Chemical sensing apparatus and methods

• US 6,808,618 B2
• Filed: 07/25/2001
• Issued: 10/26/2004
• Est. Priority Date: 07/25/2001
• Status: Expired due to Term

• Current Assignee: Sensirion AG (Sensirion Holding AG)
• Original Assignee: Joseph Robert Stetter
• Inventors: Stetter, Joseph Robert
• Primary Examiner(s): Olsen, Kaj K.
• Application Number:
  US09/915,166
• Publication Number:
  US 20030024814A1
• Time in Patent Office: 1,189 Days
• Field of Search: 204/412, 204/415, 204/431, 204/432, 205/778.5, 205/779, 205/779.5, 205/780, 205/781, 205/782, 205/782.5, 205/783
• US Class Current: 205/779.5
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 27/44 using electrolysis to generate a reagent, e.g. for titration

Abstract

In an improved amperometric gas sensor, the structure, composition, and electrode potential are adjusted so as to prevent or minimize any unwanted reactivity at the counter and/or reference electrode of any analyte or interfering component of the matrix that may cross over thereto. The sensor is preferably structured so that the product of the analyte reaction at a first working electrode can be reconverted to the original analyte at a counter electrode or at a second working electrode and then reacted again at the first working electrode, with such back-and-forth reactions repeating many times, so as to yield an amplification of the analyte signal.

Claims

1. Amperometric sensing apparatus for detecting an analyte in a gaseous medium, winch comprises:

a working electrode at which said analyte is caused to participate in an analyte half-cell reaction;

a reference electrode for controlling the electrochemical potential of said working electrode;

a counter electrode at which a complementary half-cell reaction is caused to occur, wherein all three electrodes are electrochemically connected through an electrolyte and said counter and reference electrodes may be combined into a single electrode;

means of enhancing the reactivity of the counter electrode to the product of the analyte reaction; and

means for reconverting the product of the analyte reaction back to the analyte and then reacting it again at the working electrode, with such back-and-forth reactions repeating many times, so as to yield an amplification of the analyte signal.

2. The apparatus of claim 1, wherein said reconversions are caused to occur at the counter electrode.

3. The apparatus of claim 2, wherein said sensing apparatus is designed or tuned for reconversion and detection of the NO-NO₂ or Cl-Cl₂ redox couple.

4. The apparatus of claim 2, wherein said working and counter electrodes are interdigitated or comprise an array of electrodes which are addressable in subsets.

5. Amperometric sensing apparatus for detecting an analyte in a gaseous medium, which comprises:

a first working electrode at which said analyte is caused to participate in an analyte half-cell reaction; and

a second working electrode for reconverting tho product of the analyte reaction back to the analyte; and

means for reacting said product again at the first working electrode, with such back-and-forth reactions repeating many times, so as to yield an amplification of the analyte signal,

each of said working electrodes being electrochemically connected to its respective pair of counter and reference electrodes;

wherein each of said pairs of counter and reference electrodes may be combined into a single electrode.

6. The apparatus of claim 5, wherein the first of said working electrodes is designed or tuned for detection of NO or Cl species, with the second working electrode optimized for detection or identification of the corresponding oxidizing species, NO₂ or Cl₂.

7. The apparatus of claim 5, wherein said working electrodes are interdigitated.

8. A method of detecting the presence of an analyte or trace thereof in a gaseous medium comprising the steps of:

passing a sample of said gaseous medium over a pair of interdigitated electrodes forming part of an amperometric gas sensor system, while applying an oxidizing potential to one electrode of said pair and a reducing potential to the other electrode of said pair, so as to cause repeated oxidations and reductions of said analyte and of its redox product and thereby produce amplified current signals due to said analyte and product;

measuring said amplified current signals; and

deducing the presence or identity or concentration of said analyte in said gaseous medium from said measured current signals.

9. The method of claim 8, wherein said analyte and product comprise the NO-NO₂ or Cl-Cl₂ redox couple.

10. Sensing apparatus for detecting an analyte in a gaseous medium, which comprises:

means for passing a sample of said gaseous medium over a pair of interdigitated electrodes forming part of an amperometric gas sensor system, while applying an oxidizing potential to one electrode of said pair and a reducing potential to the other electrode of said pair, so as to cause repeated oxidations and reductions of said analyte and of its redox product and thereby produce amplified current signals due to said analyte and product; and

means for measuring said amplified current signals.

11. The apparatus of claim 10, wherein said gaseous medium may be separated from said electrodes solely by a thin layer of electrolyte.

12. The apparatus of claim 10, comprising more than one of said pairs or an array of electrode pairs that are addressable individually or in subsets, each of which can perform oxidation-reduction reactions for a different analyte.

13. The apparatus of claim 10, comprising counter and reference electrodes that are inaccessible to or inactive towards said analyte.

14. The apparatus of claim 10, comprising means for deducing from said amplified signals the identity or concentration of said analyte.

15. The apparatus of claim 10, wherein both of said respective pairs of counter and reference electrodes are substantially identical or similar.

16. The apparatus of claim 10, wherein said counter and reference electrodes are inaccessible to or inactive towards said analyte.