Controlled cooling of input water by dissociation of hydrate in an artificially pressurized assisted desalination fractionation apparatus

• US 6,830,682 B2
• Filed: 02/11/2002
• Issued: 12/14/2004
• Est. Priority Date: 06/26/2000
• Status: Expired due to Fees

• Current Assignee: Marine Desalination Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael D
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US10/019,691
• Publication Number:
  US 20020155047A1
• Time in Patent Office: 1,037 Days
• Field of Search: 625/32, 625/33, 621/23, 621/24, 622/385, 203/10, 203/100, 210/170, 210/177, 210/181, 210/182, 210/195.1, 210/202, 210/205, 210/97, 210/137, 210/258
• US Class Current: 210/170.11
• CPC Class Codes: B01D 3/14 Fractional distillation or use of a fractionation or rectification column
• CPC Class Codes: C02F 1/04 by distillation or evaporation
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: Y02A 20/124 Water desalination

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Saline (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas or liquid to form either positively buoyant (also assisted buoyancy) or negatively buoyant hydrate. The hydrate rises or sinks or is carried into a lower pressure area and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths, and input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications. In other embodiments, desalination or other purification is carried out in “artificially” or mechanically pressurized vessels, which embodiments may be comparatively mobile. Such pressurized systems can be used to capture carbon dioxide from industrial waste gases and to provide liquid carbon dioxide.

Claims

1. An installation for desalinating or purifying saline or otherwise polluted input water, said installation comprising:

a desalination fractionation installation including a shaft extending downward into land and having a hydrate formation region at a lower portion of said shaft;

an input water conduit which is arranged to provide input water to said hydrate formation region;

a gas supply conduit which is arranged to provide hydrate-forming gas to said hydrate formation region; and

a hydrate dissociation region disposed at an upper portion of said installation and in fluid communication with said hydrate formation region,

wherein natural pressurization in said hydrate formation region, created by the weight of input water in said shaft, is, by itself, insufficient to cause formation of hydrate of said hydrate-forming gas;

wherein said hydrate dissociation region is artificially pressurized; and

wherein the artificial pressurization in the dissociation region and the natural pressurization in the hydrate formation region combine to create pressurization in the hydrate formation region that is suitable for the spontaneous formation of hydrate of said hydrate-forming gas.

2. The installation of claim 1, wherein said hydrate dissociation region is artificially pressurized by a pressure balance reservoir system.

3. The installation of claim 2, wherein said pressure balance reservoir system pressurizes a volume of gas so as to exert hydraulic force throughout the volume of input water in said desalination fractionation installation.

4. The installation of claim 2, wherein said pressure balance reservoir system is located on the upper portion of said dissociation region.

5. The installation of claim 1, further comprising a pump and pressure regulating apparatus which pumps the intake water into the installation at a pressure which is approximately equivalent to the pressure which is artificially maintained in the dissociation region of said installation.

6. The installation of claim 1, wherein said input water conduit has a water intake apparatus on one end thereof, and wherein said water intake apparatus is positionable at a pressure depth that is approximately equivalent to the pressure which is artificially maintained in the dissociation region of said installation.

7. The installation of claim 1, wherein said hydrate dissociation region is artificially pressurized by the head of the weight of water contained in the input water conduit.

8. The installation of claim 7, wherein said input water conduit syphons water into the installation creating the artificial pressurization in the dissociation region.

9. An installation for desalinating or purifying saline or otherwise polluted input water, said installation comprising:

a desalination fractionation installation having a lower, hydrate formation region;

an input water conduit which is arranged to provide input water to said hydrate formation region; and

a gas supply conduit which is arranged to provide hydrate-forming gas to said hydrate formation region;

said installation further comprising a hydrate dissociation region disposed at an upper portion of said installation and in fluid communication with said hydrate formation region, said hydrate dissociation region comprising a plurality of cooling segments in heat exchanging relationship with said input water; and

wherein the input water is at least partially cooled by being passed through said dissociation region in heat exchanging relationship with the dissociation region, whereby heat is absorbed from said input water as hydrate located in the dissociation region dissociates endothermically.

10. The installation of claim 9, wherein said cooling segments are separated by walls which prevent hydrate from moving laterally from one cooling segment to another.

11. The installation of claim 9, wherein said cooling segments are in fluid communication with the hydrate formation region.

12. The installation of claim 9, wherein said input water is carried in a heat exchanging apparatus which extends laterally across said plurality of cooling segments.

13. The installation of claim 12, wherein said input water becomes progressively cooler as it passes through each cooling segment of said plurality of cooling segments.

14. The installation of claim 13, wherein said input water conduit which is arranged to provide input water to said hydrate formation region after said input water conduit passes through each cooling segment of said plurality of cooling segments.