Nuclear magnetic resonance apparatus and methods for analyzing fluids extracted from earth formation

• US 6,841,996 B2
• Filed: 01/22/2003
• Issued: 01/11/2005
• Est. Priority Date: 01/22/2003
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Madio, David P., Gaylor, Richard W., Freedman, Robert, Kleinberg, Robert L.
• Primary Examiner(s): ARANA, LOUIS M
• Application Number:
  US10/349,011
• Publication Number:
  US 20040140800A1
• Time in Patent Office: 720 Days
• Field of Search: 324/303, 324/306, 324/307, 324/309, 324/318, 324/322
• US Class Current: 324/303
• CPC Class Codes: G01N 24/081 Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
• CPC Class Codes: G01V 3/32 operating with electron or nuclear magnetic resonance

Abstract

The present invention discloses a method and apparatus to make a nuclear magnetic resonance measurement on a flowing fluid using varied wait times. In one method, NMR measurements are made by: a) flowing the fluid through a static magnetic field; b) applying a group of oscillating magnetic field pulses to the flowing fluid, wherein the group of pulses is comprised of an initial pulse and one or more refocusing pulses; c) detecting magnetic resonance signals from the flowing fluid; d) after a wait time, repeating (b) and (c) one or more times, wherein at least two of the repetitions have varied wait times; and e) analyzing the detected magnetic resonance signals to extract information about the flowing fluid. Further, varied wait time measurements may be useful in determining the flow rate of the sample.

Claims

1. A method of making a nuclear magnetic resonance measurement on a flowing fluid comprising:

a) flowing the fluid through a static magnetic field;

b) applying a group of oscillating magnetic field pulses to the flowing fluid, wherein each group of pulses is comprised of an initial pulse and one or more refocusing pulses, and wherein the group of pulses further comprise a spoiler rf pulse;

c) detecting magnetic resonance signals from the flowing fluid;

d) after a wait time, repeating (b) and (c) one or more times, wherein at least two of the repetitions have varied wait times; and

e) analyzing the detected magnetic resonance signals to extract information about the flowing fluid.

2. The method of claim 1, wherein the detected magnetic resonance signals are corrected for spin dynamic effects.

3. The method of claim 1, wherein detecting magnetic resonance signals comprises detecting magnetic resonance spin echoes after each refocusing pulse.

4. The method of claim 3, wherein analyzing the detected magnetic resonance signals comprises analyzing the first spin echo from each group of pulses.

5. The method of claim 1, wherein each repetition has a progressively longer wait time.

6. The method of claim 1, wherein the fluid is extracted from an earth formation.

7. The method of claim 1, wherein analyzing the detected magnetic resonance signals includes determining initial polarization buildup.

8. The method of claim 1, wherein the static magnetic field includes a magnetic field gradient and wherein analyzing the detected magnetic resonance signals includes measuring the flow rate of the flowing fluid.

9. The method of claim 8, wherein measuring the flow rate includes monitoring the magnetic resonance signals for a change in frequency between wait times.

10. The method of claim 8, further comprising comparing the amplitude of an early detected echo to one or more subsequent echoes to determine the onset of turbulence in the flowing fluid.

11. The method of claim 10, wherein the first echo is compared to one or more later echoes.

12. The method of claim 8, further comprising comparing the amplitude of the free induction decay following the initial pulse to one or more subsequent echoes to determine the onset of turbulence.

13. The method of claim 8, wherein detecting magnetic resonance signals comprises separately detecting magnetic resonance spin echoes after each refocusing pulse;

and wherein measuring the flow rate comprises analyzing odd and even echoes to determine flow rate.

14. The method of claim 13, wherein analyzing the odd and even echoes includes analyzing the phase of the odd and even echoes.

15. The method of claim 13, wherein analyzing the odd and even echoes includes analyzing the amplitude of the odd and even echoes.

16. The method of claim 13, further comprising detecting the onset of turbulence in the flowing fluid.

17. The method of claim 16, wherein detecting the onset of turbulence is comprised of comparing the amplitude of the first detected echo to subsequent echoes.

18. The method of claim 16, wherein detecting the onset of turbulence is comprised of comparing the amplitude of the free induction decay following the initial pulse to subsequent echoes.

19. A method of analyzing a fluid in a downhole environment comprising:

a) introducing a fluid sampling tool into a well bore that traverses an earth formation;

b) using the fluid sampling tool to extract the fluid from the earth formation into a flow channel within the tool;

c) flowing the fluid through a static magnetic field;

d) applying one or more groups of oscillating magnetic field pulses to the fluid in the flow channel, wherein the group of pulses comprises an initial pulse followed by one or more refocusing pulses, wherein at least two groups of pulses are generated after a varied wait time, and wherein the group of pulses further comprise a spoiler rf pulse;

e) detecting from the flowing fluid magnetic resonance signals within each group of pulses; and

f) analyzing the detected signals to extract information about the flowing fluid.

20. The method of claim 19, wherein each repetition has a progressively longer wait time.

21. An apparatus for analyzing a fluid in a downhole environment comprising:

a) means for extracting the fluid from an earth formation into a flow channel within a well logging tool;

b) means for generating a static magnetic field within the flow channel;

c) means for generating one or more groups of oscillating magnetic field pulses to the fluid in the flow channel, wherein each group of pulses is comprised of an initial pulse followed by one or more refocusing pulses, wherein at least two groups of pulses are generated after a varied wait time, and wherein the group of pulses further comprise a spoiler rf pulse;

d) means for detecting magnetic resonance signals; and

e) means for analyzing the detected magnetic resonance signals.

22. The apparatus of claim 21, wherein each repetition has a progressively longer wait time.

23. The apparatus of claim 21, wherein said static magnetic field is generated by a series of magnets comprising an Halbach array.

24. The apparatus of claim 23, wherein one or more steel straps are inserted as one or more pole faces of the Halbach array.

25. The apparatus of claim 21, further comprising means to monitor the onset of turbulence of the fluid in the flow channel.

26. The apparatus of claim 25, further comprising means to separately detect magnetic resonance signals of even oscillating pulses and odd oscillating pulses.

27. The apparatus of claim 21, wherein the static magnetic field includes a magnetic field gradient and further including means to determine the flow rate of the fluid in the flow channel.

28. A method of making a nuclear magnetic resonance measurement on a flowing fluid comprising:

a) flowing the fluid through a static magnetic field, wherein the static magnetic field includes a magnetic field gradient;

b) applying a group of oscillating magnetic field pulses to the flowing fluid, wherein each group of pulses is comprised of an initial pulse and one or more refocusing pulses;

c) detecting magnetic resonance signals from the flowing fluid;

d) after a wait time, repeating (b) and (c) one or more times, wherein at least two of the repetitions have varied wait times; and

e) analyzing the detected magnetic resonance signals to measure the flow rate of the flowing fluid by monitoring the magnetic resonance signals for a change in frequency between wait times.