Liquid center for golf balls

• US 6,811,497 B1
• Filed: 12/03/1999
• Issued: 11/02/2004
• Est. Priority Date: 01/24/1995
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali, Jones, Douglas E.
• Primary Examiner(s): Gorden, Raeann
• Application Number:
  US09/453,697
• Time in Patent Office: 1,796 Days
• Field of Search: 473/376-378, 473/373-374, 473/371, 473/361, 473/367, 473/351, 473/357, 473/354, 473/356
• US Class Current: 473/376
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0062 Hardness
• CPC Class Codes: A63B 37/0066 Density; Specific gravity
• CPC Class Codes: A63B 37/0069 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0093 Moisture vapour transmission rate [MVTR]
• CPC Class Codes: A63B 37/04 Rigid cores
• CPC Class Codes: A63B 37/12 Special coverings , i.e. outer layer material balls with finger holes A63B37/0001, golf ball covers A63B37/0023
• CPC Class Codes: C08L 23/04 Homopolymers or copolymers of ethene
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 2314/06 Metallocene or single site catalysts
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: H04B 1/005 adapting radio receivers, transmitters andtransceivers for operation on two or more bands, i.e. frequency ranges
• CPC Class Codes: H04B 1/006 using switches for selecting the desired band H04B1/0057 takes precedence

Abstract

The present invention is directed toward golf balls with improved resistance to water permeation. These golf balls comprise cover, core and, optionally, intermediate layers, with at least one of these layers including a polymer blend that provides resistance to water permeation through that layer. The polymer blends that provide the disclosed resistance to water permeation comprise at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer. Most importantly, the golf balls formed with the polymer blends of the present invention also exhibit essentially unchanged physical and performance characteristics including coefficient of restitution, compression and initial velocity.

Claims

1. A golf ball comprising a fluid-filled center, a cover, and at least one intermediate layer interposed between the center and the cover, wherein the fluid-filled center comprises a center shell, said center shell formed from a composition comprising a blend of at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer.

2. The golf ball of claim 1 wherein the intermediate layer comprises at least one layer of tensioned elastomeric windings surrounding said fluid-filled center.

3. The golf ball of claim 1 wherein said composition comprises a blend of at least on polyether-amide block copolymer or a polyether-ester block copolymer, and a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and octene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and hexene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and butene or a blend of said metallocene-catalyzed copolymers.

4. The golf ball of claim 1 wherein the center shell has a hardness of about 30 to about 80 Shore C, a flexural modulus of about 500 psi to about 70,000 psi and a specific gravity of about 0.8 to about 2.5.

5. The golf ball of claim 4 wherein the center shell has a hardness of about 50 to about 65 Shore C, a flexural modulus of about 3000 psi to about 20,000 psi and a specific gravity of about 1.3 to about 2.0.

6. The golf ball of claim 5 wherein the center shell has a specific gravity of about 1.5 to about 1.9.

7. The golf ball of claim 1 wherein the hydrophilic thermoplastic polymer is a hydrophilic thermoplastic elastomer.

8. The golf ball of claim 1 wherein the hydrophobic thermoplastic polymer is compatible with the hydrophilic thermoplastic polymer.

9. The golf ball of claim 1 wherein said cover is formed from a polyurethane composition.

10. The golf ball of claim 9 wherein said polyurethane composition comprises at least one polyurethane prepolymer formed as a reaction product of either 4,4′

-diphenyl methane diisocyanate or 3,3′

-dimethyl-4,4′

-biphenyl diisocyanate and at least one polyol, wherein the polyurethane composition is cured with at least one polyamine selected from the group consisting of 3,5-dimethylthio-2,4-toluenediamine;

3,5-dimethylthio-2,6-toluenediamine;

N,N′

-dialkyl diamino diphenyl methane;

trimethylene glycol-di-p-aminobenzoate;

polytetramethyleneoxide-di-p-aminobenzoate and mixtures thereof.

