Method of reducing intake valve deposits in a direct injection engine

• US 6,846,782 B2
• Filed: 04/04/2003
• Issued: 01/25/2005
• Est. Priority Date: 04/04/2003
• Status: Active Grant

• Current Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Inventors: Calder, Raymond M.
• Primary Examiner(s): McAvoy, Ellen M.
• Application Number:
  US10/407,983
• Publication Number:
  US 20040198614A1
• Time in Patent Office: 662 Days
• Field of Search: 508/591, 508/293
• US Class Current: 508/293
• CPC Class Codes: C10M 111/02 at least one of them being a non-macromolecular organic compound
• CPC Class Codes: C10M 111/04 at least one of them being a macromolecular organic compound
• CPC Class Codes: C10M 169/044 the additives being a mixture of non-macromolecular and macromolecular compounds
• CPC Class Codes: C10M 169/047 the additives being a mixture of compounds of unknown or incompletely defined constitution and macromolecular compounds
• CPC Class Codes: C10M 2203/1006 used as base material
• CPC Class Codes: C10M 2205/0265 used as base material
• CPC Class Codes: C10M 2205/0285 used as base material
• CPC Class Codes: C10M 2207/2825 used as base material
• CPC Class Codes: C10M 2207/2835 used as base material
• CPC Class Codes: C10M 2207/3025 used as base material
• CPC Class Codes: C10M 2215/28 Amides; Imides
• CPC Class Codes: C10M 2223/042 Metal salts thereof
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10N 2030/02 Pour-point; Viscosity index
• CPC Class Codes: C10N 2030/04 Detergent property or dispersant property
• CPC Class Codes: C10N 2030/42 Phosphor free or low phosphor content compositions
• CPC Class Codes: C10N 2030/43 Sulfur free or low sulfur content compositions
• CPC Class Codes: C10N 2030/45 Ash-less or low ash content
• CPC Class Codes: C10N 2040/252 Diesel engines
• CPC Class Codes: C10N 2040/253 Small diesel engines
• CPC Class Codes: C10N 2040/255 : Gasoline engines

Abstract

This invention relates to a method of reducing intake valve deposits in a direct injection engine, the method comprising lubricating the engine with a lubricating oil composition comprising a base oil mixture, the base oil mixture comprising (i) a Group III, a Group IV oil, or a mixture thereof, in combination with (ii) a synthetic ester oil, the weight ratio of (i) to (ii) being from about 0.2:1 to about 6:1.

Claims

1. A method of reducing intake valve deposits in a direct injection engine, the method comprising lubricating the engine with a lubricating oil composition comprising a base oil mixture, the base oil mixture comprising (i) a Group III oil, a Group IV oil, or a mixture thereof, in combination with (ii) a synthetic ester oil, the weight ratio of (i) to (ii) being from about 0.2:

1 to about 6;

1.

2. The method of claim 1 wherein the direct injection engine is a spark ignition engine.

3. The method of claim 1 wherein the direct injection engine is a compression ignition engine.

4. The method of claim 1 wherein the lubricating oil composition has a viscosity of up to about 16.3 cSt at 100°

C.

5. The method of claim 1 wherein the lubricating oil composition has an SAE Viscosity Grade of 5, 10, 20, 30, 40, 50, 60, 0W-20, 0W-30, 0W-40, 0W-50, 0W-60, 5W-20, 5W-30, 5W-40, 5W-50, 5W-60, 10W-20, 10W-30, 10W-40, 10W-50, 15W-20, 15W-30, 15W-40, 15W-50, 20W-20, 20W-30, 20W-40 or 20W-50.

6. The method of claim 1 wherein the Group III oil has a saturates content of at least about 95% by weight and a sulfur content of up to about 0.02% by weight.

7. The method of claim 1 wherein the Group IV oil is a polyalphaolefin oil derived from one or more monomers having about 4 to about 30 carbon atoms.

8. The method of claim 1 wherein the Group IV oil is a polyalphaolefin oil having a viscosity of about 2 to about 15 cSt at 100°

C.

9. The method of claim 1 wherein the synthetic ester oil is derived from a monocarboxylic acid or a dicarboxylic acid and an alcohol or a polyol.

10. The method of claim 1 wherein the synthetic ester oil comprises dibutyl adipate, di(2-ethylhexyl) sebacate, di-n-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecyl azelate, dioctyl phthalate, didecyl phthalate, dieicosyl sebacate, 2-ethylhexyl diester of linoleic acid dimer, an ester formed by reacting one mole of sebacic acid with two moles of tetraethylene glycol and two moles of 2-ethylhexanoic acid, or a mixture of two or more thereof.

11. The method of claim 1 wherein the synthetic ester oil derived from a monocarboxylic acid of about 8 to about 10 carbon atoms and trimethyol propane.

12. The method of claim 1 wherein the synthetic ester oil is derived from a monocarboxylic acid of about 12 to about 20 carbon atoms and an alcohol of about 12 to about 20 carbon atoms.

