Polymers for control of orientation and stability of liquid crystals

• US 6,821,455 B2
• Filed: 04/05/2001
• Issued: 11/23/2004
• Est. Priority Date: 04/05/2000
• Status: Expired due to Fees

• Current Assignee: California Institute of Technology
• Original Assignee: California Institute of Technology
• Inventors: Kempe, Michael D., Kornfield, Julia A.
• Primary Examiner(s): Wu, Shean C.
• Assistant Examiner(s): Sadula, Jennifer R.
• Application Number:
  US09/828,304
• Publication Number:
  US 20020001052A1
• Time in Patent Office: 1,328 Days
• Field of Search: 428/1.1, 349/183, 349/88, 349/86, 252/299.01
• US Class Current: 252/299.01
• CPC Class Codes: C09K 19/542 Macromolecular compounds
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: G02F 1/133703 by introducing organic surfactant additives into the liquid crystal material
• CPC Class Codes: G02F 1/13775 Polymer-stabilized liquid crystal layers

Abstract

An electro-optically active polymer gel material comprising a high molecular weight alignment polymer adapted to be homogeneously dispersed throughout a liquid crystal to control the alignment of the liquid crystal molecules and/or confer mechanical stability is provided. The electro-optically active polymer gel comprises a homogenous gel in which the polymer strands of the gel are provided in low concentration and are well solvated by the small molecule liquid crystal without producing unacceptable slowing of its electrooptic response. During formation of the gel, a desired orientation is locked into the gel by physical or chemical cross-linking of the polymer chains. The electro-optically active polymer is then utilized to direct the orientation in the liquid crystal gel in the “field off” state of a liquid crystal display. The electro-optically active polymer also provides a memory of the mesostructural arrangement of the liquid crystal and acts to suppress the formation of large scale deviations, such as, for example, fan-type defects in a FLC when subjected to a mechanical shock. A method of making an electro-optically active polymer gel material and an electrooptic device utilizing the electro-optically active polymer gel of the present invention is also provided.

Claims

1. An electro-optically active gel layer having nematic, ferroelectric, antiferroelectric or electroclinic properties comprising a plurality of aligned liquid crystal molecules and an anisotropic three-dimensional polymer network comprising a plurality of sparsely cross-linked polymer molecules, wherein the anisotropic three-dimensional polymer network is homogeneously dispersed within the liquid crystal molecules.

2. An electro-optically active gel layer as described in claim 1, wherein the polymer network dictates the alignment of the molecules.

3. An electro-optically active gel layer as described in claim 1, wherein the polymer comprises less than 5% of the gel layer by mass.

4. An electro-optically active gel layer as described in claim 1, wherein the polymer comprises equal to or less than 2% of the gel layer by mass.

5. An electro-optically active gel layer as described in claim 1, wherein the polymer has a molecular weight of at least 1 million g/mol.

6. An electro-optically active gel layer as described in claim 1, wherein the polymer is a fluorinated polymer.

7. An electro-optically active gel layer as described in claim 1, wherein the electro-optically active material has a switching time less than double the switching time of the liquid crystal molecules in the absence of the polymer.

8. An electro-optically active gel layer as described in claim 1, wherein the polymer is either a block copolymer or telechelic polymer.

9. An electro-optically active gel layer as described in claim 1, wherein the polymer molecules are cross-linked only at the ends.

10. An electro-optically active gel layer as described in claim 1, wherein the homogeneously dispersed polymer network of liquid crystal molecules comprises a plurality of self-assembly block copolymers each comprising at least one endblock and at least one midblock, wherein the endblock either physically or chemically cross-links with at least one other endblock and wherein the midblock is soluble in the liquid crystal molecules.

11. An electro-optically active gel layer as described in claim 10, wherein the endblock is insoluble in the liquid crystal molecules.

12. An electro-optically active gel layer as described in claim 10, wherein the midblock further comprises a plurality of liquid crystal side-chains, wherein the liquid crystal side-chains confer solubility to the block copolymer in the liquid crystal molecules.

13. An electro-optically active gel layer as described in claim 10, wherein the midblock is a main-chain liquid crystal polymer comprising a plurality of liquid crystal mesogens, and wherein the main-chain confers solubility to the midblock of the polymer in the liquid crystal molecules.

14. An electro-optically active gel layer as described in claim 10, wherein the midblock comprises a mixed side-chain/main-chain liquid crystal polymer, and wherein at least one of the main-chain or the side-chain structures confers solubility to the midblock of polymer in the liquid crystal molecules.

15. An electro-optically active gel layer as described in claim 10, wherein the endblock further comprises at least one linking block, wherein the linking block either physically or chemically cross-links with either the linking block or endblock of another polymer.

16. An electro-optically active gel layer as described in claim 10, wherein the endblock is made crosslinkable with other endblocks by application of either a photo or thermal initiating energy.

17. An electro-optically active gel layer as described in claim 16, wherein the photo initiating energy is selected from the group consisting of:

UV-light, X-ray, gamma-ray, and radiation with high-energy electrons or ions.

18. An electro-optically active gel layer as described in claim 1, wherein the network of liquid crystal molecules comprises a plurality of self-assembly telechelic polymers each comprising at least one crosslinking functional group, wherein the crosslinking functional group either physically or chemically cross-links with at least one other crosslinking functional group and wherein the telechelic polymer is soluble in the liquid crystal molecules.

19. An electro-optically active gel layer as described in claim 18, wherein the crosslinking functional group is insoluble in the liquid crystal molecules.

20. An electro-optically active gel layer as described in claim 18, wherein the telechelic polymer further comprises a plurality of liquid crystal side-chains, wherein the liquid crystal side-chains confer solubility to the telechelic polymer in the liquid crystal molecules.

