Carbon dioxide reduction scheme for NGL processes
First Claim
1. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons into a volatile gas fraction containing substantially all the methane and a less volatile hydrocarbon fraction containing a large portion of the C2+ components, the process comprising the steps of:
- supplying and cooling an inlet gas stream having a quantity of CO2 such that at least a portion of the inlet gas stream is condensed to produce a first vapor stream and a first liquid stream;
expanding the first vapor stream to a lower pressure, and then supplying a fractionation tower with the vapor stream as a tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon fraction and a tower overhead stream containing a volatile gas fraction; and
the improvement comprising;
splitting the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying the fractionation tower with the second liquid stream as a second upper tower food stream; and
heating the third liquid stream and supplying the fractionation tower with the third liquid stream at a return location at least one theoretical stage below the second upper tower feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction.
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Abstract
An ethane recovery process resulting in a reduction in the amount of carbon dioxide in the recovered NGL stream is provided. To reduce the amount of carbon dioxide, a fractionation tower is provided with a bottom reboiler, and possibly one or more side reboilers higher up in the tower that are integrated with the cooling train. The process disclosed modifies the flow of cold liquid from the separator and tower reboiling to reject some of the more volatile components such as carbon dioxide from the less volatile fraction while maintaining recovery of desirable components such as C2+ hydrocarbon components. The modification includes heating a part of the separator liquid and introducing it at least one stage below the remaining liquid.
50 Citations
40 Claims
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1. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons into a volatile gas fraction containing substantially all the methane and a less volatile hydrocarbon fraction containing a large portion of the C2+ components, the process comprising the steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 such that at least a portion of the inlet gas stream is condensed to produce a first vapor stream and a first liquid stream;
expanding the first vapor stream to a lower pressure, and then supplying a fractionation tower with the vapor stream as a tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon fraction and a tower overhead stream containing a volatile gas fraction; and
the improvement comprising;
splitting the first liquid stream into at least a second liquid stream and a third liquid stream; supplying the fractionation tower with the second liquid stream as a second upper tower food stream; and heating the third liquid stream and supplying the fractionation tower with the third liquid stream at a return location at least one theoretical stage below the second upper tower feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (3, 4, 5, 6, 7, 8, 9)
supplying an expander outlet separator with the first vapor stream and the tower overhead stream thereby forming a separator bottoms stream and a separator overhead stream;
supplying the fractionation tower with the separator bottoms stream as the tower feed stream; and
heating and boosting in pressure the separator overhead stream to form a residue gas stream.
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6. The process of claim 5, wherein the step of healing and boosting in pressure the separator overhead stream to form a residue gas stream includes heating the separator overhead stream by heat exchange contact with at least a portion of the inlet gas stream.
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7. The process of claim 1, further comprising the steps of:
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heating and boosting in pressure the tower overhead stream to form a residue gas stream;
removing at least a portion of the residue gas stream and cooling at least a portion of the residue gas stream to substantially condense at least a portion of the tower overhead stream; and
supplying the fractionation tower with the at least a portion of the substantially condensed tower overhead stream as a top tower feed stream.
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8. The process of claim 7, wherein the step of heating and boosting in pressure the tower overhead stream to form a residue gas stream includes heating the tower overhead stream by heat exchange contact with a stream selected from the group consisting of at least a portion of the inlet gas stream, at least a portion of the residue gas stream, and combinations thereof.
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9. The process of claim 7, wherein the step of cooling at least a portion of the inlet gas stream further includes cooling at least a portion of the inlet gas stream by heat exchange contact with the third liquid stream and at least one tower reboiler stream, the at least one tower reboiler stream being removed from the fractionation tower at a removal location and being returned at a return location located at essentially a same theoretical stage within the fractionation tower as the removal location.
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2. A process for separating as inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons into a volatile gas fraction containing substantially all the methane end a less volatile hydrocarbon fraction containing a large portion of the C2+ components, the process comprising the steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
expanding the first vapor stream to a lower pressure, and then supplying a fractionation tower with the vapor stream as a tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon fraction and a tower overhead stream containing a volatile gas fraction; and
the improvement comprising;
splitting the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying the fractionation tower with the second liquid stream as a second upper tower feed stream;
heating the third liquid stream and supplying the fractionation tower with the third liquid stream at a return location at least one theoretical stage below the second upper tower feed stream, the third liquid stream providing stripping vapors capable of removing CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction; and
maintaining feed stream conditions including maintaining an adequate quantity and temperature of the third liquid stream and an amount of reboiling for the functionation tower so that a quantity of carbon dioxide in the tower bottoms stream is substantially reduced.
