Shape memory alloy/shape memory polymer tools

• US 6,872,433 B2
• Filed: 03/27/2001
• Issued: 03/29/2005
• Est. Priority Date: 03/27/2001
• Status: Expired due to Fees

• Current Assignee: Lawrence Livermore National Security LLC (Government of the United States of America)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Seward, Kirk P., Krulevitch, Peter A.
• Primary Examiner(s): Ahmad, Nasser
• Assistant Examiner(s): RHEE, JANE J
• Application Number:
  US09/819,111
• Publication Number:
  US 20020142119A1
• Time in Patent Office: 1,463 Days
• Field of Search: 606/209, 606/198, 606/281, 428/36.9, 428/36.91, 428/36.92, 428/35.7, 428/913, 604/317, 604/540, 623/1.11, 623/1.15, 623/1.17, 623/1.2
• US Class Current: 428/36.9
• CPC Class Codes: A61B 2017/003 Steerable
• CPC Class Codes: A61B 2017/00345 Micromachines, nanomachines, microsystems
• CPC Class Codes: A61B 2017/00398 using powered actuators, e.g. stepper motors, solenoids
• CPC Class Codes: A61B 2017/00867 shape memory effect
• CPC Class Codes: A61B 2017/00871 polymeric
• CPC Class Codes: A61B 2017/12077 Joint changing shape upon application of heat, e.g. bi-metal or reversible thermal memory
• CPC Class Codes: A61F 2/86 Stents in a form characterised by the wire-like elements; Stents in the form characterised by a net-like or mesh-like structure
• CPC Class Codes: A61F 2210/0023 operated at different temperatures whilst inside or touching the human body, heated or cooled by external energy source or cold supply
• CPC Class Codes: A61L 2400/16 Materials with shape-memory or superelastic properties
• CPC Class Codes: A61L 29/126 having a macromolecular matrix
• CPC Class Codes: A61L 31/128 containing other specific inorganic fillers not covered by A61L31/126 or A61L31/127
• CPC Class Codes: A61M 2025/0063 having means, e.g. stylets, mandrils, rods or wires to reinforce or adjust temporarily the stiffness, column strength or pushability of catheters which are already inserted into the human body
• CPC Class Codes: A61M 2205/0266 Shape memory materials
• CPC Class Codes: A61M 25/0043 characterised by structural features
• CPC Class Codes: A61M 25/0052 Localized reinforcement, e.g. where only a specific part of the catheter is reinforced, for rapid exchange guidewire port
• CPC Class Codes: A61M 25/0053 having a variable stiffness along the longitudinal axis, e.g. by varying the pitch of the coil or braid
• CPC Class Codes: A61M 25/0116 self-propelled, e.g. autonomous robots A61M25/0122 takes precedence
• CPC Class Codes: A61M 25/0158 with magnetic or electrical means, e.g. by using piezo materials, electroactive polymers, magnetic materials or by heating of shape memory materials
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/139 : Open-ended, self-supporting conduit, cylinder, or tube-type article
• CPC Class Codes: Y10T 428/1393 : Multilayer [continuous layer]
• CPC Class Codes: Y10T 428/1397 : Single layer [continuous layer]
• CPC Class Codes: Y10T 428/2925 : Helical or coiled

Abstract

Micro-electromechanical tools for minimally invasive techniques including microsurgery. These tools utilize composite shape memory alloy (SMA), shape memory polymer (SMP) and combinations of SMA and SMP to produce catheter distal tips, actuators, etc., which are bistable. Applications for these structures include: 1) a method for reversible fine positioning of a catheter tip, 2) a method for reversible fine positioning of tools or therapeutic catheters by a guide catheter, 3) a method for bending articulation through the body'"'"'s vasculature, 4) methods for controlled stent delivery, deployment, and repositioning, and 5) catheters with variable modulus, with vibration mode, with inchworm capability, and with articulated tips. These actuators and catheter tips are bistable and are opportune for in vivo usage because the materials are biocompatible and convenient for intravascular use as well as other minimal by invasive techniques.

Claims

1. An apparatus for minimally invasive applications, said apparatus having a longitudinal axis with said apparatus extending in a radial direction from said longitudinal axis and said apparatus being activated by a change in temperature, comprising:

a first unit comprising a first structure for at least positioning said apparatus, said first structure including a quantity of shape memory alloy and

a second unit comprising a second structure for at least positioning said apparatus, said second structure including a quantity of shape memory polymer,

said first unit comprising said first structure including said shape memory alloy having a longitudinally extending coiled configuration with more than one wrap, and

said second unit comprising said second structure including said shape memory polymer comprising a cylinder,

wherein said first unit is positioned in said second unit such that changes in temperature of said shape memory alloy causes said first unit to change position by a radial contraction and a longitudinal extension and to stretch said second unit comprising said second structure including said shape memory polymer along said longitudinal axis.

2. The apparatus of claim 1, wherein said first unit comprising said first structure including said shape memory alloy is embedded within second unit comprising said second structure including said shape memory polymer and wherein changes in temperature of said shape memory alloy causes said first unit to change position by a radial contraction and a longitudinal extension and to stretch said second unit comprising said second structure including said second shape memory polymer along said longitudinal axis.

3. The apparatus of claim 1, wherein said first unit comprising a first structure including a quantity of shape memory alloy comprises a coil configuration and wherein said second unit comprising said second structure including said shape memory polymer is a cylinder constructed so as to define a hollow tube cylinder with a wall and first unit comprising a first structure including a quantity of shape memory alloy that comprises said coil configuration is embedded in said wall.

4. The apparatus of claim 3, wherein said coil configuration of said first unit has an axis coaxial with said axis of said apparatus and said hollow tube cylinder of said second unit has an axis coaxial with said axis of said apparatus.