11. The golf ball of claim 10 wherein the polyol is selected from the group consisting of polytetramethylene ether glycol;

polyoxypropylene glycol;

polybutadiene glycol;

partially or fully hydrogenated polybutadiene glycol;

1,4-butanediol initiated caprolactone;

diethylene glycol initiated caprolactone;

trimethylol propane initiated caprolactone;

neopentyl glycol initiated caprolactone;

polyethylene adipate glycol;

polyethylene propylene adipate glycol; and

polybutylene adipate glycol; and

mixtures thereof.

12. The golf ball of claim 1 wherein said at least one intermediate layer is formed by compression molding, injection molding, casting, dipping, or spraying.

40. The golf ball of claim 1, wherein the at least one hydrophobic polymer is selected from the group consisting of ethylene-glycidyl acrylate copolymers, ethylene-glycidyl methacrylate copolymers, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and octene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and hexene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and butene, ethylene-n-butyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-acrylic acid ionomers, ethylene-n-butyl acrylate-methacrylic acid ionomers, and mixtures thereof.

41. The golf ball of claim 1, wherein the golf ball has less than 0.4 grams weight loss.

13. A golf ball comprising a cover, a core, and at least one optional intermediate layer, wherein the core comprises a plurality of layers, and wherein at least one of said plurality of layers comprises a blend of at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer, wherein said blend provides improved resistance to water permeation through said at least one layer.

14. The golf ball of claim 13, wherein the at least one hydrophilic thermoplastic polymer is a homopolymer, a copolymer, a terpolymer, a block copolymer, a graft copolymer, or a mixture thereof.

15. The golf ball of claim 13, wherein the at least one hydrophobic polymer is a homopolymer, a copolymer, a terpolymer, a block copolymer, a graft copolymer, or a mixture thereof.

16. The golf ball of claim 13, wherein the at least one hydrophilic thermoplastic polymer is selected from the group consisting of polyether-ester block copolymers, polyester-ester block copolymer, polyether-amide block copolymers, polyester-amide block copolymers, thermoplastic urethanes, and blends thereof.

17. The golf ball of claim 13, wherein the at least one hydrophobic polymer is selected from the group consisting of ethylene-glycidyl acrylate copolymers, ethylene-glycidyl methacrylate copolymers, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and octene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and hexene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and butene, ethylene-n-butyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-acrylic acid ionomers, ethylene-n-butyl acrylate-methacrylic acid ionomers, and mixtures thereof.

18. The golf ball of claim 13, wherein the at least one hydrophilic thermoplastic polymer is at least one of a polyether-amide block copolymer or a polyether-ester block copolymer, and the at least one hydrophobic polymer is at least one of a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and octene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and hexene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and butene or a blend of said metallocene-catalyzed copolymers.

19. The golf ball of claim 13, wherein the composition comprises from about 99% to about 1% of the hydrophilic thermoplastic polymer, by weight, and from about 1% to about 99% of the hydrophobic polymer, by weight.

20. The golf ball of claim 13, wherein the intermediate layer is present, and wherein said intermediate layer comprises a blend of at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer, said blend providing improved resistance to water permeation.

21. The golf ball of claim 13, wherein the hydrophobic polymer is compatible with the hydrophilic thermoplastic polymer.

42. The golf ball claim 13, wherein the golf ball has less than 0.4 grams weight loss.

22. A golf ball comprising a cover, a center and an intermediate layer, wherein the intermediate layer is disposed concentrically between the center and the cover, wherein the center and the intermediate layer comprise a plurality of layers, and wherein at least one of the plurality of layers comprises a blend of at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer, the blend providing resistance to water permeation.

23. The golf ball of claim 22, wherein the cover is formed from a thermoplastic or castable polyurethane.

24. The golf ball of claim 22, wherein the center is a fluid-filled center comprising a center shell, wherein the center shell comprises a blend of at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer.

