Method for linking two plastic work pieces without using foreign matter

• US 6,838,156 B1
• Filed: 03/29/2000
• Issued: 01/04/2005
• Est. Priority Date: 09/23/1999
• Status: Expired due to Term

• Current Assignee: Monogram Biosciences, Inc. (Laboratory Corporation Of America Holdings)
• Original Assignee: Aclara Biosciences, Inc (Laboratory Corporation Of America Holdings)
• Inventors: Jöhnck, Matthias, Neyer, Andreas
• Primary Examiner(s): Loney, Donald J.
• Application Number:
  US10/088,922
• Time in Patent Office: 1,742 Days
• Field of Search: 156/306, 156/311, 156/322, 156/272.2, 156/272.3, 156/275.1, 156/273.3, 156/272.8, 264/405, 264/445, 264/446, 264/482, 264/488, 428/172, 428/178, 428/188, 73/615.6, 210/203, 366/340, 422/101, 422/103
• US Class Current: 428/172
• CPC Class Codes: B29C 65/02 by heating, with or without pressure
• CPC Class Codes: B29C 66/0242 Heating, or preheating, e.g. drying B29C66/3464 takes precedence
• CPC Class Codes: B29C 66/028 Non-mechanical surface pre-treatments, i.e. by flame treatment, electric discharge treatment, plasma treatment, wave energy or particle radiation B29C65/14 takes precedence; non-mechanical surface treatment of plastics in general B29C59/08 - B29C59/16
• CPC Class Codes: B29C 66/1122 Single lap to lap joints, i.e. overlap joints B29C66/45, B29C66/472, B29C66/52272 take precedence
• CPC Class Codes: B29C 66/53461 joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies
• CPC Class Codes: B29C 66/71 characterised by the composition of the plastics material of the parts to be joined welding bar compositions B29C65/125
• CPC Class Codes: B29C 66/712 the composition of one of the parts to be joined being different from the composition of the other part
• CPC Class Codes: B29C 66/73117 Tg, i.e. glass transition temperature
• CPC Class Codes: B29C 71/04 by wave energy or particle radiation , e.g. for curing or vulcanising preformed articles during moulding, e.g. in a mould B29C35/08
• CPC Class Codes: B29K 2033/12 Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
• CPC Class Codes: B29K 2069/00 Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• CPC Class Codes: B29L 2031/756 Microarticles, nanoarticles
• CPC Class Codes: C08J 5/121 by heating
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/24661 Forming, or cooperating to form cells

Abstract

The invention relates to a method for linking two adjacent plastic work pieces (2, 3). The inventive method is characterized in that the intended contact zone (K) of at least one of the two work pieces (2) with which the latter adjoins to the other work piece (3) is at least partially subjected to a high-energy radiation to such an extent that the glass transition temperature is reduced in a marginal zone (R). The two work pieces (2, 3) are brought in the desired position relative to each other. For establishing the connection of the two work pieces (2, 3) at least the marginal zone (R) modified by the previous radiation process is heated at least in its surface area to a temperature that is higher than the glass transition temperature of the marginal zone (R) modified by the radiation process but lower than the glass transition temperature of the zones of the work pieces (2, 3) that have not been modified. The invention also relates to an article (1) produced according to the inventive method that consists of two work pieces (2, 3) that are linked without using foreign matte. The inventive article is characterized in that recesses (V), especially channel-shaped recesses, are introduced in at least one contact zone (K) of the two work pieces (2).

Claims

1. Method for non-adhesive bonding of two contiguous plastic work pieces (2, 3;

5, 6) characterized in that;

the intended contact surface (K) of at least one of the two work pieces (2, 5 or 3, 6) by which it borders on the other work piece (3, 6 or 2, 5) is at least in some sections subjected to a high-energy radiation which causes the lowering of the glass transition temperature in a marginal layer (R, R′

),

the two work pieces (2, 3;

5, 6) are brought into a mutual position according to the intended use, and

subsequently, to produce the bond of the two work pieces (2, 3;

5, 6) at least the modified marginal layer (R, R′

) in the area of its surface is heated to a temperature which is above the glass transition temperature of the marginal layer (R, R′

) modified by radiation, but below that of the unmodified areas of the respective work piece (2, 3;

5, 6).