21. An electro-optically active gel layer as described in claim 18, wherein the telechelic polymer is a main-chain polymer comprising a plurality of liquid crystal mesogens, and wherein the main-chain confers solubility to the telechelic polymer in the liquid crystal molecules.

22. An electro-optically active gel layer as described in claim 18, wherein the telechelic polymer comprises a mixed side-chain/main-chain polymer, and wherein at least one of the main-chain or the side-chain confers solubility to the telechelic polymer in the liquid crystal molecules.

23. An electro-optically active gel layer as described in claim 18, wherein the telechelic polymer further comprises at least two crosslinking groups at either end of the telechelic polymer.

24. An electro-optically active gel layer as described in claim 18, wherein the crosslinking group is made crosslinkable with other crosslinking groups by application of either a photo or thermal initiating energy.

25. An electro-optically active gel layer as described in claim 24, wherein the photo initiating energy is selected from the group consisting of:

UV-light, X-ray, gamma-ray, and radiation with high-energy electrons or ions.

26. An electro-optically active gel layer as described in claim 1 wherein the liquid crystal molecules are aligned according to a geometry selected from the group consisting of:

uniaxial, twisted, supertwisted, tilted, chevron and bookshelf.

27. An electro-optically active gel layer as described in claim 1, wherein the polymer network mechanically stabilizes the liquid crystal molecules.

28. An electro-optically active gel layer as described in claim 1, wherein the polymer has a molecular weight of at least 100,000 g/mol.

39. A method of manufacturing an electro-optically active gel layer as described in claim 9, wherein the polymer is crosslinked by thermal or photo initiation.

40. A method of manufacturing an electro-optically active gel layer as described in claim 39, wherein the photo initiation uses an energy selected from the group consisting of:

UV-light, X-ray, gamma-ray, and radiation with high-energy electrons or ions.

29. A method of manufacturing an electro-optically active gel layer comprising:

providing a quantity of liquid crystal molecules;

providing a quantity of polymer;

homogeneously dispersing the polymer into the liquid crystal molecules;

orienting the liquid crystal molecules and polymers; and

sparsely crosslinking the polymers to form an anisotropic polymer network.

30. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the anisotropic polymer network is also adapted to dictate the alignment of the liquid crystal molecules.

31. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer is either a block copolymer or a telechelic polymer.

32. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer is made using a technique selected from the group consisting of:

anionic, radical and polymer analogous.

33. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the liquid crystal molecules are oriented by a method selected from the group consisting of:

surface alignment, energetic field alignment, shear stress alignment, and extensional stress alignment.

34. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymers are aligned according to a geometry selected from the group consisting of:

uniaxial, twisted, supertwisted, tilted, chevron and bookshelf.

35. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer comprises less than 5% of the gel by mass.

36. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer comprises equal to or less than 2% of the gel by mass.

37. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer is either chemically or physically crosslinked.

38. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer is crosslinked by self-assembly.

41. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer is crosslinked by a combination of self-assembly and thermal or photo initiation.

42. A method of manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer has a molecular weight of at least 1 million g/mol.

43. A method for manufacturing an electro-optically active gel layer as described in claim 29, wherein the polymer network mechanically stabilizes the liquid crystal molecules.

44. An electro-optically active gel layer as described in claim 29, wherein the polymer has a molecular weight of at least 100,000 g/mol.

45. An electro-optically active gel layer having nematic, ferroelectric, antiferroelectric or electroclinic properties comprising a plurality of liquid crystal molecules and an anisotropic three-dimensional polymer network comprising a plurality of sparsely cross-linked polymer molecules, wherein the anisotropic three-dimensional polymer network is homogeneously dispersed within the liquid crystal molecules, and wherein the liquid crystal molecules comprises less than 5% of the gel layer by mass.

46. An electro-optically active gel layer as described in claim 45, wherein the polymer network further dictates the alignment of the liquid crystal molecules.

47. An electro-optically active gel layer as described in claim 45, wherein the polymer network mechanically stabilizes the liquid crystal molecules.

48. An electrooptic device comprising two substrates, which are provided with at least one electrode, and an electro-optically active gel layer which is located between the two substrates, wherein the electro-optically active gel layer has nematic, ferroelectric, antiferroelectric or electroclinic properties and comprises a plurality of aligned liquid crystal molecules and an anisotropic three-dimensional polymer network comprising a plurality of sparsely cross-linked polymer molecules, wherein the anisotropic three-dimensional polymer network is homogeneously dispersed within the liquid crystal molecules.

49. An electrooptic device as described in claim 48, wherein the polymer network further dictates the alignment of the liquid crystal molecules.

50. An electrooptic device as described in claim 48, in the form of a display device.

51. An electro-optic device as described in claim 48, wherein the polymer network mechanically stabilizes the liquid crystal molecules.

52. An electro-optically active gel layer as described in claim 48, wherein the polymer has a molecular weight of at least 100,000 g/mol.

53. An electrooptic device comprising two substrates, which are provided with at least one electrode, and an electro-optically active gel layer which is located between the two substrates, wherein the electro-optically active gel layer has nematic, ferroelectric, antiferroelectric or electroclinic properties and comprises a plurality of aligned liquid crystal molecules and an anisotropic three-dimensional polymer network comprising a plurality of sparsely cross-linked polymer molecules, wherein the anisotropic three-dimensional polymer network is homogeneously dispersed within the liquid crystal molecules, and wherein the liquid crystal molecules comprises less than 5% of the gel layer by mass, and wherein the polymer network mechanically stabilizes the liquid crystal molecules.

54. An electrooptic device as described in claim 53, wherein the polymer network further dictates the alignment of the chiral liquid crystal molecules.

55. An electrooptic device as described in claim 53, in the form of a display device.