Control of mercury emissions from solid fuel combustion

• US 6,848,374 B2
• Filed: 06/03/2003
• Issued: 02/01/2005
• Est. Priority Date: 06/03/2003
• Status: Expired due to Term

• Current Assignee: General Electric Technology GmbH (GE Vernova, Inc.)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Srinivasachar, Srivats, Kang, Shin G.
• Primary Examiner(s): RINEHART, KENNETH
• Application Number:
  US10/453,140
• Publication Number:
  US 20040244657A1
• Time in Patent Office: 609 Days
• Field of Search: 110/345, 110/342, 110/215, 110/344, 110/165.R, 959/01, 951/34, 423/239.1, 208/85, 208/91
• US Class Current: 110/345
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 53/10 with dispersed adsorbents
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: F23J 15/003 for supplying chemicals to fumes, e.g. using injection devices
• CPC Class Codes: F23J 15/006 Layout of treatment plant
• CPC Class Codes: F23J 2215/60 Heavy metals; Compounds thereof
• CPC Class Codes: F23J 2217/102 electrostatic

Abstract

A system 26 for removing elemental mercury or mercury compounds handles carbonaceous sorbent 28 of a starter batch stored in a silo 30 in an agglomerated state. The sorbent 28 is fed by a feeder 32 to a separation device 34, which comminutes (if necessary) and de-agglomerates the sorbent particles 28 to their primary size distribution. This device 34 may be a particle-particle separator or a jet mill, where compressed air or high-pressure steam is the energy source. The de-agglomerated sorbent 28 of a contact batch created from the starter batch is conveyed by an airsteam for injection at a contact location 66 in a flue gas duct whereat carbonaceous sorbent of the contact batch adsorbs mercury from the flue gas.

Claims

1. An apparatus for removing mercury from the products of fuel conversion comprising:

means for separating a starter batch of carbonaceous sorbent into a contact batch of carbonaceous sorbent and a retained batch of carbonaceous sorbent, the contact batch of carbonaceous sorbent having a particle size distribution of carbonaceous sorbent of d₅₀<

15 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch with the particle size distribution of carbonaceous sorbent in the contact batch after separation being less than the particle size distribution of carbonaceous sorbent in the starter batch before separation and less than the particle size distribution of carbonaceous sorbent in the retained batch;

means for disposing the contact batch of carbonaceous sorbent into contact with the products of fuel conversion at a contact location such that the carbonaceous sorbent of the contact batch adsorbs mercury; and

transport means for transporting carbonaceous sorbent of the contact batch to the contact location in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than thirty (30) minutes following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch, whereby the carbonaceous sorbent of the contact batch is disposed into contact with the products of fuel conversion at the contact location with substantially no intermediate storage of the carbonaceous sorbent following the conversion of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.

2. An apparatus according to claim 1, wherein the means for separating a starter batch of carbonaceous sorbent includes particle size reducing means for reducing the particle size of carbonaceous sorbent from a relatively larger coarse particle size to a relatively smaller fine particle size.

3. An apparatus according to claim 1, wherein the means for separating a starter batch of carbonaceous sorbent is operable to create a contact batch of carbonaceous sorbent having a particle size distribution of carbonaceous sorbent of d₅₀<

8 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch.

4. An apparatus according to claim 1, wherein the means for separating a starter batch of carbonaceous sorbent is operable to create a contact batch of carbonaceous sorbent having a particle size distribution of carbonaceous sorbent of d₅₀<

4 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch.

5. An apparatus according to claim 1, and further comprising means for depositing at least one of a halogen species and an acidic species on the carbonaceous sorbent of the contact batch prior to disposing the carbonaceous sorbent of the contact batch into contact with the products of fuel conversion.

6. An apparatus according to claim 1, wherein the products of fuel conversion include fly ash generated by the combustion of coal and a means for separating carbonaceous sorbent which has absorbed mercury from the products of fuel conversion includes a classifier capable of separating carbonaceous sorbent from relatively coarser and denser fly ash.

