Switchable polymer-dispersed liquid crystal optical elements

• US 6,867,888 B2
• Filed: 12/22/2000
• Issued: 03/15/2005
• Est. Priority Date: 07/12/1996
• Status: Expired due to Term

• Current Assignee: Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Sutherland, Richard L., Kelly, William, Hagan, Bill, Epling, Bob
• Primary Examiner(s): Chang, Audrey
• Assistant Examiner(s): Lavarias, Arnel C.
• Application Number:
  US09/742,397
• Publication Number:
  US 20010033400A1
• Time in Patent Office: 1,544 Days
• Field of Search: 359/15, 359/7, 359/3, 430/1, 430/2, 349/201, 349/202, 349/8, 349/9, 349/10
• US Class Current: 359/15
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: G02B 5/32 Holograms used as optical elements
• CPC Class Codes: G02F 1/1326 Liquid crystal optical waveguides or liquid crystal cells specially adapted for gating or modulating between optical waveguides
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G02F 1/13712 the liquid crystal having negative dielectric anisotropy
• CPC Class Codes: G02F 1/31 Digital deflection, i.e. optical switchingG02F1/33 takes precedence
• CPC Class Codes: G02F 2201/346 distributed (Bragg) reflector
• CPC Class Codes: G02F 2203/05 wavelength dependent
• CPC Class Codes: G02F 2203/055 wavelength filtering
• CPC Class Codes: G02F 2203/585 Add/drop devices
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2001/0264 Organic recording material
• CPC Class Codes: G03H 2001/2231 Reflection reconstruction
• CPC Class Codes: G03H 2001/2234 Transmission reconstruction
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound

Abstract

Transmission and reflection type holograms may be formed utilizing a novel polymer-dispersed liquid crystal (PDLC) material and its unique switching characteristics to form optical elements. Applications for these switchable holograms include communications switches and switchable transmission, and reflection red, green, and blue lenses. The PDLC material of the present invention offers all of the features of holographic photopolymers with the added advantage that the hologram can be switched on and off with the application of an electric field. The material is a mixture of a polymerizable monomer and liquid crystal, along with other ingredients, including a photoinitiator dye. Upon irradiation, the liquid crystal separates as a distinct phase of nanometer-size droplets aligned in periodic channels forming the hologram. The material is called a holographic polymer-dispersed liquid crystal (H-PDLC).

Claims

1. A wavelength selective optical element comprising:

a first polymer-dispersed liquid crystal switchable holographic component for diffracting a first wavelength of an incident beam wherein, a second wavelength of the incident beam passes through the first polymer dispersed liquid crystal switchable holographic component without being diffracted thereby; and

a second polymer-dispersed liquid crystal switchable holographic component for diffracting the second wavelength, wherein the first and second polymer-dispersed liquid crystal switchable holographic components are located in stacked relationship with one another and placed in the path of the incident beam, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components is made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure;

(a) a polymerizable monomer;

(b) vinyl neononanoate;

(c) a liquid crystal;

(d) a coinitiator; and

(e) a photoinitiator dye.

2. The hologram of claim 1, wherein the polymer-dispersed liquid crystal material comprises, before exposure, about 6.5% by weight vinyl neononanoate.

3. The hologram of claim 1, wherein the polymerizable monomer comprises dipentaerythritol hydroxypentaacrylate.

4. A wavelength selective optical element comprising:

a first polymer-dispersed liquid crystal switchable holographic component for diffracting a first wavelength of an incident beam wherein, a second wavelength of the incident beam passes through the first polymer dispersed liquid crystal switchable holographic component without being diffracted thereby; and

a second polymer-dispersed liquid crystal switchable holographic component for diffracting the second wavelength, wherein the first and second polymer-dispersed liquid crystal switchable holographic components are located in stacked relationship with one another and placed in the path of the incident beam, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components is made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure;

(a) a polymerizable monomer;

(b) 5-15% chain-extending monomer;

(c) 10-40% liquid crystal;

(d) 10<sup>(−

4)</sup> to 10<sup>(−

4)</sup> gram moles coinitiator; and

(e) 10<sup>(−

5)</sup> to 10<sup>(−

6)</sup> gram moles photoinitiator dye.

5. A wavelength selective optical element comprising:

a first polymer-dispersed liquid crystal switchable holographic component for diffracting a first wavelength of an incident beam wherein, a second wavelength of the incident beam passes through the first polymer dispersed liquid crystal switchable holographic component without being diffracted thereby; and

a second polymer-dispersed liquid crystal switchable holographic component for diffracting the second wavelength, wherein the first and second polymer-dispersed liquid crystal switchable holographic components are located in stacked relationship with one another and placed in the path of the incident beam, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components is made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure;

(a) a polymerizable monomer;

(b) 10-18% chain-extending monomer;

(c) 10-40% liquid crystal;

(d) 2-3% coinitiator; and

(e) 0.2-0.4% photoinitiator dye.

6. The wavelength selective optical element according to claim 5, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.

7. The wavelength selective optical element according to claim 6, wherein the surfactant comprises about 6% by total weight of the polymer-dispersed liquid crystal material.

8. The wavelength selective optical element according to claim 6, wherein the surfactant comprises about 5-10% by total weight of the polymer-dispersed liquid crystal material.

9. The wavelength selective optical element according to claim 6, wherein the liquid crystal includes a mixture of cyano biphenyls.

10. The wavelength selective optical element according to claim 6, wherein the chain extending monomer comprises N-vinylpyrrolidone.

11. The wavelength selective optical element according to claim 6, wherein the coinitiator comprises N-phenylglycine.

12. The wavelength selective optical element according to claim 6, wherein the photoinitiator dye comprises rose bengal ester.

13. The wavelength selective optical element according to claim 6, wherein the surfactant comprises octanoic acid.

14. The wavelength selective optical element according to claim 6, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

15. The wavelength selective optical element according to claim 6, wherein the liquid crystal comprises 4′

—

n-pentyl-4-cyanobiphenyl.

16. The wavelength selective optical element according to claim 6, wherein the polymer-dispersed liquid crystal material comprises 0.2% by weight to 0.4% by weight of a photoinitiator dye.

17. The wavelength selective optical element according to claim 6, wherein the polymer-dispersed liquid crystal material comprises a photoinitiator dye comprising rose bengal sodium salt.

18. The wavelength selective optical element according to claim 6, wherein the polymer-dispersed liquid crystal material comprises about 2% by weight to 3% by weight of a coinitiator.

19. The wavelength selective optical element according to claim 6, wherein the polymer-dispersed liquid crystal material comprises a coinitiator comprising N-phenyglycine;

and a photoinitiator dye comprising camphorquinone.

20. The wavelength selective optical element to claim 6, wherein the polymer-dispersed liquid crystal material comprises about 10% by weight to 18% by weight of a cross-linking monomer.