Electrophoretic display and novel process for its manufacture

• US 6,833,943 B2
• Filed: 06/24/2002
• Issued: 12/21/2004
• Est. Priority Date: 03/03/2000
• Status: Expired due to Term

• Current Assignee: E Ink California, LLC (E Ink Holdings Incorporated)
• Original Assignee: SiPix Imaging, Inc. (E Ink Holdings Incorporated)
• Inventors: Tseng, Scott C. J., Wu, Zarng-Arh George, Zang, HongMei, Liang, Rong-Chang
• Primary Examiner(s): Dang, Hung Xuan
• Assistant Examiner(s): TRA, TUYEN Q
• Application Number:
  US10/179,997
• Publication Number:
  US 20030007238A1
• Time in Patent Office: 911 Days
• Field of Search: 359/296, 359/295, 359/298, 204/600, 204/450, 345/105, 345/107, 430/32, 430/34, 430/38
• US Class Current: 359/296
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 1/133377 Cells with plural compartments or having plurality of liquid crystal microcells partitioned by walls, e.g. one microcell per pixel
• CPC Class Codes: G02F 1/1339 Gaskets; Spacers; Sealing of cells
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1679 Gaskets; Spacers; Sealing of cells; Filling or closing of cells

Abstract

This invention relates to an electrophoretic display comprising cells which are filled with charged particles dispersed in a solvent and are individually sealed with a polymeric sealing layer which is an integral part of the display and is curved.

Claims

1. An electrophoretic display comprising a plurality of cells where each of said cells comprises:

1) side walls, each of said side walls having a top surface;

2) an electrophoretic dispersion filled therein; and

3) a sealing layer which is in contact with both the top surface of said side walls and said electrophoretic dispersion and is curved.

2. The display of claim 1 wherein said sealing layer has a side that is in contact with the electrophoretic dispersion, and that side is curved.

3. The display of claim 1 wherein said sealing layer has two sides and is curved on both sides.

4. The display of claim 1 wherein said sealing layer is physically or chemically bonded to the top of the side walls of the cells.

5. The display of claim 1 wherein each of said side walls has an inner surface and said sealing layer is in intimate contact with both the dispersion and the inner surface of the side walls of said cells that are not covered by the dispersion.

6. The display of claim 1 wherein said sealing layer extends over the top surface of the side walls of said cells.

7. The display of claim 1 wherein said sealing layer is a polymeric layer.

8. The display of claim 1 wherein said sealing layer is formed from a composition comprising a material selected from the group consisting of polyvalent acrylate, polyvalent methacrylate, cyanoacrylates, polyvalent vinyl, polyvalent epoxide, polyvalent isocyanate, polyvalent allyl, and oligomers or polymers containing crosslinkable functional groups.

9. The display of claim 8 wherein said sealing layer is formed from a composition comprising polyvalent isocyanate.

10. The display of claim 8 wherein said composition further comprises an ingredient selected from the group consisting of surfactants, antioxidants, initiators, catalysts, crosslinkers, thickeners, polymer binders, pigments, dyes and fillers.

11. The display of claim 10 wherein said filler is silica, CaCO₃, BaSO₄, TiO₂, metal particles and their oxides or carbon black.

12. The electrophoretic display of claim 1 wherein said sealing layer is formed from a sealing composition having a specific gravity lower than that of the electrophoretic dispersion.

13. The electrophoretic display of claim 12 wherein said sealing composition is a UV curable composition.

14. The electrophoretic display of claim 12 wherein said sealing composition comprises a thermoplastic or thermoset precursor.

15. An electrophoretic display which comprises:

a) two electrode plates;

b) an array of cells sandwiched between the two electrode plates, where each of said cells comprises;

(i) side walls, the side walls having a top surface;

(ii) an electrophoretic fluid filled therein which comprises charged particles dispersed in a dielectric solvent or solvent mixture; and

(iii) a polymeric sealing layer which is in contact with both the top surface of said side walls and said electrophoretic fluid and is curved towards the electrophoretic fluid.

16. The display of claim 15 further comprising an adhesive layer between said polymeric sealing layer and one of said electrode plates.

17. The display of claim 16 wherein said polymeric sealing layer is formed from a composition comprising a material selected from the group consisting of polybutadiene, polyisoprene, styrene-butadiene copolymers, olefin rubbers, nitrile rubbers, polyvalent acrylate, polyvalent methacrylate, cyanoacrylates, polyvalent vinyl, polyvalent epoxide, polyvalent isocyanate, polyvalent allyl, and oligomers or polymers containing crosslinkable functional groups.

18. The display of claim 17 wherein said polymeric sealing layer is formed of a composition comprising polyvalent isocyanate.

19. The display of claim 17 wherein said composition further comprises one or more additives selected from the group consisting of surfactants, antioxidants, initiators, catalysts, crosslinkers, thickeners, polymer binders, pigments, dyes and fillers.

20. The display of claim 19 wherein said filler is silica, CaCO₃, BaSO₄, TiO₂, metal particles and their oxides or carbon black.

21. The display of claim 16 wherein said adhesive layer is a pressure sensitive adhesive, a hot melt adhesive or a heat, moisture, or radiation curable adhesive.

22. The display of claim 21 wherein said adhesive layer is formed from a material selected from a group consisting of acrylics, styrene-butadiene copolymers, styrene-butadiene-styrene block copolymers, styrene-isoprene-styrene block copolymers, polyvinylbutyral, cellulose acetate butyrate, polyvinylpyrrolidofle, polyurethanes, polyamides, ethylene-vinylacetate copolymers, epoxides, multifunctional acrylates, vinyls, vinylethers, and their oligomers, polymers, and copolymers.

23. The display of claim 22 wherein said adhesive layer is formed from a polyurethane, epoxide, multifunctional vinyl or acrylate.

24. The display of claim 16 wherein said sealing layer and said adhesive layer are formed from the same material.

25. The display of claim 24 wherein said same material is a radiation curable material.

26. The display of claim 16 wherein said sealing layer and said adhesive layer are formed from different materials.

27. The electrophoretic display of claim 15 wherein said polymeric sealing layer is formed from a sealing composition having a specific gravity lower than that of the electrophoretic fluid.

28. The electrophoretic display of claim 27 wherein said sealing composition is a UV curable composition.

29. The electrophoretic display of claim 27 wherein said sealing composition