Optical fiber with an improved primary coating composition

• US 6,849,333 B2
• Filed: 01/25/2002
• Issued: 02/01/2005
• Est. Priority Date: 05/18/2001
• Status: Expired due to Fees

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Schissel, David N, Winningham, Michael J
• Primary Examiner(s): Dye, Rena
• Assistant Examiner(s): Gray, Jill M.
• Application Number:
  US10/056,940
• Publication Number:
  US 20030049446A1
• Time in Patent Office: 1,103 Days
• Field of Search: 385/123, 385/126, 385/128, 385/145, 427/163.2, 427/162, 428/375, 428/392, 522/96, 522/90, 522/98, 522/97
• US Class Current: 428/392
• CPC Class Codes: C03C 25/106 Single coatings
• CPC Class Codes: C08G 18/48 Polyethers
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: C08G 18/758 containing two or more cycloaliphatic rings
• CPC Class Codes: C08G 18/8175 with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament

Abstract

The present invention is directed to a radiation curable primary coating composition and an optical fiber with said coating. The primary coating preferably results in excellent mechanical and physical properties, and when coated on optical fibers in a reduction in micro-bending transmission losses over optical fibers with conventional coatings. In one embodiment of this invention, it relates to a coated optical fiber comprising an optical fiber and a radiation cured primary coating wherein the radiation cured primary coating on the optical fiber comprises an oligomer and wherein the oligomer is formed from a reaction comprising a polyol having “m” hydroxyl functional groups, wherein “n” hydroxyl groups of said polyol are terminated in forming the oligomer and “m” is greater than “n”.

Claims

1. A coated optical fiber comprising:

an optical fiber and a radiation cured coating, wherein the radiation cured coating on the optical fiber comprises an oligomer wherein the oligomer is formed from a reaction comprising a polyol having “

m”

hydroxyl functional groups, wherein “

n”

hydroxyl groups of said polyol are terminated in forming the oligomer and “

m”

is greater than “

n”

.

2. The coated optical fiber in claim 1, wherein the radiation cured coating further comprises a second oligomer.

3. The coated optical fiber in claim 1, wherein “

m”

−

“

n”

≧

about 1.

4. The coated optical fiber in claim 3, wherein “

m”

≦

4.

5. The coated optical fiber in claim 1, wherein a number average molecular weight of said oligomer is at least 6000 Daltons.

6. The coated optical fiber in claim, 1 wherein the oligomer is a (meth)acrylated urethane oligomer.

7. The coated optical fiber in claim 6, wherein the radiation cured coating has a T_g of less than about −

35°

C.

8. The coated optical fiber in claim 6, wherein the radiation cured coating has a T_g of less than about −

40°

C.

9. The coated optical fiber in claim 1, wherein the radiation cured coating has a T_g of less than about −

30°

C.

10. The coated optical fiber in claim 1, wherein the radiation cured coating includes a monomer having a functional group or groups selected from the group consisting of acrylates, methacrylates, acrylamides, N-vinyl am ides, styrenes, vinyl ethers, vinyl esters, acid esters and combinations thereof.

11. The coated optical fiber in claim 10, wherein the monomer has a viscosity of less than about 500 centipoise and the monomer is an acrylate.

12. The coated optical fiber in claim 1, wherein the radiation cured coating has a Young'"'"'s modulus of less than about 1.2 MPa.

13. The coated optical fiber in claim 1, wherein the radiation cured coating has a Young'"'"'s modulus of less than about 1.0 MPa.

14. The coated optical fiber in claim 1, wherein the radiation cured coating has a Young'"'"'s modulus of about 0.85 MPa or less.

15. The coated optical fiber in claim 1, wherein the radiation cured coating has an elongation at break of greater than about 100%.

16. The coated optical fiber in claim 15, wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.3 dB/m at a wavelength of 1310 nm, of less than about 0.35 dB/m at a wavelength of 1550 nm, and of less than about 0.55 dB/m at a wavelength of 1625 nm.

17. The coated optical fiber in claim 16, wherein the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.35 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 1.1 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 2.0 (dB/km)/% strain at a wavelength of 1625 nm.

