Hollow fiber microfiltration membranes and a method of making these membranes

• US 6,890,435 B2
• Filed: 01/28/2002
• Issued: 05/10/2005
• Est. Priority Date: 01/28/2002
• Status: Expired due to Fees

• Current Assignee: Koch Membrane Systems, Inc. (KOCH Industries Incorporated)
• Original Assignee: Koch Membrane Systems, Inc. (KOCH Industries Incorporated)
• Inventors: Koch, David H, McKinley, David, Ji, Jiang, Stead, David, Schulz, Edward M., DiCecca, Candeloro, Mehta, Mahesh
• Primary Examiner(s): Fortuna, Ana
• Application Number:
  US10/058,983
• Publication Number:
  US 20030141251A1
• Time in Patent Office: 1,198 Days
• Field of Search: 210/500.23, 210/500.29, 210/500.36, 210/500.41, 210/500.28, 210/500.38, 210/500.37, 210/500.39, 210/500.27, 264/41
• US Class Current: 210/500.23
• CPC Class Codes: B01D 2323/06 Specific viscosities of materials involved
• CPC Class Codes: B01D 2323/12 Specific ratios of components used
• CPC Class Codes: B01D 67/0011 Casting solutions therefor
• CPC Class Codes: B01D 67/0016 Coagulation
• CPC Class Codes: B01D 67/00165 Composition of the coagulation baths
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: B01D 71/68 Polysulfones; Polyethersulfones
• CPC Class Codes: D01D 5/24 with a hollow structure; Spinnerette packs therefor D01D5/38 takes precedence; producing tubes of plastic material B29D; addition of agents forming hollow filaments D01F1/08

Abstract

A hollow fiber microfiltration (MF) membrane is provided. The casting solution used to make this membrane includes a fiber-forming polymer having a degree of polymerization greater than about 1000, a water-soluble polymer, an anhydride with about 2 to 12 carbon atoms, and a solvent. The membrane is formed by mixing and heating these components to form a viscous dope and then extruding the dope through an annular orifice to form a hollow fiber MF membrane. The hollow fiber membrane is then fed through a coagulation bath and two leaching baths. The membrane is especially useful for filtering liquids, such as wine and juice, so as to remove bacteria, gel, and solid particles from the liquids.

Claims

1. A hollow fiber microfiltration membrane, said membrane being prepared from a mixture comprising:

about 12-30% by weight polysulfone polyethersulfone, polyvinyledene fluoride or mixtures thereof;

about 8-25% by weight polyvinylpyrrolidone;

about 8-25% by weight maleic anhydride; and

an aprotic solvent, wherein said mixture is extruded through an annular orifice using a bore fluid comprised of N-methyl pyrrolidone, polyethylene glycol, and isopropylnol and then fed through a gelation bath comprised of water and N-methyl pyrrolidone to form said hollow fiber microfiltration membrane wherein said membrane has a narrow quasi Gaussian pore size distribution of about 0 to 0.3 μ

m and an average pore size of about 0.15 to 0.3μ

m.

2. The membrane of claim 1, wherein said membrane has a tensile strength of at least about 400 psi.

3. The membrane of claim 1, wherein said membrane has a water flux of about 100 to 6000 gfd at about 20 psi transmembrane pressure.

4. The membrane of claim 1, wherein said polysulfone has a weight average molecular weight of about 100,000 to 1,000,000 g/mol.

5. The membrane of claim 1, wherein said mixture has a viscosity of about 10,000 to 100,000 centipoise at about 25°

C.

6. The membrane of claim 1, wherein said solvent is selected from the group consisting of dimethylacetamide, N-methyl-pyrrolidone (NMP), dimethyl formamide, dimethylsulfone, trialkylphosphate, and combinations thereof.

7. The membrane of claim 1, wherein said solvent is about 40 to 75% by weight of said mixture extruded to form said membrane.

8. The membrane of claim 1, wherein said hollow fiber membrane has an outside diameter of about 10 mil to 350 mil.

9. The membrane of claim 1, wherein said hollow fiber membrane has an inside diameter of about 1 mil to 300 mil.

10. The membrane of claim 1, wherein said membrane is about 1 to 50 mil thick.