Lignocellulose fiber composite with soil conditioners

• US 6,855,182 B2
• Filed: 07/17/2002
• Issued: 02/15/2005
• Est. Priority Date: 07/17/2002
• Status: Expired due to Fees

• Current Assignee: Rayonier Performance Fibers, LLC (Rayonier Advanced Materials, Inc.)
• Original Assignee: Rayonier Products and Financial Services Company
• Inventors: Sears, Karl D.
• Primary Examiner(s): SAYALA, CHHAYA D
• Application Number:
  US10/197,205
• Publication Number:
  US 20040011102A1
• Time in Patent Office: 944 Days
• Field of Search: 71/24, 71/27, 71/31, 71/54, 71/61
• US Class Current: 71/24
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C05G 1/00 Mixtures of fertilisers belonging individually to different subclasses of C05
• CPC Class Codes: C05G 3/80 Soil conditioners
• CPC Class Codes: C05G 5/12 Granules or flakes
• CPC Class Codes: C09K 17/32 of natural origin, e.g. cellulosic materials
• CPC Class Codes: C09K 17/40 containing mixtures of inorganic and organic compounds

Abstract

A pellet for use in conditioning soil made of a lignocellulose fiber matrix having up to 20% by weight of a soil conditioning material incorporated therein. The soil conditioning material comprises one or more synthetic soil conditioning polymers and, optionally, additional soil enhancing additives such as fertilizers, gypsum, and calcium salts. The preferred lignocellulose materials are pulp fibers with an alpha-cellulose purity of greater than about 75% by weight, with preferred lignin content of no higher than 10%. The soil conditioning polymers are preferably polyacrylamides (PAMs) or modified PAMs, but may be a combination of other soil conditioning polymers. The pellet is produced by dispersing the polymers into a bath of lignocellulose fibers. The dispersion is then formed into pellets with a pelletizing machine such that the polymer and other soil conditioning material is interspersed within the matrix formed by the pelletized lignocellulose.

Claims

1. A soil conditioning composite comprising

a pelletized matrix of lignocellulose fiber and

soil conditioning material interspersed within said matrix,

wherein said conditioning material is between 1.0% and about 20 wt % by weight of the composite and

wherein said soil conditioning material comprises at least one synthetic soil conditioning polymer.

2. The soil conditioning composite of claim 1, wherein the lignocellulose results from a process selected from the group consisting of kraft;

prehydrolyzed kraft;

sulfite, including acid bisulfite, bisulfite, and neutral sulfite;

soda;

thermomechanical; and

chemi-thermomechanical pulping processes.

3. The soil conditioning composite of claim 2, wherein the lignocellulose fiber is produced by a pulping process selected from a kraft, prehydrolyzed kraft, and acid bisulfite process.

4. The soil conditioning composite of claim 3, wherein the lignocellulose fiber is unbleached.

5. The soil conditioning composite of claim 4, wherein the lignocellulose fiber has an alpha-cellulose content of at least 75 wt %.

6. The soil conditioning composite of claim 5, wherein the lignocellulose fiber has an lignin content of less than about 10 wt %.

7. The soil conditioning composite of claim 1, wherein the soil conditioning polymer is selected from the group consisting of polyacrylamides (PAMs), poly(ethylene glycol), poly(vinyl alcohol), copolymers of maleic anhydride, poly(urea formaldehyde), starch grafted acrylonitriles, and combinations thereof.

8. The soil conditioning composite of claim 7, wherein the soil conditioning polymer is a PAM.

9. The soil conditioning composite of claim 8, wherein the PAM is an anionic PAM.

10. The soil conditioning composite of claim 8, wherein the PAM is a superabsorbent, cross-linked PAM.

11. The soil conditioning composite of claim 8, wherein the PAM has an average molecular weight of at least 1×

10⁵ g/mol.

12. The soil conditioning composite of claim 9, wherein the PAM has up to about 20% carboxylate functional groups.

13. The soil conditioning composite of claim 8, wherein the PAM is up to 20 wt % of the conditioning composite by weight of the pellet.

