Grafted polymers as gas hydrate inhibitors

• US 6,867,262 B1
• Filed: 07/11/2000
• Issued: 03/15/2005
• Est. Priority Date: 07/28/1999
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Angel, Maximilian, Sanner, Axel, Neubecker, Karin
• Primary Examiner(s): HAMPTON HIGHTOWER, PATRICIA
• Application Number:
  US10/030,987
• Time in Patent Office: 1,708 Days
• Field of Search: 525/326.9, 526/264, 307/90, 307/246, 585/15, 585/950, 951/53, 208/48.AA
• US Class Current: 525/326.9
• CPC Class Codes: C08F 251/00 Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
• CPC Class Codes: C08F 261/04 on to polymers of vinyl alcohol
• CPC Class Codes: C08F 271/00 Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C09K 2208/22 Hydrates inhibition by using well treatment fluids containing inhibitors of hydrate formers
• CPC Class Codes: C10L 3/00 Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
• CPC Class Codes: F17D 1/05 Preventing freezing by heating F16L53/30
• CPC Class Codes: Y10S 585/95 Prevention or removal of corrosion or solid deposits

Abstract

Graft polymers are used as gas hydrate inhibitors.

Claims

1. A graft polymer comprising:

a hydrophilic base polymer which is a polyalkylene glycol, a polyether or a polymer having at least one heteroatom in the main chain, with the proviso that polyphenylene ether is excluded as a base polymer, having a N-vinyllactam grafted thereon.

12. A process for preventing or reducing the formation of gas hydrates in liquid or gaseous systems, which comprises:

adding a graft polymer of claim 1 to the liquid or gaseous system.

13. The graft polymer as claimed in claim 1, wherein said polymer having at least one heteroatom in the main chain is a polyurethane or a polyalkyleneimine and said N-vinyllactam is grafted onto the base polymer with a N-vinylamide, an acrylate, an acrylamide and/or a vinyl ester monomer.

2. A method of inhibiting gas hydrates, comprising:

contacting a gas hydrate with a graft copolymer.

3. The method as claimed in claim 2, wherein the graft polymers have a hydrophilic and/or hydrophobic base polymer.

4. The method as claimed in claim 2, wherein the hydrophilic base polymers are selected from the group consisting of polyalkylene glycols, polyvinyl alcohols, polyvinylamides, polyvinylpyrrolidone, polyethers, polyesters, polyurethanes, polyacrylamides, polysaccharides, cellulose ethers, polyalkyleneimines, polycarboxylic acids, polyvinylsulfonic acids, polyvinylphosphonic acids and copolymers of the monomer components of these polymers.

5. The method as claimed in claim 3, wherein the hydrophobic base polymers are selected from the group consisting of polyalkylene glycols, such as ethylene oxide-propylene oxide copolymers or ethylene oxide-propylene oxide block copolymers, polyethers, poly(meth)acrylates, polyolefins, polystyrene or styrene copolymers, polyvinyl acetate, polyvinyl ethers, polyvinyl formals, polyvinyl acetals, polyvinyl chloride or other halogenated polyvinyl compounds, polyacrylonitrile, polyamides, polyurethanes, silicones, polycarbonates, polyterephthalates, cellulose, cellulose ethers, cellulose esters, polyoxymethylene and copolymers of the monomer components of these polymers.

6. The use The method as claimed in claim 2, wherein the graft polymers contain grafted-on units of water-soluble and/or water-insoluble monomers.

7. The method as claimed in claim 6, wherein the units grafted onto the base polymer make-up from 10 to 90% by weight of the graft polymer.

8. The method as claimed in claim 6, wherein the units grafted on onto the base polymer comprise N-vinyllactams, N-vinylamides, acrylates, arylamides and/or a vinyl esters.

9. The method as claimed in claim 8, wherein the units grafted on onto the base polymer comprise N-vinylcaprolactam.

10. The graft polymer as claimed in claim 2, wherein the hydrophilic base polymer is polyethylene glycol.

11. The graft polymer as claimed in claim 2, wherein the unit grafted onto the base polymer is N-vinylcaprolactam.

14. The method as claimed in claim 7, wherein the units grafted onto the base polymer make-up from 25 to 75% by weight of the graft polymer.

15. A method of inhibiting gas hydrates, comprising:

contacting a gas hydrate with a graft copolymer prepared by graft polymerizing a N-vinyllactam, a N-vinylamide, an acrylate, an arylamide or a vinyl ester onto a hydrophilic base polymer selected from the group consisting of polyalkylene glycols, polyvinyl alcohols, polyvinylamides, polyvinylpyrrolidone, polyethers, polyesters, polyurethanes, polyacrylamides, polysaccharides, cellulose ethers, polyalkyleneimines, polycarboxylic acids, polyvinylsulfonic acids, polyvinylphosphonic acids and copolymers of the monomer components of these polymers or onto a hydrophobic base polymer selected from the group consisting of polyalkylene glycols, polyethers, poly(meth)acrylates, polyolefins, polystyrene, styrene copolymers, polyvinyl acetate, polyvinyl ethers, polyvinyl formals, polyvinyl acetals, halogenated polyvinyl compounds, polyacrylonitrile, polyamides, polyurethanes, silicones, polycarbonates, polyterephthalates, cellulose, cellulose ethers, cellulose esters, polyoxymethylene and copolymers of the monomer components of these polymers, thereby removing water from the gas hydrate.

16. The process as claimed in claim 15, wherein the graft polymer is in the form of an aqueous solution or in a water/solvent mixture.