Antireflection film

• US 6,815,056 B2
• Filed: 09/23/2002
• Issued: 11/09/2004
• Est. Priority Date: 02/19/1998
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Jones, Robert L., Smyth, William K., Wang, Xiaojia Z., Nagarkar, Pradnya V., Choi, Hyung-Chul
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): BLACKWELL, GWENDOLYN
• Application Number:
  US10/252,257
• Publication Number:
  US 20030021972A1
• Time in Patent Office: 778 Days
• Field of Search: 428/212, 428/220, 428/156, 428/332, 428/339, 428/341, 428/426, 428/432, 428/699, 428/701, 428/702
• US Class Current: 428/339
• CPC Class Codes: C08L 27/12 containing fluorine atoms
• CPC Class Codes: C08L 33/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C08L 33/10 Homopolymers or copolymers of methacrylic acid esters
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 1/105 Protective coatings
• CPC Class Codes: G02B 1/113 using inorganic layer materials only
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 27/0006 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation G02B1/18 takes precedence; cleaning in general B08B
• CPC Class Codes: G06F 3/041 Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component

Abstract

An antireflection coating comprises one or more inorganic antireflection layers (typically metal oxide or silica layers) and a polymer layer cured in situ, the polymer layer having a refractive index not greater than about 1.53 over the wavelength range of 400 to 700 nm and a thickness of from about 20 to about 200 nm. The polymer layer provides good scratch and fingerprint protection, and also enables the thicknesses of the inorganic antireflection layers to be reduced, thereby reducing the cost of the coating.

Claims

1. An article having an antireflection film, the article comprising a substrate carrying an inorganic antireflection layer and, in contact with the inorganic antireflection layer and forming the outer surface of the antireflection film, an optically active polymer layer formed by curing a curable composition in situ on the inorganic antireflection layer, the polymer layer having a refractive index not greater than approximately 1.53 over the wavelength range of 400 to 700 nm and a thickness of from approximately 50 to approximately 200 nm.

2. An article according to claim 1 wherein the inorganic antireflection layer is formed from a metal oxide.

3. An article according to claim 2 wherein the metal oxide layer comprises at least one of indium oxide, titanium dioxide, cadmium oxide, gallium indium oxide, niobium pentoxide, indium tin oxide and tin dioxide.

4. An article according to claim 3 wherein the metal oxide layer has a thickness of from approximately 10 to approximately 30 nm and the polymer layer has a thickness of from approximately 80 to approximately 150 nm.

5. An article according to claim 4 wherein the metal oxide layer has a thickness of from approximately 17 to approximately 23 nm and the polymer layer has a thickness of from approximately 110 to approximately 130 nm.

6. An article according to claim 2 comprising a first metal oxide layer carried by the substrate;

a silica layer superposed on the first metal oxide layer; and

a second metal oxide layer superposed on the silica layer, the polymer layer being superposed on the second metal oxide layer.

7. An article according to claim 6 wherein the first metal oxide layer has a thickness of from approximately 20 to approximately 35 nm, the silica layer has a thickness of from approximately 10 to approximately 25 nm, the second metal oxide layer has a thickness of from approximately 50 to approximately 100 nm and the polymer layer has a thickness of from approximately 70 to approximately 120 nm.

8. An article according to claim 7 wherein the first metal oxide layer has a thickness of from approximately 25 to approximately 30 nm, the silica layer has a thickness of from approximately 15 to approximately 20 nm, the second metal oxide layer has a thickness of from approximately 65 to approximately 80 nm and the polymer layer has a thickness of from approximately 85 to approximately 100 nm.

9. An article according to claim 1 wherein the inorganic antireflection layer is formed from silica.

10. An article according to claim 1 wherein the inorganic antireflection layer comprises a metal oxide layer carried by the substrate and a silica layer superposed on the metal oxide layer, the polymer layer being superposed on the silica layer.

11. An article according to claim 10 wherein the metal oxide layer has a thickness of from approximately 10 to approximately 30 nm, the silica layer has a thickness of from approximately 10 to approximately 120 nm, and the polymer layer has a thickness of from approximately 50 to approximately 130 nm.

12. An article according to claim 11 wherein the metal oxide layer has a thickness of from approximately 10 to approximately 20 nm, the silica layer has a thickness of from approximately 10 to approximately 50 nm, and the polymer layer has a thickness of from approximately 60 to approximately 100 nm.

13. An article according to claim 1 wherein the polymer layer has a refractive index not greater than approximately 1.50 over the wavelength range of 400 to 700 nm.

14. An article according to claim 1 wherein the polymer layer comprises repeating units derived from a fluoroalkene.

15. An article according to claim 1 wherein the polymer layer comprises repeating units derived from an alkyl acrylate or methacrylate.

16. An article according to claim 1 wherein the polymer layer comprises repeating units derived from a polyfunctional acrylate monomer.

18. An article according to claim 1 further comprising a hard coat disposed between the substrate and the inorganic antireflection layer.

17. An article having an antireflection film, the article comprising a substrate carrying an inorganic antireflection layer and, in contact with the inorganic antireflection layer and forming the outer surface of the antireflection film, an optically active polymer layer formed by curing a curable composition in situ on the inorganic antireflection layer, the polymer layer having a refractive index not greater than approximately 1.53 over the wavelength range of 400 to 700 nm and a thickness of from approximately 20 to approximately 200 nm, the polymer layer comprising repeating units derived from a fluoroalkene and repeating units derived from an alkyl acrylate or methacrylate, the polymer layer having an outer portion enriched in the alkyl acrylate or methacrylate and an inner portion enriched in the fluoroalkene.