14. The soil conditioning composite of claim 1, wherein the pellet has an average density of between about 0.4 and about 1.0 g/cm³.

15. The soil conditioning composite of claim 14, wherein the pellet has an average density of between about 0.5 and about 0.8 g/cm³.

16. The soil conditioning composite of claim 1, wherein the average length of the lignocellulose fiber is between about 0.5 mm and about 6.0 mm.

17. The soil conditioning composite of claim 16, wherein the average length of the lignocellulose fiber is between about 0.6 mm and 3.0 mm.

18. The soil conditioning composite of claim 1, wherein the soil conditioning material further comprises at least one water soluble binder.

19. The soil conditioning composite of claim 18, wherein the at least one binder is selected from the group consisting of polyacrylamide, polyacrylic acid, poly(n-vinyl pyrroliddinone), sodium carboxymethyl cellulose, polyvinyl alcohol, polyethylene glycol, sodium hydroxy ethyl cellulose, sodium carboxy methyl hydroxy ethyl cellulose, sodium hydroxy propyl cellulose and mixtures thereof.

20. The soil conditioning composite of claim 1, wherein the soil conditioning material further comprises a soil enhancing additive.

21. The soil conditioning composite of claim 20, wherein the enhancing additive is selected from the group consisting of calcium salts, gypsum, fertilizer salts, and polysaccharides.

22. A method of forming a soil conditioning pellet comprising:

mixing water, lignocellulose fibers, at least one soil conditioning polymer, and a binder into a mixture;

forming pellets from portions of the mixture with a pelletizer; and

drying the pellets to an average density of between about 4.0 and about 1.0 g/cm³.

23. The method of claim 22, wherein the lignocellulose fiber has an alpha-cellulose content of at least 75 wt %.

24. The method of claim 23, wherein the lignocellulose fiber has a lignin content of less than about 10 wt % of the fiber.

25. The method of claim 22, wherein the soil conditioning polymer is selected from the group consisting of polyacrylamides (PAMs), poly(ethylene glycol), poly(vinyl alcohol), copolymers of maleic anhydride, poly(urea formaldehyde), starch grafted acrylonitriles and combinations thereof.

26. The method of claim 25, wherein the polymer is a PAM.

27. The method of claim 26, wherein the PAM is an anionic PAM.

28. The method of claim 26, wherein the PAM is a superabsorbent, cross-linked PAM.

29. The method of claim 26, wherein the PAM has an average molecular weight of at least 1×

10⁵ g/mol.

30. The method of claim 26, wherein the PAM is up to 20 wt % by weight of the pellet.

31. The method of claim 22, wherein the pellet is formed with an average density of between about 0.5 and about 0.8 g/cm³.

32. The method of claim 22, further comprising the step of mixing a soil enhancing additive selected from the group consisting of calcium salts, gypsum, fertilizer salts, and polysaccharides into said mixture prior to pelletizing.

33. A soil conditioning pellet formed by the method of claim 22.

34. A method of forming a soil conditioning pellet comprising:

mixing water, lignocellulose fibers, at least one polyacrylamide (PAM) soil conditioning polymer, and a binder into a mixture;

forming pellets from portions of the mixture with a pelletizer; and

drying the pellets.

35. The method of claim 34, wherein the PAM is an anionic PAM.

36. The method of claim 34, wherein the PAM is a superabsorbent, cross-linked PAM.

37. The method of claim 34, wherein the PAM has an average molecular weight of at least 1×

10⁵ g/mol.

38. The method of claim 34, wherein the PAM is up to 20 wt % by weight of the pellet.

39. A soil conditioning pellet formed by the method of claim 34.

40. A method of forming a soil conditioning pellet comprising:

mixing water, lignocellulose fibers, at least one soil conditioning polymer, a binder, and a soil enhancing additive selected from the group consisting of calcium salts, gypsum, fertilizer salts, and polysaccharides into a mixture;

forming pellets from portions of the mixture with a pelletizer; and

drying the pellets.

41. A soil conditioning pellet formed by the method of claim 40.