Slidably movable member and method of producing same

• US 6,844,068 B1
• Filed: 04/07/2000
• Issued: 01/18/2005
• Est. Priority Date: 04/09/1999
• Status: Expired due to Term

• Current Assignee: Nissan Motor Co., Ltd., Shojiro Miyake
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Mabuchi, Yutaka, Kano, Makoto, Yasuda, Yoshiteru, Miyake, Shojiro
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US09/545,181
• Time in Patent Office: 1,747 Days
• Field of Search: 428/408, 428/217, 428/141, 428/142, 428/174, 428/336, 428/698, 428/701, 428/457, 428/469, 292/137, 403/135, 280/86.753
• US Class Current: 428/408
• CPC Class Codes: F01L 1/143 for use with overhead camshafts
• CPC Class Codes: F01L 1/205 by means of shims or the like
• CPC Class Codes: F01L 2301/00 Using particular materials
• CPC Class Codes: F01L 2810/02 Lubrication
• CPC Class Codes: F16C 33/043 Sliding surface consisting mainly of ceramics, cermets or hard carbon, e.g. diamond like carbon [DLC]
• CPC Class Codes: Y10T 292/096 Sliding
• CPC Class Codes: Y10T 403/32737 including liner, shim, or discrete seat
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/24364 with transparent or protective coating
• CPC Class Codes: Y10T 428/24628 Nonplanar uniform thickness material
• CPC Class Codes: Y10T 428/24983 Hardness
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A slidably movable member such as an adjusting shim used in a valve operating mechanism of an internal combustion engine of an automotive vehicle. The slidably movable member is used in contact with lubricating oil and comprises a substrate. A hard carbon-based film is coated on a surface of the substrate. The hard carbon-based film has a surface section which contains at least one of nitrogen and oxygen in an amount ranging from 0.5 to 30 at % and/or hydrogen in an amount of not more than 10 at %.

Claims

1. A system comprising:

a slidable member;

lubricating oil for an internal combustion engine in contact with said slidable member, the lubricating oil containing one or more oiliness agents;

wherein the slidable member includes a substrate selected from the group consisting of silicon nitride and a metal; and

a hard carbon-based film coated on a surface of said substrate, said hard carbon-based film having been applied by a process that produces in the surface of the film a sufficient number of polar groups to adsorb the oiliness agents from the lubricating oil to a degree to produce a lowered coefficient of friction;

wherein the hard carbon-based film has a coefficient of friction of not higher than 0.07 and wherein the hard carbon-based film has a surface roughness, Ra, of not higher than 0.1 μ

m.

2. A system as claimed in claim 1, wherein the process for applying the hard carbon-based film is selected from the group consisting of a process that provides at least one of (a) introducing into the surface of the film at least one of nitrogen and oxygen in an amount ranging from 0.5 to 30 at %;

and (b) lowering the content of hydrogen in the surface of the film.

3. A system as claimed in claim 1, wherein the process for applying the hard carbon-based film is selected from the group consisting of a carbon ion beam process in which hydrogen plasma is not used at least during formation of the hard carbon-based film, a thermal chemical vapor deposition process which produces a diamond polycrystal, an ion plating process, and a sputtering process.

4. A system as claimed in claim 1, wherein the hard carbon-based film has a thickness of 1 to 10 μ

m.

5. A system as claimed in claim 1, wherein the substrate comprises steel.

6. A system comprising:

a) a metal or silicon nitride substrate;

b) an oiliness agent; and

c) a hard carbon-based film formed on the substrate, the hard carbon-based film comprising a sufficient number of polar groups to adsorb the oiliness agent to a degree to produce a lowered coefficient of friction;

wherein the hard carbon-based film has a coefficient of friction of not higher than 0.07 and wherein the hard carbon-based film has a surface roughness, Ra, of not higher than 0.1 μ

m.

7. A system according to claim 6, wherein said hard carbon-based film is a film selected from the group consisting of amorphous carbon and diamond like carbon.

8. A system according to claim 6, wherein the hard carbon-based film is a diamond polycrystal film.

9. A system according to claim 8, wherein the diamond polycrystal film is produced by thermal chemical vapor deposition.

10. A system according to claim 6, wherein the hard carbon-based film is produced by a process selected from the group consisting of a carbon ion beam process in which hydrogen plasma is not used during formation of the hard carbon-based film, a thermal chemical vapor deposition process which produces a diamond polycrystal, an ion plating process, and a sputtering process.

11. A system according to claim 6, wherein the substrate comprises steel.

12. A slidable member comprising the system of claim 6.

13. An adjusting shim for an internal combustion engine comprising a slidable member according to claim 12.

14. A motor vehicle comprising an adjusting shim according to claim 13.

15. A motor vehicle according to claim 14, wherein the adjusting shim is mounted on a valve lifter for an engine valve.

16. A motor vehicle according to claim 15, wherein the valve lifter forms part of a valve operating mechanism.

17. A motor vehicle according to claim 16, wherein the adjusting shim is arranged in slidable contact with a camshaft.

18. A motor vehicle according to claim 17, wherein a lubricating oil comprising the oiliness agent is present between a surface section of the hard carbon-based film of the adjusting shim and the camshaft.

19. A motor vehicle according to claim 15, wherein the adjusting shim is in contact with a lubricating oil comprising an oiliness agent.

20. A system comprising:

a) a metal or silicon nitride substrate;

b) a hard carbon-based film formed on the substrate, the hard carbon-based film having been applied by a process that produces in a surface of the film an increased concentration of polar groups; and

c) an agent which adsorbs to the surface of the hard carbon-based film as a result of the presence of the polar groups and which thereby decreases the friction coefficient of the surface;

wherein the hard carbon-based film has a coefficient of friction of not higher than 0.07 and wherein the hard carbon-based film has a surface roughness, Ra, of not higher than 0.1 μ

m.

21. A system comprising:

a) a metal or silicon nitride substrate having a film formed thereon;

b) a lubricant comprising an oiliness agent in contact with the film; and

c) said film comprising a hard carbon-based film formed on the substrate, the hard carbon-based film having (i) a surface roughness of not higher than 0.1 μ

m, (ii) a thickness of 1 to 10 μ

m, and (iii) comprising a sufficient number of polar groups to adsorb the oiliness agent to produce a coefficient of friction, Ra, of not higher than 0.07.

22. A system according to claim 21, wherein the hardness, Hv, of the hard carbon-based film is not lower than 1000.