Method for making multilayer optical films

• US 6,827,886 B2
• Filed: 03/16/2001
• Issued: 12/07/2004
• Est. Priority Date: 01/13/1998
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Ouderkirk, Andrew J., Neavin, Terence D., Liu, Yaoqi J.
• Primary Examiner(s): Vargot, Mathieu D.
• Application Number:
  US09/810,916
• Publication Number:
  US 20010013668A1
• Time in Patent Office: 1,362 Days
• Field of Search: 264/1.1, 264/1.6, 264/1.7, 264/2.7, 264/1.9, 264/173.12, 264/173.16, 425/133.5, 425/462
• US Class Current: 264/1.6
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 48/495 Feed-blocks extrusion moulding of multi-component articles B29C48/16
• CPC Class Codes: B29C 48/71 for layer multiplication extrusion of multi-component articles B29C48/16
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

Methods and apparatuses are provided for the manufacture of coextruded polymeric multilayer optical films. The multilayer optical films have an ordered arrangement of layers of two or more materials having particular layer thicknesses and a prescribed layer thickness gradient throughout the multilayer optical stack. The methods and apparatuses described allow improved control over individual layer thicknesses, layer thickness gradients, indices of refraction, interlayer adhesion, and surface characteristics of the optical films. The methods and apparatuses described are useful for making interference polarizers, mirrors, and colored films that are optically effective over diverse portions of the ultraviolet, visible, and infrared spectra.

Claims

1. A method for making a multilayered optical film, comprising:

(a) providing at least a first and a second stream of resin;

(b) providing a feeder tube plate having a first plurality of conduits, and having a second plurality of conduits interleaved with the first plurality of conduits;

(c) feeding the first stream into the first plurality of conduits and the second stream into the second plurality of conduits;

(d) providing a slot die for each of the first and second plurality of conduits such that the first and second streams are divided into a plurality of interleaved layers to yield a composite stream;

(e) passing the composite stream through an extrusion die to form a multilayer web in which each layer is generally parallel to the major surface of adjacent layers; and

(f) heating the first and second streams of resin with at least one axial rod heater that extends along at least one of the first and second plurality of conduits.

2. The method of claim 1, further comprising:

(g) positioning the at least one axial rod heater proximate the first and second plurality of conduits.

3. The method of claim 1, further comprising:

(g) positioning the at least one axial rod heater between the first and second plurality of conduits.

4. The method of claim 1, further comprising:

(g) varying temperature of the at least one axial rod heater in zones along a length of the axial rod heater.

5. The method of claim 1, wherein the heating step comprises heating with a plurality of axial rod heaters.

6. The method of claim 5, wherein the healing step comprises heating with a first axial rod heater disposed proximate the first plurality of conduits and heating with a second axial rod heater disposed proximate the second plurality of conduits.

7. The method of claim 1, further comprising after step (d):

(g) passing the composite stream into a multiplier where the composite stream is divided into a plurality of substreams, the multiplier expanding at least one of the substreams in a direction transverse to its direction of flow; and

(h) recombining the substreams to increase the number of layers in the composite stream.

8. The method of claim 1, further comprising:

(g) casting the multilayer web onto a casting roll to form a cast multilayer film.

9. The method of claim 8, further comprising:

(h) quenching said multilayer web during the casting step.