Biodegradable composition and products prepared therefrom

• US 6,835,764 B2
• Filed: 01/13/2003
• Issued: 12/28/2004
• Est. Priority Date: 07/14/2000
• Status: Expired due to Fees

• Current Assignee: Bio-Deg Moulding Pty Limited
• Original Assignee: Bio-Deg Moulding Pty Limited
• Inventors: Hill, Allan Leon Sydney, Leckey, Richard Anthony, Reichle, Alan John
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US10/312,567
• Publication Number:
  US 20040028927A1
• Time in Patent Office: 715 Days
• Field of Search: 524/13, 524/15, 524/451, 524/494, 523/223
• US Class Current: 524/15
• CPC Class Codes: B27N 3/00 Manufacture of substantially flat articles, e.g. boards, from particles or fibres
• CPC Class Codes: B27N 3/002 characterised by the type of binder compositions of macromolecular compounds C08L
• CPC Class Codes: Y10T 428/3179 Next to cellulosic

Abstract

This invention relates to a composition which can be used to form a wood substitute. The composition comprises 30 to 70% (volume by volume) of a high molecular weight aliphatic polyester and comminuted cellulose-containing plant material, wherein the aliphatic polyester comprises 1,4-butanediol condensed with adipic acid and/or succinic acid. The invention also provides for producing wood substitute from the composition. The wood substitute has characteristics of natural wood. Articles made from the wood substitute are biodegradable and do not give off toxic fumes when combusted.

Claims

1. A composition for forming a wood substitute, the composition comprising 30 to 70% (volume by volume) of a high molecular weight aliphatic polyester and the balance a comminuted cellulose-containing plant material, wherein said aliphatic polyester comprises 1,4-butanediol condensed with adipic acid and/or succinic acid and said comminuted cellulose-containing plant material is a dry material and said comminuted cellulose-containing plant material is a dry material.

2. The composition according to claim 1, wherein said aliphatic polyester has a weight average molecular weight (Mw) in the range of 40,000 to 300,000.

3. The composition according to claim 1, wherein said aliphatic polyester is poly (butylene) succinate.

4. The composition according to claim 1, wherein said aliphatic polyester is poly (butylene) succinate/adipate.

5. The composition according to claim 1, wherein said cellulose-containing plant material is from the epidermis or cortex of a plant, or is seed coat material.

6. The composition according to claim 5, wherein said cellulose-containing plant material is nutshell material.

7. The composition according to claim 6, wherein said nutshell is pecan nutshell.

8. The composition according to claim 5, wherein said cellulose-containing plant material is saw dust, milling waste or sugar cane bagasse.

9. The composition according to claim 1, wherein particles of said comminuted cellulose-containing plant material have a size range of a fine powder up to about 5 mm.

10. The composition according to claim 1, wherein said composition further includes a colouring agent and/or a weight minimisation agent.

11. The composition according to claim 10, wherein said colouring agent is selected from fly-ash, talc and colouring pigments.

12. The composition according to claim 10, wherein said weight minimisation agent is a micro-balloon, a hollow glass sphere or a foaming agent.

13. The composition according to claim 1, wherein said composition further includes a plant growth compound and/or plant fibre.

14. The composition according to claim 13, wherein said plant growth compound is manure and/or fertiliser.

19. A wood substitute formed from the composition according to claim 1.

15. A process for producing a wood substitute, the process comprising the steps of:

a) heating a composition comprising 30 to 70% (volume by volume) of a high molecular weight aliphatic polyester and the balance a comminuted cellulose-containing plant material at a temperature of 110 to 180°

C. to provide a flowable material, wherein said aliphatic polyester comprises 1,4-butanediol condensed with adipic acid and/or succinic acid and said comminuted cellulose-containing plant material is a dry material;

b) forming said heated material from step (a) into a desired product; and

c) allowing said product to cool to at least ambient temperature.

16. The process according to claim 15, wherein said forming into a desired product in step (b) is by compression, vacuum, injection or rotation moulding.

17. The process according to claim 15, wherein said forming into a desired product in step (b) is by extrusion.

18. The process according to claim 15, wherein said cooling in step (c) is mechanically aided.

20. A wood substitute article prepared by the process according to claim 15.

21. A composition for forming a wood substitute, the composition comprising 50 to 70% (volume by volume) of poly (butylene) succinate having a weight average molecular weight (Mw) in the range of 40,000 to 300,000 as the sole binder substance and the balance is a comminuted cellulose-containing plant material.

22. A composition according to claim 21, wherein said comminuted cellulose-containing plant material is comminuted pecan nutshell.