Secondary battery
First Claim
1. A secondary battery comprising:
- a negative electrodes;
a positive electrode; and
an electrolyte, wherein;
the negative electrode includes a negative electrode material capable of occluding and releasing light metal in an ionic state while the light metal precipitates on the negative electrode in a state where an open circuit voltage is lower than an overcharge voltage; and
wherein when the open circuit voltage of the battery is below overcharging voltages, the ratio (moles of light metal precipitated on the negative electrode)/(moles of light metal reversibly occluded in the material of the negative electrode) is at least 0.05/1 and at most 3/1.
3 Assignments
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Accused Products
Abstract
Provided is a secondary battery in which high energy density can be obtained and charging/discharging cycle characteristic can be improved. A positive electrode (13) and a negative electrode (15) are stacked with a separator (16) interposed therebetween, and are enclosed inside an exterior can (11) to which an electrolyte is injected. The negative electrode (15) contains a negative electrode material capable of occluding/releasing lithium in an ionic state. Thereby, lithium metal precipitates in the negative electrode (15) in a state where the open circuit voltage is lower than the overcharge voltage. In other words, lithium is occluded in an ionic state in a negative electrode material capable of occluding/releasing lithium in the beginning of charging, and then lithium metal precipitates on the surface of the negative electrode material thereafter during charging. The amount of precipitation of lithium metal is preferable to be from 0.05 to 3.0 times, both inclusive, the ability of charging capacity of the negative electrode material capable of occluding/releasing lithium. Thereby, a high energy density and an excellent cycle characteristic can be obtained.
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Citations
22 Claims
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1. A secondary battery comprising:
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a negative electrodes;
a positive electrode; and
an electrolyte, wherein;
the negative electrode includes a negative electrode material capable of occluding and releasing light metal in an ionic state while the light metal precipitates on the negative electrode in a state where an open circuit voltage is lower than an overcharge voltage; and
wherein when the open circuit voltage of the battery is below overcharging voltages, the ratio (moles of light metal precipitated on the negative electrode)/(moles of light metal reversibly occluded in the material of the negative electrode) is at least 0.05/1 and at most 3/1. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22)
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Specification