7. An apparatus according to claim 1, wherein the products of fuel conversion include flue gases generated by the combustion of coal and the carbonaceous sorbent adsorbs at least one of elemental mercury and mercury compounds from the flue gases.

8. An apparatus according to claim 1, wherein the transport means for transporting carbonaceous sorbent of the contact batch to the contact location is operable to transport the carbonaceous sorbent of the contact batch in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than five (5) minutes following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.

9. An apparatus according to claim 1, wherein the transport means for transporting carbonaceous sorbent of the contact batch to the contact location is operable to transport the carbonaceous sorbent of the contact batch in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than one (1) minute following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.

19. An apparatus according to claim 1, and further comprising means for separating carbonaceous sorbent which has absorbed mercury from the products of fuel conversion.

20. An apparatus according to claim 1, wherein the median particle size distribution (d₅₀) of the contact batch, representing 50% of the particles by mass in the entire distribution in the contact batch, is no more than one-half (½

) of the median particle size distribution (d₅₀) of the starter batch representing 50% of the particles by mass in the entire distribution in the starter batch.

10. A method for removing mercury from the products of fuel conversion comprising:

separating a starter batch of carbonaceous sorbent into a contact batch of carbonaceous sorbent and a retained batch of carbonaceous sorbent, the contact batch of carbonaceous sorbent having a particle size distribution of carbonaceous sorbent of d₅₀<

15 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch with the particle size distribution of carbonaceous sorbent in the contact batch after separation being less than the particle size distribution of carbonaceous sorbent in the starter batch before separation and less than the particle size distribution of carbonaceous sorbent in the retained batch;

disposing the contact batch of carbonaceous sorbent into contact with the products of fuel conversion at a contact location such that the carbonaceous sorbent of the contact batch adsorbs mercury; and

transporting carbonaceous sorbent of the contact batch to the contact location in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than thirty (30) minutes following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch, whereby the carbonaceous sorbent of the contact batch is disposed into contact with the products of fuel conversion at the contact location with substantially no intermediate storage of the carbonaceous sorbent following the conversion of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.

11. A method according to claim 10, wherein separating a starter batch of carbonaceous sorbent includes reducing the particle size of carbonaceous sorbent from a relatively larger coarse particle size to a relatively smaller fine particle size.

12. A method according to claim 10, wherein separating a starter batch of carbonaceous sorbent includes creating a contact batch of carbonaceous sorbent having a primary particle size distribution of carbonaceous sorbent of d₅₀<

8 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch.

13. A method according to claim 10, wherein separating a starter batch of carbonaceous sorbent includes creating a contact batch of carbonaceous sorbent having a primary particle size distribution of carbonaceous sorbent of d₅₀<

4 microns, where d₅₀ represents 50% of the particles by mass in the entire distribution in the contact batch.

14. A method according to claim 10, and further comprising depositing at least one of a halogen species and an acidic species on the carbonaceous sorbent of the contact batch prior to disposing the carbonaceous sorbent of the contact batch into contact with the products of fuel conversion.

15. A method according to claim 10, wherein the products of fuel conversion include fly ash generated by the combustion of coal and separating carbonaceous sorbent which has absorbed mercury from the products of fuel conversion includes subjecting the products of fuel conversion to a classification process operable to separate carbonaceous sorbent from relatively coarser and denser fly ash.

16. A method according to claim 10, wherein the products of fuel conversion include flue gases generated by the combustion of coal and the carbonaceous sorbent adsorbs at least one of elemental mercury and mercury compounds from the flue gases.

17. A method according to claim 10, wherein transporting carbonaceous sorbent of the contact batch to the contact location includes transporting the carbonaceous sorbent of the contact batch in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than five (5) minutes following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.

18. A method according to claim 10, wherein transporting carbonaceous sorbent of the contact batch to the contact location includes transporting the carbonaceous sorbent of the contact batch in a manner in which, on average, at least ninety percent (90%) of the carbonaceous sorbent of the contact batch is delivered to the contact location in less than one (1) minute following the separation of the carbonaceous sorbent of the starter batch into the carbonaceous sorbent of the contact batch and the carbonaceous sorbent of the retained batch.