Method of stabilizing the density of gas generant pellets containing nitroguanidine

• US 6,887,325 B2
• Filed: 01/22/2003
• Issued: 05/03/2005
• Est. Priority Date: 01/24/2001
• Status: Expired due to Term

• Current Assignee: Key Safety Systems, Inc. (Ningbo Junsheng Investment Group Co., Ltd.)
• Original Assignee: Key Safety Systems, Inc. (Ningbo Junsheng Investment Group Co., Ltd.)
• Inventors: Schmidt, Mark A., Walsh, Robert K., Adams, John H., Hosey, Edward O., Canterberry, J B
• Primary Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US10/347,938
• Publication Number:
  US 20030127167A1
• Time in Patent Office: 832 Days
• Field of Search: 149/109.6, 149/47, 149/48, 264/34
• US Class Current: 149/109.6
• CPC Class Codes: C06B 21/0066 by granulation, e.g. flaking
• CPC Class Codes: C06B 25/34 the compound being a nitrated acyclic, alicyclic or heterocyclic amine
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A non azide gas generant composition of nitroguanidine and an oxidizer such as phase stabilized ammonium nitrate is provided. A gas generant having nitroguanidine and phase stabilized ammonium nitrate has many desirable characteristics such as little production of ash and the production of essentially toxic free exhaust gas. When nitroguanidine is compressed into a pellet it has needle shaped crystals that bend or distort. When the gas generant pellets are subjected to thermal cycling some nitroguanidine crystals will return to their native conformation resulting in pellet growth. To eliminate this pellet growth, nitroguanidine is passed through a vibrating ball mill. The media in the vibrating ball mill pulverizes the nitroguanidine into an amorphous crumb.

Claims

1. A process for preparing an azide-free gas generant composition that produces gases on combustion for inflating a vehicle restraint device, said composition comprising an oxidizer and nitroguanidine, said process comprising the steps of

a. grinding the nitroguanidine to pulverize and convert the nitroguanidine from a crystalline needle structure into an amorphous crumb having insufficient structure to move appreciably during thermal cycling, and

b. mixing the nitroguanidine with the oxidizer.

2. The process of claim 1, wherein the gas generant comprises about 32-50% by weight of nitroguanidine.

3. The process of claim 1, wherein the gas generant composition further comprises less than 2% by weight of silica and less than 2% by weight of boron nitride.

4. The process of claim 1, wherein the nitroguanidine is pulverized and converted into an amorphous crumb by being passed through a vibrating ball mill.

5. The process of claim 4, wherein the vibrating ball mill is preloaded with an alumina media that pulverizes the nitroguanidine.

6. The process of claim 4, wherein the nitroguanidine is passed through the vibrating ball mill twice.

12. The process of claim 4, wherein after one pass through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb to a state wherein the crystalline needles are broken and fractured.

13. The process of claim 4, wherein after one pass through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb structure as shown in FIG. 5, which is a pictorial representation under 400×

magnification.

14. The process of claim 6, wherein after two passes through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb wherein the crystalline needles have no discernable length, the crumb being a pulp or powder structure.

15. The process of claim 6, wherein after two passes through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb structure as shown in FIG. 6, which is a pictorial representation under 400×

magnification.

7. A process for preparing an azide-free gas generant composition that produces exhaust gases on combustion for inflating a vehicle restraint device, said process comprising the steps of

a. grinding nitroguanidine to convert the nitroguanidine from a crystalline needle structure into an amorphous crumb having insufficient structure to move appreciably during thermal cycling, and

b. mixing the nitroguanidine with an oxidizer.

8. The process of claim 7, wherein the nitroguanidine is pulverized and converted into an amorphous crumb by being passed through a vibrating ball mill.

9. The process of claim 8, wherein the vibrating ball mill is preloaded with an alumina media that pulverizes the nitroguanidine.

10. The process of claim 9, wherein the nitroguanidine is passed through the vibrating ball mill twice.

16. The process of claim 8, wherein after one pass through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb wherein the crystalline needles are broken and fractured.

17. The process of claim 8, wherein after one pass through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb as shown in FIG. 5, which is a pictorial representation under 400×

magnification.

18. The process of claim 10, wherein after two passes through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb wherein the crystalline needles have no discernable length, the crumb being of a pulp or powder structure.

19. The process of claim 10, wherein after two passes through the mill the crystalline needle structure of the nitroguanidine is pulverized and converted into an amorphous crumb as shown in FIG. 6, which is a pictorial representation under 400×

magnification.

11. A process for preparing an azide-free gas generant composition that produces exhaust gases on combustion for inflating a vehicle restraint device, said process comprising the steps of

a. grinding nitroguanidine by using a mill, wherein the mill converts the structure from a crystalline needle structure to an amorphous crumb, and

b. mixing the nitroguanidine with an oxidizer.