18. The coated optical fiber in claim 1, wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.15 dB/m at a wavelength of 1550 nm, and of less than about 0.25 dB/m at a wavelength of 1625 nm.

19. The coated optical fiber in claim 18, wherein the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 0.75 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 1.4 (dB/km)/% strain at a wavelength of 1625 nm.

20. The coated optical fiber in claim 1, wherein the optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.3 dB/m at a wavelength of 1550 nm, and of less than about 1.0 dB/m at a wavelength of 1625 nm.

21. The coated optical fiber in claim 20, wherein the optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 2.0 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 4.0 (dB/km)/% strain at a wavelength of 1625 nm.

22. A coated optical fiber comprising:

an optical fiber, a radiation cured primary coating and a radiation cured secondary coating, wherein the radiation cured primary coating comprises an oligomer wherein the oligomer is formed from a reaction comprising a polyol having “

m”

hydroxyl functional groups, wherein “

n”

hydroxyl groups of said polyol are terminated in forming the oligomer and “

m”

is greater than “

n”

, and has a T_g of less than about −

30°

C., a Young'"'"'s modulus of less than about 1.0 MPa, a tensile strength of at least 50% of the modulus and an elongation to break of at least about 100%.

23. The coated optical fiber in claim 22, wherein the radiation cured primary coating has a T_g of less than about −

40°

C., a Young'"'"'s modulus of less than about 1.0 MPa, a tensile strength of at least 50% of the modulus and an elongation to break of at least about 100%.

24. The coated optical fiber in claim 22, wherein the radiation cured primary coating comprises an oligomer wherein a number average molecular weight of said oligomer is at least 6000 Daltons.

25. The coated optical fiber in claim 22, wherein the radiation cured secondary coating has a Young'"'"'s modulus greater than the Young'"'"'s modulus of the radiation cured primary coating.

26. The coated optical fiber an claim 25, wherein the radiation cured secondary coating has a Young'"'"'s modulus of greater than about 600 Mpa.

27. The coated optical fiber in claim 22, wherein “

m”

−

“

n”

≧

about 1 and “

m”

≦

about 4.

28. A coated optical fiber comprising:

an optical fiber,

a radiation cured primary coating and

a radiation cured secondary coating

wherein the radiation cured primary coating is the cured product of a bulk composition comprising;

an acrylated urethane oligomer,

an ethylenically unsaturated monomer and

a photoinitiator;

wherein the oligomer is formed from a reaction comprising a polyol having “

m”

hydroxyl functional groups, wherein “

n”

hydroxyl groups of said polyol are terminated in forming the oligomer and “

m”

is greater than “

n”

, and said polyol has a number average molecular weight of at least 4000 Daltons;

wherein the ethylenically unsaturated monomer has an number average molecular weight of less than about 1000 Daltons;

wherein the radiation cured primary coating has a Young'"'"'s modulus of less than about 1.0 MPa, a T_g of less than about −

30°

C., an elongation to break of at least about 100%, and a tensile strength of at least 50% of the Young'"'"'s modulus; and

wherein the cured radiation curable secondary coating has a Young'"'"'s modulus of greater than about 600 MPa.

29. The coated optical fiber in claim 28, wherein “

m”

−

“

n”

≧

about 1 and “

m”

≦

about 4.

30. The coated optical fiber in claim 28, wherein the radiation cured coating further comprises a second oligomer.

31. The coated optical fiber in claim 28, wherein the ethylenically unsaturated monomer is selected from the group of a mono-functional monomer, a poly-functional monomer, and mixtures thereof.

32. The coated optical fiber in claim 28, wherein the ethylenically unsaturated monomer comprises a mono-functional monomer having a functional group selected from the group consisting of acrylates, methacrylates, acrylamides, N-vinyl amides, styrenes, vinyl ethers, vinyl esters, acid esters and combinations thereof.

33. The coated optical fiber in claim 28, wherein the monomer has a viscosity of less than about 500 centipoise and the monomer is an acrylate.

34. The coated optical fiber in claim 28, wherein the radiation cured primary coating has a T₂ of less than about −

40°

C.

