Stable solid block detergent composition

• US 6,831,054 B2
• Filed: 05/08/2003
• Issued: 12/14/2004
• Est. Priority Date: 01/13/1997
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Wei, G. Jason, Olson, Keith E., Lentsch, Steven E.
• Primary Examiner(s): Douyon, Lorna M.
• Application Number:
  US10/431,665
• Publication Number:
  US 20030216279A1
• Time in Patent Office: 586 Days
• Field of Search: 510/224, 510/228, 510/231, 510/446, 510/451, 510/469, 510/509, 510/510, 510/444
• US Class Current: 510/446
• CPC Class Codes: C11D 17/0047 Detergents in the form of bars or tablets
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: C11D 17/0065 Solid detergents containing builders C11D17/06 takes precedence
• CPC Class Codes: C11D 3/06 Phosphates, including polyphosphates
• CPC Class Codes: C11D 3/08 Silicates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/361 Phosphonates, phosphinates or phosphonites
• CPC Class Codes: C11D 3/364 containing nitrogen
• CPC Class Codes: C11D 7/12 Carbonates bicarbonates
• CPC Class Codes: C11D 7/36 containing phosphorus

Abstract

The dimensionally stable alkaline solid block warewashing detergent uses an E-form binder forming a solid comprising a sodium carbonate source of alkalinity, a sequestrant, a surfactant package and other optional material. The solid block is dimensionally stable and highly effective in removing soil from the surfaces of dishware in the institutional and industrial environment. The E-form hydrate comprises an organic phosphonate and a hydrated carbonate.

Claims

1. A method of manufacturing detergent composition, which method comprises:

(i) combining the following components to form a blended mass;

(a) about 20 to 80 wt % of an alkali metal carbonate;

(b) about 1 wt % to 30 wt % of an organic phosphonate;

(c) about 0.01 to 1.3 mole of water per mole of carbonate; and

(d) at least one of bleaching agent and enzyme; and

(ii) forming the blended mass into a composition comprising non-hydrated alkali metal carbonate and a binding agent comprising a mono-hydrated alkali metal carbonate and organic phosphonate, wherein the mole ratio of alkali metal carbonate to organic phosphonate in the binding agent is in range of about 3;

1 to about 7;

1 and the composition is substantially free of a source of alkalinity other than an alkali metal carbonate.

2. The method of claim 1, wherein the binding agent comprises a hydrated sodium carbonate and an organic phosphonate.

3. The method of claim 1, wherein the mono-hydrated alkali metal carbonate comprises sodium carbonate and combining further comprises (e) about 1.5 to 15 wt % of a surfactant which is selected from the group consisting of an anionic surfactant, a nonionic surfactant, and mixtures thereof.

4. The method of claim 1, wherein combining includes about 0.9 to less than 1.3 moles of water per each mole of carbonate.

5. The method of claim 1, wherein forming comprises forming the blended mass into a solid.

6. The method of claim 5, wherein the solid is a solid block.

7. The method of claim 5, wherein forming comprises extruding the blended mass.

8. The method of claim 5, wherein forming comprises forming the blended mass into pellets.

9. The method of claim 1, wherein combining comprises enzyme and the enzyme comprises at least one of lipase, protease, and amylase.

10. The method of claim 1, wherein combining comprises bleaching agent and the bleaching agent comprises at least one of encapsulated bleach, sodium hypochlorite, and hydrogen peroxide.

11. The method of claim 1, wherein combining comprises bleaching agent and the bleaching agent comprises halogen-releasing compound.

12. The method of claim 11, wherein the halogen-releasing compound comprises one or more of chlorine, hypochlorite, and chloramine.

13. The method of claim 11, wherein the halogen-releasing compound comprises one or more of alkali metal dichloroisocyanurate, chlorinated trisodium phosphate, alkali metal hypochlorite, monochloramine, and dichloramine.

14. The method of claim 1, wherein combining comprises bleaching agent and die bleaching agent comprises an active oxygen source.

15. The method of claim 14 wherein the active oxygen source comprises one or more of hydrogen peroxide, perborate, sodium carbonate peroxyhydrate, phosphate peroxyhydrate, and potassium permonosulfate.

16. The method of claim 15, wherein the perborate comprises at least one of sodium perborate monohydrate and sodium perborate tetrahydrate.

17. The method of claim 14, wherein combining comprises bleach activator.

18. A detergent composition comprising:

(a) about 20 to 65 wt % of alkali metal carbonate;

(b) about 1 wt % to 30 wt % of an organic phosphonate;

(c) about 0.01 to 1.3 mole of water per mole of carbonate; and

(d) at least one of bleaching agent and enzyme;

wherein the composition comprises non-hydrated alkali metal carbonate and a binding agent comprising mono-hydrated alkali metal carbonate and organic phosphonate, and the mole ratio of alkali metal carbonate to organic phosphonate in the binding agent is in range of about 3;

1 to about 7;

1, and the composition is substantially free of a second source of alkalinity.