25. The golf ball of claim 24, wherein the plurality of layers comprises at least one layer of tensioned elastomeric windings surrounding said center shell.

26. The golf ball of claim 22, wherein the at least one hydrophilic thermoplastic polymer is a homopolymer, a copolymer, a terpolymer, a block copolymer, a graft polymer, or a mixture thereof.

27. The golf ball of claim 22, wherein the at least one hydrophobic polymer is a homopolymer, a copolymer, a terpolymer, a block copolymer, a graft polymer, or a mixture thereof.

28. The golf ball of claim 22, wherein the at least one hydrophilic thermoplastic polymer is selected from the group consisting of polyether-ester block copolymers, polyester-ester block copolymers, polyether-amide block copolymers, polyester-amide block copolymers, thermoplastic urethanes, and blends thereof.

29. The golf ball of claim 22, wherein the at least one hydrophobic polymer is selected from the group consisting of ethylene-glycidyl acrylate copolymers, ethylene-glycidyl methacrylate copolymers, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and octene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and hexene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and butene, ethylene-n-butyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-acrylic acid ionomers, ethylene-n-butyl acrylate-methacrylic acid ionomers, and mixtures thereof.

30. The golf ball of claim 22, wherein the at least one hydrophilic thermoplastic polymer is at least one of a polyether-amide block copolymer or a polyether-ester block copolymer, and the at least one hydrophobic polymer is at least one of a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and octene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and hexene, a maleic anhydride grafted metallocene-catalyzed copolymer of ethylene and butene, or a mixture thereof.

31. The golf ball of claim 22, wherein the blend comprises from about 99% to about 1% of the hydrophilic thermoplastic polymer, by weight, and from about 1% to about 99% of the hydrophobic polymer, by weight.

32. The golf ball of claim 22, wherein the hydrophobic thermoplastic polymer is compatible with the hydrophilic thermoplastic polymer.

43. The golf ball of claim 22, wherein the golf ball has less than 0.4 grams weight loss.

33. A method of making a golf ball, comprising the steps of:

preparing a blend comprising at least one hydrophilic thermoplastic polymer and at least one hydrophobic polymer; and

forming a core, an intermediate layer, and a cover, wherein the intermediate layer and cover comprise a plurality of layers, and wherein at least one layer of the intermediate layer and the cover is formed from the blend.

34. The method of claim 33, wherein the core comprises a plurality of layers.

35. The method of claim 34, wherein said core comprises a plurality of layers and wherein at least one said core layer is formed of said blend.

36. The method of claim 33, wherein the hydrophobic polymer is compatible with the hydrophilic thermoplastic polymer.

37. The method of claim 33, further comprising the steps of:

c) forming a hollow center shell from said blend;

d) filling the hollow center shell with a fluid, thereby providing a fluid-filled center;

e) forming said intermediate layer around the fluid-filled center, thereby providing a core; and

f) encasing the core in a cover.

38. The method of claim 37, wherein at least one layer of the intermediate layer is formed by wrapping the fluid-filled center with an elastic thread.

39. The method of claim 37, wherein at least one layer of the intermediate layer is a solid, non-wound layer.

44. The method of claim 33, wherein the golf ball has less than 0.4 grams weight loss.

45. The method of claim 33, wherein the at least one hydrophilic thermoplastic polymer is a homopolymer, a copolymer, a terpolymer, a block copolymer, a graft polymer, or a mixture thereof and the at least one hydrophobic polymer is selected from the group consisting of ethylene-glycidyl acrylate copolymers, ethylene-glycidyl methacrylate copolymers, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and octene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and hexene, maleic anhydride grafted metallocene-catalyzed copolymers of ethylene and butene, ethylene-n-butyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl acrylate terpolymers, ethylene-methyl acrylate-glycidyl methacrylate terpolymers, ethylene-n-butyl acrylate-acrylic acid ionomers, ethylene-n-butyl acrylate-methacrylic acid ionomers, and mixtures thereof.