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10. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
splitting at least a portion of the first vapor stream into a second vapor stream a third vapor stream;
cooling, expanding, and then supplying the fractionation tower with the second vapor stream as a first upper tower feed stream;
expanding the third vapor stream and supplying the fractionation tower with the third vapor stream as a second upper tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon stream and a tower overhead stream containing a more volatile fraction; and
an improvement to the process comprising the steps of;
splitting the first liquid stream into at least a second liquid stream and a third liquid stream; supplying the fractionation tower with the second liquid stream as a middle feed stream; and heating the third liquid stream and supplying the third liquid stream to the fractionation tower at a location at learnt one theoretical stage below the middle feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 as significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (12, 13, 14, 15)
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11. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
splitting at least a portion of the first vapor stream into a second vapor stream and a third vapor stream;
cooling, expanding, and then supplying the fractionation tower with the second vapor stream as a first upper tower feed stream;
expanding the third vapor stream and supplying the fractionation tower with the third vapor stream as a second upper tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon stream and a tower overhead stream containing a more volatile fraction; and
an improvement to the process comprising the step of;
splitting the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying the fractionation tower with the second liquid stream as a middle feed stream;
heating the third liquid stream and supplying the third liquid stream to the fractionation tower at a location at least one theoretical stage below the middle feed stream, the third liquid stream providing stripping vapors capable of removing CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction; and
maintaining feed stream conditions including maintaining an adequate quantity and temperature of the third liquid stream and an amount of reboiling for the fractionation tower so that a quantity of carbon dioxide in the tower bottoms stream is substantially reduced. - View Dependent Claims (16, 17)
heating and boosting in pressure the tower overhead stream to form a residue gas stream;
removing and cooling at least a portion of the residue gas stream to substantially condense the at least a portion of the residue gas stream; and
supplying the fractionation tower with the at least a portion of the residue gas stream as a top tower food stream.
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17. The process of claim 16, wherein the step of heating and boosting in pressure the tower overhead stream to form a residue gas stream includes heating the tower overhead stream by heat exchange contact with a stream selected from the group consisting of the second vapor stream, at least a portion of the inlet gas stream, and combinations thereof.
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18. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
splitting at least a portion of the first vapor stream into a second vapor stream and a third vapor stream;
cooling the second vapor stream to substantially condense the second vapor stream and supplying the second vapor stream to an absorber tower as an absorber top feed stream;
expanding the third vapor stream to a lower pressure and then supplying the absorber tower with the third vapor stream as an absorber bottoms feed stream so that the absorber tower produces an absorber overhead stream containing a more volatile fraction of the second and third vapor streams and an absorber bottoms stream containing a less volatile fraction of the second and third vapor streams;
supplying a fractionation tower with the absorber bottoms stream as a top tower feed stream so that the fractionation tower produces a tower bottom stream containing a less volatile hydrocarbon fraction of the inlet gas stream and a tower overhead stream containing a more volatile fraction of the inlet gas stream;
supplying the absorber tower with the tower overhead stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at least a second liquid stream and a third liquid stream; supplying the fractionation tower with the second liquid stream as a lower tower feed stream; and healing and then supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the lower tower feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (20, 21, 22, 23, 24)
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19. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon strewn containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
splitting at least a portion of the first vapor stream into a second vapor stream and a third vapor stream;
cooling the second vapor stream to substantially condense the second vapor stream and supplying the second vapor stream to an absorber tower as an absorber top feed stream;
expanding the third vapor stream to a lower pressure and then supplying the absorber tower with the third vapor stream as an absorber bottoms feed stream so that the absorber tower produces an absorber overhead stream containing a more volatile function of the second and third vapor streams and an absorber bottoms stream containing a less volatile fraction of the second and third vapor streams;
supplying a fractionation tower with the absorber bottoms stream as a top tower feed stream so that the fractionation tower produces a tower bottoms stream containing a less volatile hydrocarbon fraction of the inlet gas stream and a tower overhead stream containing a more volatile fraction of the inlet gas stream;
supplying the absorber tower with the tower overhead stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying the fractionation tower with the second liquid stream as a lower tower feed stream;
heating and that supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the lower tower feed stream, the third liquid stream providing stripping vapors capable of removing CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction; and
maintaining feed stream conditions including maintaining an adequate quantity and temperature of the third liquid stream and an amount of reboiling for the fractionation tower so that a quantity of carbon dioxide in the tower bottoms stream is substantially reduced.
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25. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling the inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
expanding the first vapor stream to a lower pressure, and then supplying an absorber tower with the first vapor stream as an absorber bottom feed stream so that the absorber tower produces an absorber overhead stream and an absorber bottoms stream;
supplying the absorber bottoms stream to a fractionation tower as top tower feed stream so that the fractionation tower produces a tower overhead stream and a tower bottoms stream;
heating and boosting in pressure the absorber overhead stream to form a residue gas stream;
removing and then cooling at least a portion of the residue gas stream so that the at least a portion of the residue gas stream is substantially condensed;
supplying the absorber tower with the at least a portion of the residue gas stream as a top absorber feed stream;
supplying the absorber tower with the tower overhead stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at least a second liquid stream and a third liquid stream; supplying fractionation tower with the second liquid stream as a first lower tower feed stream; and heating and then supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the first lower tower feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (27, 28, 29, 30, 31)
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26. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling the inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
expanding the first vapor stream to a lower pressure, and then supplying an absorber tower with the first vapor stream as an absorber bottom feed stream so that the absorber tower produces an absorber overhead stream and an absorber bottoms stream;
supplying the absorber bottoms stream to a fractionation tower as top tower feed stream so that the fractionation tower produces a tower overhead stream and a tower bottoms stream;
heating and boosting in pressure the absorber overhead stream to turn a residue gas stream;
removing and then cooling at least a portion of the residue gas stream so that the at least a portion of the residue gas stream is substantially condensed;
supplying the absorber tower with the at least a portion of the residue gas stream as a top absorber feed stream;
supplying the absorber tower with the tower overhead stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying fractionation tower with the second liquid stream as a first lower tower feed stream;
heating and than supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the first lower tower feed stream, the third liquid stream providing stripping vapor capable of removing CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction; and
maintaining feed stream conditions including maintaining an adequate quantity and temperature of the third liquid stream and an amount of reboiling for the fractionation tower so that a quantity of carbon dioxide in the tower bottoms stream is substantially reduced.
