Clear or translucent aqueous polyquaternary ammonium fabric softener compositions containing low solvent

• US 6,884,767 B1
• Filed: 07/05/2000
• Issued: 04/26/2005
• Est. Priority Date: 07/06/1999
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Frankenbach, Gayle Marie, Sivik, Mark Robert, Declercq, Marc Johan, Demeyere, Hugo Jean Marie, Trinh, Toan, Wahl, Errol Hoffman, Baker, Ellen Schmidt, Murphy, Ruth Anne
• Primary Examiner(s): Hardee, John R.
• Application Number:
  US09/980,797
• Time in Patent Office: 1,756 Days
• Field of Search: 515/522, 515/527
• US Class Current: 510/522
• CPC Class Codes: C11D 1/525 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
• CPC Class Codes: C11D 1/526 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
• CPC Class Codes: C11D 1/662 Carbohydrates or derivatives
• CPC Class Codes: C11D 1/667 Neutral esters, e.g. sorbitan esters
• CPC Class Codes: C11D 1/835 Mixtures of non-ionic with cationic compounds
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/3723 Polyamines or polyalkyleneimines
• CPC Class Codes: C11D 3/43 Solvents

Abstract

Clear/translucent formulations comprise polyquaternary ammonium actives with lower, or no, solvent levels except the solvent which is normally present in the polyquaternary raw material stocks by choosing highly efficient solvents within a specific Clog P range, employing higher levels of polyquaternary ammonium, actives, and/or augmenting the bilayer with surfactants and/or polar oils. Compositions with lowered solvent levels have at or below about 5% by volume of secondary dispersed phases preferably below about 3% by volume of secondary dispersed phase, and more preferably 1% by volume of secondary dispersed phases. The most preferred compositions are essentially free of secondary dispersed phases. High-speed centrifugation easily and quickly reveals the % volume of secondary phase(s).

Claims

1. A clear or translucent liquid fabric softener composition comprising:

A. from about 1% to about 80% by weight of the composition, of polyquaternary ammonium fabric softener active which either has a phase transition temperature in the presence of less than about 5% organic solvent or water of less than about 50°

C. or which has no significant endothermic phase transition in the region −

50°

C. to 100°

C. said active being in a bilayer; and

B. an effective amount of stabilizer for maintaining said composition clear or translucent comprising an effective amount of bilayer modifier, wherein said bilayer modifier comprises a nonionic surfactant with a bulky head group selected from;

1. a surfacant having the formula

R₁—

C(O)—

Y′

—

[C(R⁵)]_m—

CH₂O(R₂O)_zH

 

wherein R¹ is selected from the group consisting of saturated or unsaturated, primary, secondary or branched chain alkyl or alkyl-aryl hydrocarbons;

said hydrocarbon chain containing from about 6 to about 22 carbon atoms;

Y′

is selected from the following groups;

—

O—

;

—

N(A)—

; and

/or mixtures thereof;

A is selected from the following groups;

H;

R¹;

—

(R²—

O)_z—

H;

—

(CH₂)_zCH₃;

phenyl, or substituted aryl, wherein 0≦

x≦

about 3 and z is from about 5 to about 30;

each R^w is selected from the following groups or combinations of the following groups;

—

(CH₂)_n wherein n is from about 1 to about 4 and/or —

[CH(CH₃)CH₂]—

; and

each R² is selected from the following groups;

—

OH; and

—

O(R²O)_z—

H; and

m is from about 2 to about 4;

2. a surfactant having at least one of the following formulas

 

wherein Y″

=N or O; and

each R⁵ is selected independently from the following;

—

H, —

OH, —

(CH₂)xCH₃, —

O(OR²)_z—

H, —

OR, —

OC(O)R¹, and —

CH(CH₂—

(OR²)_z—

H)—

CH₂—

(OR²)_z—

C(O)R¹, x and R¹ are as define above and 5≦

z, z′

and z″

≦

20;

3. a polyhydroxy fatty acid amide surfactant of the formula;

R²—

C(O)—

N(R¹)—

Z

 

wherein;

each R¹ is H, C₁-C₄ hydrocarbyl, C₁-C₄ alkoxyalkyl, or hydroxyalkyl; and

R² is a C₅-C₃₁ hydrocarbyl moiety; and

each Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an ethoxylated derivative thereof; and

R′

is H or a cyclic mono- or poly-saccharide, or alkoxylated derivative of; and

4. a mixture thereof.

2. The composition of claim 1, further comprising an organic solvent from at or above about 0.25% to at or below about 7% by weight of the composition.

3. The composition of claim 2, wherein said organic solvent is from at or above 0.5% to at or below about 5% by weight of the composition.

4. The method of determining the stability of an aqueous clear or translucent softening composition according to claim 1, said method comprising the step of subjecting said composition to high-speed centrifugation and measuring the % volume of secondary phase which separates.