloom rigidity of said SEEPS triblock copolymer.

2. A material as recited in claim 1, wherein said gel has a ratio of oil to elastomer from about 1:

1 to about 8;

1.

3. A material as recited in claim 1, wherein the material can be readily pour-cast at about 375 degrees F. when melt blended in a 3:

1 ratio of said plasticizer to said SEEPS triblock copolymer.

4. An elastomeric material as recited in claim 1, wherein said plasticizer comprises a plurality of components;

wherein at least one of said components is a hydrocarbon resin; and

wherein at least one of said components is selected from the group consisting of naturally derived oils, synthetic oils, and liquid oligomers.

5. An elastomeric material as recited in claim 1, wherein said solution viscosity is about 95 to 115 cps.

6. An elastomeric material comprising:

a plasticizer and

a SEEPS triblock copolymer of the general configuration A-B-A and having a weight average molecular weight of from about 125,000 to 175,000;

wherein A is a non-elastomeric polymer and B is a hydrogenated polymer selected from the group consisting of ethylene/propylene, ethylene/butylene, and a combination thereof;

wherein the combined weights of said ethylene/propylene and said ethylene/butylene comprise more than about 50 weight percent of said hydrogenated polymer B;

wherein said plasticizer associates with said hydrogenated polymer B;

wherein said SEEPS triblock copolymer has a measurable percent elongation at break;

wherein said plasticizer tends to increase the percent elongation at break of said SEEPS triblock copolymer;

wherein said SEEPS triblock copolymer has a rigidity measurable on the Gram Bloom scale; and

wherein said plasticizer tends to decrease the Gram Bloom rigidity of said SEEPS triblock copolymer.

7. A material as recited in claim 6 wherein said plasticizer and said copolymer are mixed to form a gelatinous thermoplastic elastomer.

8. A material as recited in claim 7 wherein said gel has an oil to copolymer ratio of from about 1:

1 to about 8;

1.

9. A material as recited in claim 7 wherein the material can be readily pour-cast at about 375 degrees F. when melt blended in a 3:

1 ratio of said plasticizer to said SEEPS triblock copolymer.

10. A material as recited in claim 6 wherein said copolymer has a weight average molecular weight of about 150,000.

11. A material as recited in claim 6 wherein said plasticizer includes a polymer.

12. A material as recited in claim 7 further comprising a quantity of spherical objects.

13. A material as recited in claim 12 wherein said spherical objects are microspheres.

14. A material as recited in claim 6

wherein each of said mid block B is covalently linked to both of said end blocks A;

wherein said end blocks A are non-elastomeric polymers;

wherein said mid block B is an elastomeric polymer.

15. A material as recited in claim 6 further comprising an antioxidant.

16. A material as recited in claim 6,

wherein A is a polymer selected from the group consisting of monoalkenylarene polymers;

wherein B is a hydrogenated polymer comprising a plurality of covalently linked conjugated diene monomers; and

wherein at least one of said conjugated diene monomers is isoprene and at least one of said conjugated diene monomers is butadiene.

17. A material as recited in claim 16 wherein said plasticizer and said copolymer are mixed to form a gelatinous thermoplastic elastomer.

18. A material as recited in claim 17 wherein said gel has an oil to copolymer ratio of from about 1:

1 to about 8;

1.

19. A material as recited in claim 17 wherein the material can be readily pour-cast at about 375 degrees F. when melt blended in a 3:

1 ratio of said plasticizer to said SEEPS triblock copolymer.

20. A material as recited in claim 16 wherein said copolymer has a weight average molecular weight of about 150,000.

21. A material as recited in claim 16 wherein said plasticizer includes a polymer.

22. A material as recited in claim 17 further comprising a quantity of spherical objects.

23. A material as recited in claim 22 wherein said spherical objects are microspheres.

24. A material as recited in claim 16

wherein each of said mid block B is covalently linked to both of said end blocks A;

wherein said end blocks A are non-elastomeric polymers;

wherein said mid block B is an elastomeric polymer.

25. A material as recited in claim 16 further comprising an antioxidant.

26. A material as recited in claim 16, wherein the material has a durometer of about 15 Shore A or lower.

27. An elastomeric material comprising:

a SEEPS triblock copolymer elastomer of the configuration A-B-A and having a weight average molecular weight of from about 125,000 to 175,000, block A being a non-elastomeric polymer and block B being an elastomeric polymer, and

a plasticizer combined with said SEEPS triblock copolymer elastomer to form a visco-elastic material, said plasticizer being compatible with said B block.

28. A material as recited in claim 27 wherein said plasticizer and said elastomer are found in the material in a ratio of from about 1:

1 to about 8;

1.

29. A material as recited in claim 27, wherein the material has a short term degradation temperature of at least about 375 degrees F.;

and wherein said copolymer has a solution viscosity of about 104 cps @ 30 degrees C. when in a 7.5% solution in toluene.