Process for removing mercury from flue gases

• US 6,878,358 B2
• Filed: 05/06/2003
• Issued: 04/12/2005
• Est. Priority Date: 07/22/2002
• Status: Expired

• Current Assignee: Bromerc Limited
• Original Assignee: Bayer AG
• Inventors: Mueller, Claus, Beyer, Joachim, Fleth, Olaf, Standau, Ewa, Vosteen, Bernhard, Kanefke, Rico, Pohontsch, Andreas, Koeser, Heinz, Wieland, Andrea, Bonkhofer, Theodore-Gerhard, Nolte, Michael
• Primary Examiner(s): Silverman, Stanely S.
• Assistant Examiner(s): Strickland, Jonas N.
• Application Number:
  US10/430,088
• Publication Number:
  US 20040086439A1
• Time in Patent Office: 707 Days
• Field of Search: 423/210, 756/70, 757/42
• US Class Current: 423/210
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury

Abstract

Process for removing mercury from flue gases of high-temperature plants, in particular power stations and waste incineration plants in which a bromine compound is fed to the multistage furnace and/or the flue gas in a plant section downstream of the furnace, the temperature during contact of the bromine compound with the flue gas being at least 500° C., preferably at least 800° C. The combustion is carried out in the presence of a sulphur compound, in particular sulphur dioxide. Subsequently to the furnace, the flue gas is subjected to an optional multistage cleanup for removing mercury from the flue gas, which cleanup comprises a wet scrubber and/or a dry cleanup.

Claims

1. Process for removing mercury from mercury-containing flue gases of a furnace within which a combustion or incineration is carried out, wherein

bromine, a bromine compound, a mixture of bromine compounds or a mixture of bromine and a bromine compound or compounds, is fed to the furnace or to the flue gas of the furnace in a plant section downstream of the furnace, or to both the furnace and the flue gas, the temperature during the first contact of the bromine or of said mixture with the flue gas being at least 500°

C.,

the combustion or incineration is carried out in the presence of a sulphur compound,

and then the flue gas is subjected to a cleanup for removing mercury from the flue gas.

2. Process according to claim 1, wherein the bromine compound is an aqueous solution of hydrogen bromide, an alkali metal bromide, or a mixture thereof.

3. The process according to claim 2, wherein said bromine compound is sodium bromide.

4. Process according to claim 1, wherein the bromine compound or said mixture or both are liquid or solid bromine-rich wastes.

5. Process according to claim 1, wherein the bromine, the bromine compound or the mixture is added to combustion air supplied to the furnace, to a recycled flue gas stream, a recycled fly ash or any combination thereof.

6. Process according to claim 1, wherein the mass ratio of bromine to mercury in the flue gas is in the range from 10² to 10⁴.

7. Process according to claim 1, wherein the combustion or incineration is carried out additionally in the presence of chlorine, a chlorine compound, a mixture of chlorine compounds, iodine, an iodine compound, a mixture of iodine compounds or combination thereof.

8. Process according to claim 1, wherein the furnace is provided with a flue gas emission control system comprising a multistage wet flue gas scrubber having at least one strongly acidic scrubbing, at least one weakly acidic scrubbing stage, at least one alkaline scrubbing stage, or a combination of said scrubbing stages.

9. Process according to claim 8, wherein the mercury content of the flue gas is measured continuously downstream of the flue gas emission control system and the amount of bromine, bromine compounds fed and any sulphur or sulphur compounds fed is controlled on the basis of the measured mercury content.

10. The process according to claim 8, wherein said emission control system comprises filtration, electrostatic separation or both.

11. The process according to claim 10, wherein fly ash loaded with mercury is recovered from said filtration or electrostatic separation and is subjected to a thermal secondary treatment to decrease mercury load in a rotary drum heated to temperatures of at least 200°

C.

12. Process according to claim 1, wherein the furnace is provided with a flue gas emission control system comprising at least one dry or semi-dry absorption based emission control stage.

13. The process according to claim 1, wherein the temperature during the contact of the bromine compound or mixture with the flue gas is at least 800°

C.

14. The process according to claim 1, wherein said sulphur compound is sulphur dioxide.

15. The process according to claim 1, wherein sulphur, a sulphur compound or a mixture of sulphur compounds is added to said furnace.

16. The process according to claim 1, wherein said furnace is a multistage furnace.