35. The coated optical fiber in claim 28, wherein the acrylated urethane oligomer is present in an amount from about 40 to about 65 weight percent, the ethylenically unsaturated monomer is present in an amount from about 60 to about 20 weight percent, and the photoinitiator is present in an amount from about 0.1 to about 10 weight percent of a bulk radiation curable primary coating composition.

36. A coated optical fiber comprising:

an optical fiber,

a radiation cured primary coating comprising an oligomer, wherein the oligomer is formed from a reaction comprising a polyol having “

m”

hydroxyl functional groups, wherein “

n”

hydroxyl groups of said polyol are terminated in forming the oligomer and “

m”

is greater than “

n” and

a radiation cured secondary coating wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.3 dB/m at a wavelength of 1310 nm, of less than about 0.35 dB/m at a wavelength of 1550 nm, and of less than about 0.55 dB/m at a wavelength of 1625 nm.

37. The coated optical fiber in claim 36, wherein the radiation cured primary coating is the cured product of a bulk composition comprising:

an acrylated urethane oligomer,

an ethylenically unsaturated monomer and

a photoinitiator.

38. The coated optical fiber in claim 37, wherein the oligomer has a number average molecular weight of at least 4000 Daltons.

39. The coated optical fiber in claim 37, wherein the ethylenically unsaturated monomer has an number average molecular weight of less than about 1000 Daltons.

40. The coated optical fiber in claim 37, wherein the radiation cured primary coating has a Young'"'"'s modulus of less than about 1.0 MPa, and a T, of less than about −

40°

C.

41. The coated optical fiber in claim 37, wherein the cured radiation curable secondary coating has a Young'"'"'s modulus of greater than about 600 MPa.

42. The coated optical fiber in claim 36, wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.15 dB/m at a wavelength of 1550 nm, and of less than about 0.25 dB/m at a wavelength of 1625 nm.

43. The coated optical fiber in claim 42, wherein the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 0.75 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 1.4 (dB/km)/% strain at a wavelength of 1625 nm.

44. The coated optical fiber in claim 36, wherein the optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.3 dB/m at a wavelength of 1550 nm, and of less than about 1.0 dB/m at a wavelength of 1625 nm.

45. The coated opt claim 44, wherein optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 2.0 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 4.0 (dB/km)/% strain at a wavelength of 1625 nm.

46. A method of coating an optical fiber comprising the steps of:

(a) drawing an optical fiber comprising a core and a cladding;

(b) coating the optical fiber with a radiation curable coating comprising an oligomer, wherein the oligomer is formed from a reaction comprising a polyol having “

m”

hydroxyl functional groups, wherein “

n”

hydroxyl groups of said polyol are terminated in forming the oligomer and “

m”

is greater than “

n”

; and

(c) irradiating the optical fiber at a dose level of from about 0.5 J/cm² to about 1.0 J/cm²;

wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.3 dB/m at a wavelength of 1310 nm, of less than about 0.35 dB/m at a wavelength of 1550 nm, and of less than about 0.55 dB/m at a wavelength of 1625 nm.

47. The method in claim 46, wherein the radiation cured coating further comprises a second oligomer.

48. The method in claim 46, wherein “

m”

−

“

n”

≧

about 1.

49. The method in claim 46, wherein m≦

about 4.

50. The method in claim 46, wherein the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.15 dB/m at a wavelength of 1550 nm, and of less than about 0.25 dB/m at a wavelength of 1625 nm.

51. The method in claim 50, wherein the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 0.75 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 1.4 (dB/km)/% strain at a wavelength of 1625 nm.

52. The method in claim 46, wherein the optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the LLWM test of less than about 0.1 dB/m at a wavelength of 1310 nm, of less than about 0.3 dB/m at a wavelength of 1550 nm, and of less than about 1.0 dB/m at a wavelength of 1625 nm.

53. The method in claim 52, wherein the optical fiber has an effective area greater than about 70 μ

m², said effective area measured at a wavelength of 1550 nm, and the coated optical fiber has a micro-bend attenuation as measured by the EDM test of less than about 0.151 (dB/km)/% strain at a wavelength of 1310 nm, of less than about 2.0 (dB/km)/% strain at a wavelength of 1550 nm, and of less than about 4.0 (dB/km)/% strain at a wavelength of 1625 nm.