13. The method of claim 1 wherein the lubricating oil composition further comprises of an acylated nitrogen-containing compound having a substituent of at least about 10 aliphatic carbon atoms.

14. The method of claim 13 wherein the acylated nitrogen-containing compound is derived from a carboxylic acylating agent and at least one amino compound containing at least one —

NH—

group, the acylating agent being linked to the amino compound through an imido, amido, amidine or salt linkage.

15. The method of claim 14 wherein the amino compound is an alkylenepolyamine represented by the formula:

wherein U is an alkylene group of from about 2 to about 10 carbon atoms;

each R is independently a hydrogen atom, a hydrocarbyl group, a hydroxy-substituted hydrocarbyl group, or an amine-substituted hydrocarbyl group containing up to about carbon atoms, with the proviso that at least one R is a hydrogen atom; and

n is 1 to about 14.

16. The method of claim 13 wherein the acylated nitrogen containing compound is a polyisobutene substituted succinimide, the ratio of succinic groups to equivalent weights of polyisobutene being in the range of about 0.6:

1 to about 1.8;

1.

17. The method of claim 13 wherein the acylated nitrogen containing compound is a polyisobutene substituted succinimide, the ratio of succinic groups to equivalent weights of polyisobutene being in the range of about 0.9:

1 to about 1.5;

1.

18. The method of claim 13 wherein the acylated nitrogen containing compound is a polyisobutene substituted succinimide, the polyisobutene substituted succinimide being derived from a polyisobutene substituted succinic anhydride or acid and at least one polyamine, the ratio of C═

O from the polyisobutene substituted succinic anhydride to N from the polyamine being up to about 1.18;

1.

19. The method of claim 13 wherein the acylated nitrogen containing compound is a polyisobutene substituted succinimide, the polyisobutene substituted succinimide being derived from a polyisobutene substituted succinic anhydride or acid and at least one polyamine, the ratio of C═

O from the polyisobutene substituted succinic anhydride to N from the polyamine being up to about 1.1;

1.

20. The method of claim 13 wherein the acylated nitrogen containing compound is a polyisobutene substituted succinimide, the polyisobutene substituted succinimide being derived from a polyisobutene substituted succinic anhydride or acid and at least one polyamine, the polyisobutene substituent having a number average molecular weight in the range of about 1500 to about 3000, the ratio of C═

O from the polyisobutene substituted succinic anhydride or acid to N from the polyamine being up to about 1;

2.

21. The method of claim 13 wherein the acylated nitrogen-containing compound is a polyisobutene substituted succinimide containing at least about 50 aliphatic carbon atoms in the polyisobutene group.

22. The method of claim 1 wherein the lubricating oil composition further comprises a Mannich condensate.

23. The method of claim 1 wherein the lubricating oil composition further comprises a metal salt of a compound represented by the formula

wherein X¹, X² and X³ and X⁴ are independently O or S, a and b are independently zero or 1, and R¹ and R² are independently hydrocarbyl groups.

24. The method of claim 1 wherein the lubricating oil composition further comprises an alkali or alkaline earth metal salt detergent.

25. The method of claim 1 wherein the lubricating oil composition further comprises at least one detergent, dispersant, corrosion-inhibiting agent, antioxidant, viscosity improving agent, EP agent, pour point depressant, friction modifier, fluidity modifier, anti-foam agent, or mixture of two or more thereof.

26. The method of claim 1 wherein the lubricating oil composition has a sulfated ash content of up to about 1.8% by weight.

27. A method of reducing intake valve deposits in a direct injection engine, the method comprising lubricating the engine with a lubricating oil composition comprising:

a base oil mixture comprising a polyalphaolefin oil and a synthetic ester oil, the weight ratio of the polyalphaolefin oil to the synthetic ester oil being about 0.2;

1 to about 6;

1; and

a polyisobutene substituted succinimide, the polyisobutene substituted succinimide being derived from a polyisobutene substituted succinic anhydride or acid and at least one polyamine, the ratio of succinic groups to equivalent weights of polyisobutene being in the range of about 0.9;

1 to about 1.8;

1, the number average molecular weight of the polyisobutene being in the range of about 750 to about 3000.

28. A method of reducing intake valve deposits in a direct injection engine, the method comprising lubricating the engine with a lubricating oil composition comprising:

a base oil mixture comprising a polyalphaolefin oil and a synthetic ester oil, the weight ratio of the polyalphaolefin oil to the synthetic ester oil being about 0.2;

1 to about 6;

1; and

a polyisobutene substituted succinimide, the polyisobutene substituted succinimide being derived from a polyisobutene substituted succinic anhydride or acid and at least one polyamine, the mole ratio of C═

O from the polyisobutene substituted succinic anhydride to N from the polyamine being up to about 1.18;

1, the number average molecular weight of the polyisobutene being in the range of about 750 to about 3000.