Silicone-polyester-polysilicate hybrid compositions for thermal resistance coating

• US 6,893,724 B2
• Filed: 03/11/2003
• Issued: 05/17/2005
• Est. Priority Date: 03/11/2003
• Status: Active Grant

• Current Assignee: Grand Tek Advance Material Science Co., Ltd.
• Original Assignee: Grand Tek Advance Material Science Co., Ltd.
• Inventors: Lin, Hsueh-Tso, Chen, Kuan-Ching
• Primary Examiner(s): Feely, Michael J.
• Application Number:
  US10/384,656
• Publication Number:
  US 20040180221A1
• Time in Patent Office: 798 Days
• Field of Search: 428/429, 428/447, 428/450, 525/474, 525/477, 528/33, 528/34, 528/39
• US Class Current: 428/429
• CPC Class Codes: C03C 17/006 with materials of composite character
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 2217/40 Coatings comprising at least one inhomogeneous layer
• CPC Class Codes: C08G 77/445 containing polyester sequences
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/02 Polysilicates
• CPC Class Codes: C08L 83/10 Block- or graft-copolymers containing polysiloxane sequences obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00
• CPC Class Codes: C09D 183/10 Block or graft copolymers containing polysiloxane sequences obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C09D151/08, C09D153/00
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

The present invention employs alkyl polysilicate to form silicone-polyester-polysilicate hybrid compositions with an appropriate proportion to modify silicone-polyester resin, or directly adds the alkyl polysilicate at an appropriate proportion into silicone-polyester resin to produce a hybrid composition. The composition in high baking temperature forms a hybrid structure having good thermal resistance, especially, hot-oil resistance and hot hardness, and good adhesion to metals such as carbon steel, stainless steel and aluminum. The present invention can be used in the field of the protective coating for heat-resistant metal such as frying pans and electric irons to be a kind of novel heat-resistant composition having hybrid structure. The composition in accordance with the present invention comprises (A)silicone-polyester; (B)alkyl polysilicate and the structure thereof comprises (RO)₃—Si—O—(Si(OR)₂—O)_n—R, where n=0˜20 and R represents —CH₃, —C₂H₅, —C₃H₇, or —C₄H₉. The composition mentioned above comprises the compounds of (A) and (B) or the copolymer comprised by (A) and (B).

Claims

1. A heat-resistant material, said material being a kind of silicone-polyester-polysilicate composition consisting essentially of:

1) silicone-polyester

2) alkyl polysilicate

wherein said material is formed by a combination method of bonding said silicone-polyester and said alkyl polysilicate, and a solid weight ratio of said alkyl polysilicate to said silicone-polyester is about 3;

100 to 15;

100;

wherein said silicone-polyester comprises a silicone resin and a polyester, wherein a combination percentage of said silicone resin is higher than said polyester, and said silicone-polyester has OH functional group which can react with said alkyl polysilicate; and

said alkyl polysilicate is

(RO)₃—

Si—

O—

[Si(OR)₂—

O]_n—

R,

wherein n represents a numeric and about less than 20 and R represents an alkyl functional group.

2. The material according to claim 1, wherein said silicone resin is from 50% to 80% by weight of said silicone-polyester, said polyester is from 50% 20% by weight of said silicone-polyester and said alkyl functional group of said alkyl polysilicate comprises —

CH₃, —

C₂H₅, —

C₃H₇, or —

C₄H₉.

3. The material according to claim 2, wherein said combination method comprises a step for copolymerizing said silicon-polyester and said alkyl polysilicate.

4. The material according to claim 2, wherein said combination method comprises a step for polymerizing said silicone and said polyester, and then adding said alkyl polysilicate for a blending reaction.

5. The material according to claim 1, wherein a coating formed from said heat-resistant material withstands 80 circulations of a 260°

C. hot-oil resistant test.

6. A heat-resistant material utilized as a substrate coating, said material being a kind of silicone-polyester-polysilicate composition consisting essentially of:

1) silicone-polyester

2) alkyl polysilicate

wherein said material is formed by a combination method of bonding said silicone-polyester and said alkyl polysilicate, and a solid weight ratio of said alkyl polysilicate to said silicone-polyester is about 3;

100 to 15;

100;

wherein said silicone-polyester comprises a silicone resin and a polyester, wherein a combination percentage of said silicone resin is higher than said polyester, and said silicone-polyester has OH functional group which can react with said alkyl polysilicate; and

said alkyl polysilicate is

(RO)₃—

Si—

O—

[Si(OR)₂—

O]_n—

R

wherein n represents a numeric and about less than 20 and R represents an alkyl functional group.

7. The material according to claim 6, wherein said substrate comprises metal or glass.

8. The material according to claim 7, wherein said silicone resin is from 50% to 80% by weight of said silicone-polyester, said polyester is from 50% m 20% by weight of said silicone-polyester, and said alkyl functional group of said alkyl polysilicate comprises —

CH₃, —

C₂H₅, —

C₃H₇, or —

C₄H₉.

9. The material according to claim 7, wherein said combination method comprises a step for copolymerizing said silicon-polyester and said alkyl polysilicate.

10. The material according to claim 7, wherein said combination method comprises a step for polymerizing said silicone and said polyester, and then adding said alkyl polysilicate for a blending reaction.

11. The material according to claim 6, wherein the substrate coating formed from said heat-resistant material withstands 80 circulations of a 260°

C. hot-oil resistant test.