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32. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling the inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
dividing the first vapor stream into a second vapor stream and a third vapor stream;
cooling and at least partially condensing the second vapor stream thereby forming a flash separator bottoms stream and a flash separator overhead stream and expanding the third vapor stream;
cooling the flash separator overhead stream and supplying an absorber tower with the flash separator overhead stream as a first upper absorber feed stream, the flash separator bottoms stream a first lower absorber feed stream, and the third vapor stream as a second lower absorber feed stream to thereby produce an absorber overhead stream and an absorber bottoms stream;
supplying a fractionation tower with the absorber bottoms stream as an upper tower feed stream to thereby produce a tower overhead stream and a tower bottoms stream;
heating and boosting in pressure the absorber overhead stream to form a residue gas stream;
removing and cooling at least a portion of the residue gas stream so that the at least a portion of the residue gas stream is substantially condensed;
supplying the absorber tower with the tower overhead stream and the at least a portion of the residue gas stream as a second upper absorber feed stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at last a second liquid stream and a third liquid stream; supplying the fractionation tower with the second liquid stream; and heating and supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the second liquid stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (34, 35, 36, 37, 38)
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33. A process for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the process comprising steps of:
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supplying and cooling the inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
dividing the first vapor stream into a second vapor stream and a third vapor stream;
cooling and at least partially condensing the second vapor stream thereby forming a flash separator bottoms stream and a flash separator overhead stream and expanding the third vapor stream;
cooling the flash separator overhead stream and supplying an absorber tower with the flash separator overhead stream as a first upper absorber feed stream, the flash separator bottoms stream as a first lower absorber feed stream, and the third vapor stream as a second lower absorber feed stream to thereby produce an absorber overhead stream and an absorber bottoms stream;
supplying a fractionation tower with the absorber bottoms stream as an upper tower feed stream to thereby produce a tower overhead stream and a tower bottoms stream;
heating and boosting in pressure the absorber overhead stream to form a residue gas stream;
removing and cooling at least a portion of the residue gas stream so that the at least a portion of the residue gas stream is substantially condensed;
supplying the absorber tower with the tower overhead stream and the at least a portion of the residue gas stream as a second upper absorber feed stream; and
an improvement to the process comprising the steps of;
dividing the first liquid stream into at least a second liquid stream and a third liquid stream;
supplying the fractionation tower with the second liquid stream;
heating and supplying the fractionation tower with the third liquid stream at a location at least one theoretical stage below the second liquid stream, the third liquid stream providing stripping vapors capable of removing CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction; and
maintaining feed stream conditions including maintaining an adequate quantity and temperature of the third liquid stream and an amount of rebelling for the fractionation tower so that a quantity of carbon dioxide in the tower bottoms stream is substantially reduced.
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39. An apparatus for separating an inlet gas stream containing methane, C2 components, C3 components and heavier hydrocarbons, into a residue gas stream containing substantially all the methane and more volatile components and a less volatile hydrocarbon stream containing C2 components, C3 and heavier components, the apparatus comprising:
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an inlet heat exchanger for cooling an inlet gas stream having a quantity of CO2 to partially condense at least a portion of the inlet gas stream to produce a first vapor stream and a first liquid stream;
an expander for expending the first vapor stream to a lower pressure;
a fractionation tower for receiving a tower feed stream and producing a tower bottoms stream containing a less volatile hydrocarbon fraction and a tower overhead stream containing a more volatile gas fraction;
at least one side reboiler that removes that returns a tower reboiler stream from essentially a same theoretical stage with the fractionation tower, the side reboiler heats the more volatile gas fraction higher in the fractionation tower thereby preventing the more volatile gas fraction from reaching a bottom of the fractionation tower and reducing an amount of the more volatile gas fraction recovered in the tower bottoms stream; and
a splitter for splitting the first liquid stream into at least a second liquid stream and a third liquid stream, the second liquid stream being supplied to the fractionation tower as a second upper tower feed stream and the third liquid stream being heated and supplied to the fractionation lower at a return location at least one theoretical stage below the second upper tower feed stream, the third liquid stream providing stripping vapors to remove CO2 from the liquid descending down the fractionation tower such that the quantity of CO2 is significantly reduced in the less volatile hydrocarbon fraction or ethane is significantly increased while the quantity of CO2 is substantially maintained in the less volatile hydrocarbon fraction. - View Dependent Claims (40)
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Specification