Method of manufacturing window using ion beam milling of glass substrate(s)
First Claim
1. A method of making a window including at least one glass substrate, the method comprising:
- providing a first glass substrate;
ion beam treating a surface of the first glass substrate with an ion beam comprising at least fluorine (F) ions thereby forming an ion beam treated surface of the first glass substrate; and
following said ion beam treating, sputtering a coating including at least one infrared (IR) reflecting layer on the ion beam treated surface of the first glass substrate.
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Accused Products
Abstract
This invention relates to a method of making a window (e.g., vehicle windshield, architectural window, etc.), and the resulting window product. At least one glass substrate of the window is ion beam treated and/or milled prior to application of a coating (e.g., sputter coated coating) over the treated/milled substrate surface and/or prior to heat treatment. As a result, defects in the resulting window and/or haze may be reduced. The ion beam used in certain embodiments may be diffused. In certain embodiments, the ion beam treating and/or milling is carried out using a fluorine (F) inclusive gas(es) and/or argon/oxygen gas(es) at the ion source(s). In certain optional embodiments, F may be subimplanted into to treated/milled glass surface for the purpose of reducing Na migration to the glass surface during heat treatment or thereafter, thereby enabling corrosion and/or stains to be reduced for long periods of time.
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Citations
51 Claims
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1. A method of making a window including at least one glass substrate, the method comprising:
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providing a first glass substrate;
ion beam treating a surface of the first glass substrate with an ion beam comprising at least fluorine (F) ions thereby forming an ion beam treated surface of the first glass substrate; and
following said ion beam treating, sputtering a coating including at least one infrared (IR) reflecting layer on the ion beam treated surface of the first glass substrate. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18)
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10. The method of claim 1, wherein the coating has a sheet resistance (Rs) of less than or equal to 10 ohms/sq.
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11. The method of claim 10, wherein the coating has a sheet resistance (Rs) of less than or equal to 5 ohms/sq.
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12. The method of claim 1, further comprising making the first glass substrate via a float process so as to include sodium (Na) and utilizing a tin bath so as to cause the first glass substrate to have a tin surface and a non-tin surface, and wherein the ion beam treating is performed on the non-tin surface of the first glass substrate.
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13. The method of claim 1, further comprising:
- after said sputtering, heat treating the first glass substrate with the coating thereon so as to temper and/or bend the first glass substrate.
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14. The method of claim 2, wherein the ion beam milling reduces haze in the windshield by at least about 20%.
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15. The method of claim 2, wherein the ion beam milling comprises directing the ion beam at the surface of the first glass substrate so that the ion beam is incident upon the surface of the first glass substrate so as to form an angle θ
- with the first glass substrate of from 20-70 degrees.
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16. The method of claim 2, wherein the ion beam milling comprises directing an ion beam at the first glass substrate so that the ion beam is incident upon the first substrate in order to form an angle θ
- with the first glass substrate of from 30-60 degrees.
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17. The method of claim 1, wherein the ion beam treating comprises generating and directing the ion beam comprising at least fluorine (F) ions toward the first glass substrate in a manner so that F ions and/or molecules is/are subimplanted into the glass substrate.
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18. The method of claim 1, wherein said ion beam treating comprises generating an ion beam including each of argon, oxygen and fluorine ions, and directing the ion beam including the argon, oxygen and fluorine ions toward the surface of the first glass substrate.
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19. A method of making a window including at least one glass substrate, the method comprising:
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providing a first glass substrate;
ion beam milling a surface of the first glass substrate with an ion beam comprising at least ions of a Group VII A element so as to remove at least 2 Å
of glass from the first glass substrate thereby forming an ion beam milled surface of the first glass substrate; and
following said ion beam milling, forming a coating on the ion beam milled surface of the first glass substrate. - View Dependent Claims (20, 41, 42)
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21. A method of making a window comprising:
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providing a first glass substrate;
ion beam milling a surface of the first glass substrate with an ion beam comprising at least argon and oxygen ions so as to remove at least 2 Å
of glass from at least a portion of the first glass substrate thereby forming an ion beam milled surface of the first glass substrate; and
following said ion beam milling, sputtering a coating including at least one infrared (IR) reflecting layer on the ion beam milled surface of the first glass substrate. - View Dependent Claims (22, 23, 24, 43)
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25. A method of making a window, the method comprising:
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providing first and second glass substrates;
ion beam milling at least one surface of the first glass substrate using an ion beam comprising argon and fluorine ions so as to remove at least 2 Å
of glass from at least a portion of the first glass substrate and form an ion beam milled surface of the first glass substrate,forming a coating on the ion beam milled surface of the first substrate; and
coupling the first glass substrate with the coating thereon to the second glass substrate so that the coating is provided between the first and second glass substrates. - View Dependent Claims (26, 27, 28, 29, 30, 31, 32)
a first dielectric layer provided between the first substrate and the first layer comprising Ag, a second dielectric layer between the first and second layers comprising Ag, and a third dielectric layer between the second layer comprising Ag and a polymer inclusive interlayer that laminates the first and second substrates to one another.
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29. The method of claim 25, wherein said ion beam milling removes at least 5 Å
- of glass from the first glass substrate.
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30. The method of claim 25, wherein said ion beam milling removes from 10-100 Å
- of glass from the first glass substrate.
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31. The method of claim 25, wherein the window has a visible transmittance of at least 70%.
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32. The method of claim 25, wherein the window has haze of <
- =0.4.
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33. A method of making a window including at least one glass substrate, the method comprising:
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providing a first glass substrate;
ion beam milling a surface of the first glass substrate with a diffused ion beam so as to remove at least 2 Å
of glass from at least a portion thereby forming an ion beam milled surface of the first glass substrate; and
following said ion beam milling, forming a coating including at least one infrared (IR) reflecting layer on the ion beam milled surface of the first glass substrate. - View Dependent Claims (34, 35, 36, 37)
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38. A method of making a window comprising:
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providing a first glass substrate;
ion beam milling a surface of the first glass substrate with an ion beam comprising at least oxygen ions so as to remove at least 2 Å
of glass from at least a portion of the first glass substrate thereby forming an ion beam milled surface of the first glass substrate; and
following said ion beam milling, sputtering a coating including at least one infrared (IR) reflecting layer on the ion beam milled surface of the first glass substrate. - View Dependent Claims (39, 40)
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44. A method of making a coated article, the method comprising:
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providing a first glass substrate;
ion beam milling a surface of the first glass substrate with an ion beam so as to remove at least 5 Å
of glass from at least a portion of the first glass substrate thereby forming an ion beam milled surface of the first glass substrate; and
following said ion beam milling, sputtering a coating onto the ion beam milled surface of the first glass substrate, wherein the coating comprises at least the following layers from the first glass substrate outwardly;
a first dielectric layer;
a first IR reflecting layer comprising silver;
a second dielectric layer;
a second IR reflecting layer comprising silver; and
a third dielectric layer; and
wherein the coating has a sheet resistance of less than or equal to 10 ohms/square. - View Dependent Claims (45, 46, 47, 48, 49, 50, 51)
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Specification