Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant

• US 6,861,466 B2
• Filed: 01/20/2004
• Issued: 03/01/2005
• Est. Priority Date: 02/28/2003
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Harvey, Leonard W., Dadalas, Michael C.
• Primary Examiner(s): Wu, David W.
• Assistant Examiner(s): Hu, Henry S.
• Application Number:
  US10/761,086
• Publication Number:
  US 20040171736A1
• Time in Patent Office: 406 Days
• Field of Search: 526/242, 526/248, 526/280, 526/805, 524/544
• US Class Current: 524/544
• CPC Class Codes: C08K 5/06 Ethers; Acetals; Ketals; Ortho-esters
• CPC Class Codes: C08K 5/42 Sulfonic acids; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 27/18 Homopolymers or copolymers or tetrafluoroethene
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: C09D 127/18 Homopolymers or copolymers of tetrafluoroethene

Abstract

In an aspect of the invention, a fluoropolymer dispersion, preferably a PTFE dispersion, is provided that comprises fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion has an amount of solids between 35 and 70% by weight. The dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol (hereinafter called low molecular weight fluorinated surfactant) or contains the low molecular weight fluorinated surfactant in an amount of not more than 0.05% by weight based on the total weight solids of the dispersion. The dispersion further comprises a non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants and one or more non-fluorinated anionic surfactants. Through the use of a non-fluorinated anionic surfactant, a dispersion is obtained that has a low viscosity at room temperature (20° C.). The dispersion is further free of aromatic group containing non-ionic surfactants and is accordingly environmentally more friendly and can yield coatings that are less susceptible of discoloration. The amount and nature of the non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants is selected such that the Viscosity Transition Temperature (VTT) (measured as set forth in the examples) of the fluoropolymer dispersion is at least 26, preferably at least 28° C. In a further aspect of the invention, a method is provided to obtain the aforementioned dispersion.

Claims

1. Fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water, said dispersion having a solids content between 35 and 70% by weight, said dispersion being free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or containing said fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.05% by weight based on the total weight solids of said dispersion, said dispersion further comprising a non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants and one or more non-fluorinated anionic surfactants, characterized in that the amount and nature of said non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants is selected such that the Viscosity Transition Temperature (VTT) of said fluoropolymer dispersion is at least 26°

C. and that the fluoropolymer dispersion is essentially free of aromatic group containing non-ionic surfactants.

2. Fluoropolymer dispersion according to claim 1 wherein said non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants can be represented by the general formula:

R¹—

O—

[CH₂CH₂O]_n—

[R²O]_m—

R³ 

 

(I)

wherein R¹ represents an aliphatic hydrocarbon group having at least 8 carbon atoms, R² represents an alkylene having 3 carbon atoms, R³ represents hydrogen or a C₁-C₃ alkyl group, n has a value of 0 to 40, m has a value of 0 to 40 and the sum of n+m being at least 2.

3. Fluoropolymer dispersion according to claim 2 wherein m is 0 and wherein said non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants has a Hydrophilic Lypophilic Balance (HLB) between 11 and 16.

4. Fluoropolymer dispersion according to claim 2 wherein said fluoropolymer dispersion comprises a mixture of non-ionic non-fluorinated surfactants comprising one or more non-ionic non-fluorinated surfactants according to formula (I) wherein m is 0 and one or more non-ionic non-fluorinated surfactants according to formula (I) wherein n and m each are different from 0.

5. Fluoropolymer dispersion according to claim 2 wherein said fluoropolymer dispersion comprises one or more non-ionic non-fluorinated surfactants according to formula (I) and one or more polysorbates.

6. Fluoropolymer dispersion according to claim 2 wherein said fluoropolymer dispersion comprises one or more non-ionic non-fluorinated surfactants according to formula (I) and one or more ethoxylated acetylenic diols.

7. Fluoropolymer dispersion according to claim 6 wherein said ethoxylated acetylenic diols have an HLB between 11 and 16.

8. Fluoropolymer dispersion according to claim 1 wherein the fluoropolymer comprises polytetrafluoroethylene.

9. A method comprising, coating or impregnating a substrate with the fluoropolymer dispersion as defined in claim 1.

10. A method according to claim 9 wherein said substrate comprises metal substrates, glass fiber fabrics, polymeric substrata and paper.

11. Method of providing a fluoropolymer particle dispersion comprising:

(a) providing a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm and comprising fluorinated surfactant having a molecular weight of less than 1000 g/mol or being free thereof;

(b) reducing the amount of said fluorinated surfactant in said dispersion if the amount thereof is more than 0.05% by weight based on the total weight of solids of the dispersion in the presence of a non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants;

(c) upconcentrating the fluoropolymer dispersion in the presence of a non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants so as to increase the amount of fluoropolymer solids in said dispersion to a level between 35% and 75% by weight; and

(d) adding one or more non-fluorinated anionic surfactants to the fluoropolymer dispersion prior to or after upconcentrating said fluoropolymer dispersion;

wherein said non-ionic non-fluorinated surfactant or mixture of non-ionic non-fluorinated surfactants used in said step (b) and/or (c) are selected such that the fluoropolymer dispersion after step (d) has a Viscosity Transition Temperature (VTT) of at least 26°

C. or alternatively, further one or more non-ionic non-fluorinated surfactants are added to adjust the Viscosity Transition Temperature (VTT) of the fluoropolymer dispersion to at least 26°

C. and wherein said non-ionic non-fluorinated surfactants are selected such that the fluoropolymer dispersion is free from aromatic coup containing non-ionic surfactant.