5. The improvement of claim 3, wherein said coil configuration has an axis off-set from an axis of said hollow tube.

6. The apparatus of claim 3, including a plurality of additional structures each having a longitudinally extending coiled configuration of shape memory alloy located within a shape memory polymer comprising a cylinder.

7. The improvement of claim 6, wherein each coil configuration has a different configuration.

8. The improvement of claim 6, wherein said plurality of structures are in a series configuration to said first structure and said second structure.

11. The improvement of claim 1, wherein said quantity of shape memory alloy is composed of NiTiCu.

23. The improvement of claim 1, wherein said quantity of shape memory alloy comprises a plurality of strips, wherein said quantity of shape memory polymer is a tubular configuration and includes a plurality of longitudinally extending openings and a plurality of longitudinal slots, wherein said plurality of strips are located in said plurality of longitudinally extending slots.

24. The improvement of claim 23, additionally including a plurality of light diffusers mounted in certain of said longitudinally extending openings.

25. The improvement of claim 23, wherein said tubular configuration is constructed to mate up to a catheter having a plurality of longitudinally extending openings, whereby said slots and openings in said tubular configuration align with said openings in said catheter.

9. An apparatus for minimally invasive applications, said apparatus having a longitudinal axis with said apparatus extending in a radial direction from said longitudinal axis and said apparatus being activated by a change in temperature, comprising:

a first structure for at least positioning said apparatus, said first structure having an axis aligned with said longitudinal axis of said apparatus and said first structure having a longitudinally extending coiled configuration with more than one wrap,

said first structure including a quantity of shape memory alloy in said longitudinally extending coiled configuration with more than one wrap, and

a second structure for at least positioning said apparatus,

a quantity of shape memory polymer in said second structure,

wherein said quantity of shape memory polymer in said second structure is a cylinder, and

wherein said first structure including a quantity of shape memory alloy is positioned in said second structure that is a cylinder and wherein said first structure including a quantity of shape memory alloy is positioned in said second structure that is a cylinder such that changes in temperature of said shape memory alloy causes said first structure to change position by a radial contraction and a longitudinal extension and to stretch said second structure along said longitudinal axis.

10. The apparatus of claim 9, wherein said quantity of shape memory alloy has a ribbon configuration.

12. The apparatus of claim 9, wherein said quantity of shape memory alloy is composed of a plurality of shape memory alloy strips.

13. The apparatus of claim 9, wherein said quantity of cylindrical shape memory polymer has a closed cylinder configuration.

14. The apparatus of claim 13, wherein said quantity of shape memory alloy has a coiled spring configuration located within said shape memory polymer.

15. The apparatus of claim 13, wherein said quantity of shape memory alloy is composed of a plurality of strips, and wherein said strips are located in a wall surface of said shape polymer.

16. The apparatus of claim 13, wherein said quantity of shape memory alloy is composed of a plurality of sections embedded in said shape memory polymer.

17. The improvement of claim 13, wherein said quantity of shape memory alloy is composed of net-like configuration attached to said tubular configuration.

18. The improvement of claim 13, wherein said quantity of shape memory alloy is composed of a compressed spring located in a wall surface of tubular configuration.

19. The improvement of claim 13, wherein said quantity of shape alloy is composed of a plurality of bent sections located in openings said tubular configuration.

20. The improvement of claim 13, wherein said quantity of shape memory alloy is composed of a plurality of ribbons mounted in spaced relation around said tubular configuration.

21. The improvement of claim 14, wherein said plurality of ribbons are of mesh configuration and mounted to a said tubular configuration support members.

22. The apparatus of claim 9, wherein said quantity of shape memory alloy has a coiled spring configuration, wherein said quantity of shape memory polymer is a cylinder and wherein said coiled spring configuration is embedded in said shape memory polymer.

26. The improvement of claim 9, including a light source connected to said apparatus via a plurality of optical fibers and light control mechanism.

27. The apparatus of claim 26, wherein said light source is a laser.

28. An articulated tip for a catheter, said articulated tip having a central axis with said articulated tip extending in a radial direction from said central axis and said articulated tip being activated by a change in temperature, comprising

a composite of shape memory alloy forming a first portion of said articulated tip with said composite of shape memory alloy having an axis that is aligned with said central axis of the articulated tip for a catheter

and shape memory polymer forming a second portion of said articulated tip, wherein said shape memory polymer comprises a cylinder, and wherein said first portion of said articulated tip with said composite of shape memory alloy is positioned in second portion of said articulated tip such that changes in temperature of said shape memory alloy causes said first portion of said articulated tip with said composite of shape memory alloy to change position by a radial contraction and a longitudinal extension and to stretch said second portion of said articulated along said central axis.

29. A device for reversible fine positioning of an object, said device being activated by a change in temperature, comprising:

a member constructed of shape memory polymer portion, wherein said shape memory polymer portion comprises a cylinder and said cylinder has a cylinder central axis,

said member including a shape memory alloy portion with a coiled configuration with more than one wrap, wherein said shape memory alloy portion is located in said shape memory polymer portion such that changes in temperature of said shape memory alloy portion causes said shape memory alloy portion to change position by a radial contraction and a longitudinal extension and to stretch said shape memory polymer portion along said cylinder central axis that will cause said device to move upon a change in configuration of said shape memory alloy portion, and

means for selectively heating said shape memory alloy portion to change temperature of said shape memory alloy portion causing said shape memory alloy portion to change position by a radial contraction and a longitudinal extension and to stretch said shape memory polymer portion along said cylinder central axis and cause a change in configuration thereof, whereby the change in configuration results in positioning of said object.