Castings of metallic alloys with improved surface quality, structural integrity and mechanical properties fabricated in finegrained isotropic graphite molds under vacuum

• US 6,799,626 B2
• Filed: 05/14/2002
• Issued: 10/05/2004
• Est. Priority Date: 05/15/2001
• Status: Expired due to Term

• Current Assignee: Santoku Corporation (Proterial Ltd.)
• Original Assignee: Santoku America, Inc. (Oaktree Capital Management LP)
• Inventors: Ray, Ranjan, Scott, Donald W.
• Primary Examiner(s): Elve, M. Alexandra
• Assistant Examiner(s): LIN, ING HOUR
• Application Number:
  US10/143,920
• Publication Number:
  US 20040003913A1
• Time in Patent Office: 875 Days
• Field of Search: 164/529, 164/519, 164/418, 164/459, 164/72, 164/268, 106/38.2, 106/38.27, 106/38.9, 427/228
• US Class Current: 164/529
• CPC Class Codes: B22C 1/00 Compositions of refractory mould or core materials; Grain structures thereof refractory materials in general C04B35/00; Chemical or physical features in the formation or manufacture of moulds
• CPC Class Codes: B22C 9/061 Materials which make up the mould
• CPC Class Codes: B22D 27/04 Influencing the temperature of the metal, e.g. by heating or cooling the mould
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22C 19/051 and Mo or W
• CPC Class Codes: C22C 19/055 with the maximum Cr content being at least 20% but less than 30%
• CPC Class Codes: C22C 19/056 with the maximum Cr content being at least 10% but less than 20%
• CPC Class Codes: C22C 19/057 with the maximum Cr content being less 10%
• CPC Class Codes: C22C 19/07 based on cobalt
• CPC Class Codes: C22C 30/00 Alloys containing less than 50% by weight of each constituent
• CPC Class Codes: C22C 38/40 with nickel

Abstract

Methods for making various metallic alloys such as nickel, cobalt and/or iron based superalloys, stainless steel alloys, titanium alloys and titanium aluminide alloys into engineering components by melting of the alloys in a vacuum or under a low partial pressure of inert gas and subsequent casting of the melt in the graphite molds under vacuum or low partial pressure of inert gas are provided, the molds having been fabricated by machining high density, high strength ultrafine grained isotropic graphite, wherein the graphite has been made by isostatic pressing or vibrational molding.

Claims

1. A method of making cast shapes of a metallic alloy, comprising the steps of:

melting the alloy under vacuum or partial pressure of inert gas;

pouring the alloy into a mold with a cavity, wherein the mold is made of machined graphite, wherein the graphite has been isostatically or vibrationally molded and has ultra fine isotropic grains having a particle size in the range of 3 to 40 microns, a density between 1.65 and 1.9 grams/cc, flexural strength between 5,500 and 20,000 psi, compressive strength between 9,000 and 35,000 psi, and porosity below 15%;

solidifying the melted alloy into a solid body taking the shape of the mold cavity.

2. The method of claim 1, wherein the mold has a temperature between 100 and 800°

C. when the alloy is poured into the mold.

3. The method of claim 1, wherein the mold has a temperature between 150 and 800°

C. when the alloy is poured into the mold.

4. The method of claim 1, wherein the mold has a temperature between 200 and 800°

C. when the alloy is poured into the mold.

5. The method of claim 1, wherein the mold has a temperature between 150 and 450°

C. when the alloy is poured into the mold.

6. The method of claim 1, wherein the mold has a temperature between 250 and 450°

C. when the alloy is poured into the mold.

7. The method of claim 1, wherein the metallic alloy is a nickel base superalloy, nickel-iron base superalloy and cobalt base superalloy.

8. The method of claim 1, wherein the metallic alloy is a nickel base superalloy containing 10-20% Cr, up to about 8% Al and/or Ti, and one or more elements in 0.1-12% total such as B, C and/or Zr, as well as 0.1-12% total of one or more alloying elements such as Mo, Nb, W, Ta, Co, Re, Hf, and Fe, and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

9. The method of claim 1, wherein the metallic alloy is a cobalt base superalloys containing 10-30% Cr, 5-25% Ni and 2-15% W and 0.1-12% total of one or more other elements such as Al, Ti, Nb, Mo, Fe, C, Hf, Ta, and Zr, and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

10. The method of claim 1, wherein the metallic alloy is a nickel-iron base superalloy containing 25-45% Ni, 37-64% Fe, 10-15% Cr, 0.5-3% Al and/or Ti, and 0.1-12% total of one or more elements selected from the group consisting of B, C, Mo, Nb, and W, as well as inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

11. The method of claim 1, wherein the metallic alloy is a stainless steel alloy based on Fe, containing 10-30% Cr and 5-25% Ni, and small amounts (0.1-12% ) of one or more other elements such as Mo, Ta, W, Ti, Al, Hf, Zr, Re, C, B and V, and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

12. The method of claim 1, wherein the metallic alloy is based on titanium and contains at least about 50% Ti and at least one other element selected from the group consisting of Al, V, Cr, Mo, Sn, Si, Zr, Cu, C, B, Fe and Mo, and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

13. The method of claim 1, wherein the metallic alloy is titanium aluminide based on titanium and aluminum and containing 50-85% titanium, 15-36% Al, and at least one other element selected from the group consisting of Cr, Nb, V, Mo, Si and Zr and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

14. The method of claim 1, wherein the metallic alloy containing at least 50% zirconium and at least one other element selected from the group consisting of Al, V, Mo, Sn, Si, Ti, Hf, Cu, C, Fe and Mo and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

15. The method of claim 1, wherein the metallic alloy is nickel aluminide containing at least 50% nickel, 20-40% Al and optionally at least one other element selected from the group consisting of V, Si, Zr, Cu, C, Fe and Mo and inevitable impurity elements, wherein the impurity elements are less than 0.05% each and less than 0.15% total.

16. The method of claim 1, wherein the alloy is melted by a method selected from the group consisting of vacuum induction melting and plasma arc remelting.

17. The method of claim 1, wherein the mold has been isostatically molded.

18. The method of claim 17, wherein the graphite of the mold has isotropic grains with grain size between 3 and 10 microns, and the mold has flexural strength of 7,000 to 20,000 psi, compressive strength between 12,000 and 35,000 psi, and porosity below 13%.

19. The method of claim 17, wherein the mold has a density between 1.77 and 1.9 grams/cc and compressive strength between 17,000 psi and 35,000.

20. The method of claim 17, wherein the mold comprises copper impregnated graphite.

21. The method of claim 1, wherein the mold has been vibrationally molded.

22. The method of claim 1, wherein the mold has a SiC coating defining the cavity.