2. Article (1, 4) formed of two work pieces (2, 3;

5, 6) non-adhesively bonded together, produced according to claim 1, characterized in that in at least one contact surface (K) of the two work pieces (2, 5), recesses (V), in particular channel-like recesses, are provided.

3. A hot-melt adhesion method for bonding two plastic work pieces, each work piece having an intended contact surface by which the two work pieces bond, the method comprising the steps of:

subjecting at least some sections of the intended contact surface of at least one of the work pieces to a high-energy radiation that causes the lowering of a glass transition temperature of such work piece in a marginal layer to produce a modified marginal layer;

contacting the intended contact surfaces of the two work pieces; and

heating at least the modified marginal layer to a temperature above the glass transition temperature of the modified marginal layer but below that of the unmodified areas of the respective work piece so that a bond is formed between the two work pieces.

4. The hot-melt adhesion method of claim 3, wherein the entirety of said intended contact surface of at least one of said work pieces is subjected to said high-energy radiation.

5. The hot-melt adhesion method of claim 3, wherein at least some sections of both of said intended contact surfaces are subjected to said high-energy radiation to produce said modified marginal layer.

6. The hot-melt adhesion method of claim 3, wherein said high-energy radiation is selected from the group of UV, laser, X ray and synchrotron radiation.

7. The hot-melt adhesion method of claim 3, wherein both of said work pieces are heated in said heating step.

8. The hot-melt adhesion method of claim 3, wherein said intended contact surface contains microstructure or nanostructure recesses, and wherein said modified marginal layer is a fraction of a μ

m so that the microstructure or nanostructure recesses remain dimensionally stable during said step of heating.

9. The hot-melt adhesion method of claim 8, further characterized in that said recesses are not pinched or plugged as a result of said step of heating.

10. The hot-melt adhesion method of claim 3, wherein said work pieces are continuous films.

11. The hot-melt adhesion method of claim 3, 8, or 10, wherein said heating step further includes holding said work pieces under pressure in relation to each other.

12. A hot-melt adhesion method for bonding two plastic work pieces, each work piece having an intended contact surface by which the two work pieces bond and wherein one work piece is comprised of microstructure or nanostructure recesses in the contact surface and the other work piece includes electrodes on its contact surface, the method comprising the steps of:

subjecting at least some sections of the intended contact surface of at least one of the work pieces to a high-energy radiation that causes the lowering of a glass transition temperature of such work piece in a marginal layer to produce a modified marginal layer;

contacting the intended contact surfaces of the two work pieces; and

heating at least the modified marginal layer to a temperature above the glass transition temperature of the modified marginal layer but below that of the unmodified areas of the respective work piece while the two work pieces are under pressure in relation to each other so that a bond is formed between the two work pieces.

13. An article for microfluidics applications comprising:

a first and a second plastic work piece, each having a contact surface by which the two work pieces are hot-melt adhesion bonded together;

wherein

microstructure or nanostructure recesses are provided in the contact surface of the first work piece; and

a modified marginal layer is produced by high-energy radiation in at least a section of at least one of the contact surfaces, such that the modified marginal layer is characterized by a glass transition temperature lower than that of unmodified areas of the respective work piece.

14. The article according to claim 13, wherein electrodes are provided on said contact surface of said second work piece.

15. The article according to claim 13 or 14, wherein said modified marginal layer is a fraction of a μ

m so that the microstructure or nanostructure recesses remain dimensionally stable.

16. The article according to claim 15, wherein said microstructure or nanostructure recesses are further comprised of a filter structure.

17. The article according to claim 15, wherein said microstructure or nanostructure recesses are used as a microanalysis unit.

18. The article according to claim 13, characterized in that said recesses are not pinched or plugged as a result of said bonding.

19. The article according to claim 13, wherein said two work pieces are made of the same material.

20. The article according to claim 13, wherein at least one of said work pieces is made of one of the group consisting of PMMA, polycarbonate and polymethacryl.