Continuous aspiration process for manufacture of ultra-fine particle HNS

• US 6,844,473 B1
• Filed: 02/18/2004
• Issued: 01/18/2005
• Est. Priority Date: 02/18/2004
• Status: Expired due to Fees

• Current Assignee: BWXT Pantex LLC (Honeywell International Inc.)
• Original Assignee: BWXT Pantex LLC (Honeywell International Inc.)
• Inventors: Sproul, Maury L., Quinlin, William T., Thorpe, Raymond, Cates, Dillard M.
• Primary Examiner(s): PARSA, JAFAR F
• Application Number:
  US10/783,533
• Time in Patent Office: 335 Days
• Field of Search: 568/931
• US Class Current: 568/931
• CPC Class Codes: C06B 25/04 the nitrated compound being an aromatic
• CPC Class Codes: C07C 281/02 Compounds containing any of the groups , e.g. carbazates
• CPC Class Codes: C07C 281/20 the two nitrogen atoms of the functional groups being doubly-bound to each other, e.g. azoformamide

Abstract

A process for the manufacture of ultra-fine-particle hexanitrostilbene (HNS). Hexanitrostilbene is mixed in n-methylpyrrolidone (NMP) and the solution is steam heated for approximately one hour. The solution is rapidly mixed with cold water by means of drawing it through an aspirator through which water is flowing. The produced slurry is captured in a receiver and then filtered through a 0.45-micron filter. The recovered HNS product is then freeze dried.

Claims

1. A process for the manufacture of ultra-fine-particle hexanitrostilbene, comprising the steps:

a. mixing hexanitrostilbene with n-methylpyrrolidone at a ratio of 15 grams hexanitrostilbene per 400 ml n-methylpyrrolidone;

b. heating the mixture to a temperature of 82 degrees Celsius;

c. mixing the heated solution with cold water by aspiration;

d. capturing the resulting slurry in a receiver;

e. filtering the slurry; and

f. drying the filtered slurry.

2. The process of claim 1, wherein the step of heating the mixture is held for a time period of approximately one hour.

3. The process of claim 1, wherein the step of mixing the heated solution with cold water is accomplished by drawing it through an aspirator through which water is flowing.

4. The process of claim 1, wherein the step of filtering the slurry uses a 0.45-micron filter.

5. The process of claim 1, wherein the step of drying the filtered slurry is accomplished using freeze drying.

6. A process for the manufacture of ultra-fine-particle hexanitrostilbene, comprising the steps:

a. mixing hexanitrostilbene with n-methylpyrralidone at a ratio of 15 grams hexanitrostilbene per 400 ml n-methylpyrralidone;

b. steam heating the mixture to a temperature of 82 degrees Celsius for a time period of approximately one hour;

c. mixing the heated solution with cold water by drawing it through an aspirator through which water is flowing;

d. capturing the resulting slurry in a receiver;

e. filtering the slurry using a 0.45-micron filter; and

f. freeze drying the filtered slurry.