19. The composition of claim 18, wherein the alkali metal carbonate is sodium carbonate, and composition comprises about 0.9 to 1.3 moles of water per mole of sodium carbonate.

20. The composition of claim 18, wherein the composition further comprises about 1.5 to 15 wt % of a surfactant composition which is selected from the group consisting of an anionic surfactant, a nonionic surfactant, and mixtures thereof.

21. The composition of claim 18, wherein the detergent composition is a solid.

22. The composition of claim 21, wherein the solid is provided in the form of a solid block.

23. The composition of claim 22, wherein the solid block has a mass greater than about 10 gins.

24. The composition of claim 21, wherein the solid is provided in the form of a pellet.

25. The composition of claim 18, wherein the composition comprises enzyme and the enzyme comprises at least one of lipase, protease, and amylase.

26. The composition of claim 18, wherein the composition comprises bleaching agent and the bleaching agent comprises at least one of encapsulated bleach, sodium hypochlorite, end hydrogen peroxide.

27. The composition of claim 18, wherein the composition comprises bleaching agent and the bleaching agent comprises halogen-releasing compound.

28. The composition of claim 27, wherein the halogen-releasing compound comprises one or more of chlorine, hypochlorite, and chloramine.

29. The composition of claim 27, wherein the halogen-releasing compound comprises one or more of alkali metal dichloroisocyanurate, chlorinated trisodium phosphate, alkali metal hypochlorite, monochloramine, and dichloramine.

30. The composition of claim 18, wherein the composition comprises bleaching agent and the bleaching agent comprises an active oxygen source.

31. The composition of claim 30, wherein the active oxygen source comprises one or more of hydrogen peroxide, perborate, sodium carbonate peroxyhydrate, phosphate peroxyhydrate, and potassium permonosulfate.

32. The composition of claim 31, wherein the perborate comprises at least one of sodium perborate monohydrate and sodium perborate tetrahydrate.

33. A solid detergent composition comprising:

(a) about 20 to 80 wt % of a Na₂CO₃;

(b) about 1 wt % to 30 wt % of an organic phosphonate;

(c) an effective amount of a chelating/sequestering agent including a condensed phosphate;

(d) about 0.9 to about 1.3 moles of water per each mole of Na₂CO₃; and

(e) at least one of bleaching agent and enzyme;

wherein the detergent comprises a binding agent comprising an organic phosphonate and sodium carbonate monohydrate, and the mole ratio of sodium carbonate to organic phosphonate in the binding agent is in range of about 3;

1 to about 7;

1, and the detergent is substantially free of a source of alkalinity other than Na₂CO₃.

34. The solid of claim 33, wherein the composition is cast in a disposable capsule to solidify.

35. The solid of claim 33, wherein the chelating/sequestering agent comprises about 5 to 60 wt % of the composition.

36. The solid of claim 33, wherein the composition comprises 1 to 45 wt % of an inorganic tripolyphosphate and about 1 to 20 wt % of the organic phosphonate.

37. The solid of claim 33, wherein the solid is provided in the form of a pellet.

38.The solid of claim 33, wherein the solid is provided in a form resulting from extrusion.

38. The solid of claim 33, wherein the solid comprises enzyme and the enzyme comprises at least one of lipase, protease, and amylase.

39. The solid of claim 33, wherein the solid comprises bleaching agent and the bleaching agent comprises at least one of encapsulated bleach, sodium hypochlorite, and hydrogen peroxide.

40. The solid of claim 33, wherein the solid comprises bleaching agent and the bleaching agent comprises halogen-releasing compound.

43. The solid of claim 33, wherein the solid comprises bleaching agent and the bleaching agent comprises an active oxygen source.

41. The solid of claim 41, wherein the halogen-releasing compound comprises one or more of chlorine, hypochlorite, and chloramine.

42. The solid of claim 41, wherein the halogen-releasing compound comprises one or more of alkali metal dichloroisocyanurate, chlorinated trisodium phosphate, alkali metal hypochlorite, monochloramine, and dichloramine.

44. The solid of claim 44, wherein the active oxygen source comprises one or more of hydrogen peroxide, perborate, sodium carbonate peroxyhydrate, phosphate peroxyhydrate, and potassium permonosulfate.

46. The solid of claim 44, further comprising bleach activator.

45. The solid of claim 45, wherein the perborate comprises at least one of sodium perborate monohydrate and sodium perborate tetrahydrate.