Process for producing alkaline treated cellulosic fibers

• US 6,896,810 B2
• Filed: 08/02/2002
• Issued: 05/24/2005
• Est. Priority Date: 08/02/2002
• Status: Active Grant

• Current Assignee: Rayonier Performance Fibers, LLC (Rayonier Advanced Materials, Inc.)
• Original Assignee: Rayonier Products and Financial Services Company
• Inventors: Taylor, Jay D., Cenicola, John T., Li, Jian, Ali, Omar F.
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US10/211,043
• Publication Number:
  US 20040020854A1
• Time in Patent Office: 1,026 Days
• Field of Search: 210/652, 210/651, 210/195.2, 812/5, 536/56, 536/60, 162/1, 162/14, 162/29, 162/60
• US Class Current: 210/652
• CPC Class Codes: C08B 1/00 Preparatory treatment of cellulose for making derivatives thereof , e.g. pre-treatment, pre-soaking, activation
• CPC Class Codes: C08B 1/08 Alkali cellulose
• CPC Class Codes: C08B 1/10 Apparatus for the preparation of alkali cellulose
• CPC Class Codes: C08B 1/12 Steeping devices
• CPC Class Codes: D21C 9/004 inorganic compounds

Abstract

Systems and methods by which to subject cellulosic fibers to alkaline treatment are provided. The systems and methods of the invention include equipment, such as nanofiltration units and slurry concentrators, which result in a lowered overall consumption of alkaline solution during alkaline treatment. The systems and methods of the invention further allow the components of hemicaustic streams produced by such alkaline treatments to be utilized in higher value end uses.

Claims

1. An alkaline treatment system comprising:

a cellulose slurry supply system for providing cellulosic fiber containing hemicellulose to said alkaline treatment system;

a steeping liquor supply system for providing an effective amount of a steeping liquor comprising an alkaline solution to said alkaline treatment system;

a mixing system for combining the cellulosic fiber and the steeping liquor into an alkaline cellulose slurry;

at least one alkaline treatment unit for steeping the alkaline cellulose slurry for a sufficient amount of time to diffuse an effective amount of the hemicellulose out of the cellulosic fibers and into the steeping liquor;

at least one treated cellulose washer to separate the spent steeping liquor containing the diffused hemicellulose from the treated cellulosic fibers; and

a nanofiltration system comprising at least one nanofiltration unit to remove at least a portion of the hemicellulose from the spent steeping liquor.

2. An alkaline treatment system according to claim 1, wherein said nanofiltration unit includes at least one nanofiltration membrane capable of excluding compounds having a molecular weight of about 200 and higher.

3. An alkaline treatment system according to claim 1, wherein said nanofiltration system comprises a plurality of nanofiltration units.

4. An alkaline treatment system according to claim 1, wherein said nanofiltration unit includes at least one polymeric nanofiltration membrane.

5. An alkaline treatment system according to claim 4, wherein said polymeric nanofiltration membrane is formed from a polymer selected from the group consisting of polyether sulfone, polysulfone, polyarylether sulfones, polyvinylidene fluoride, polyvinyl chloride, polyketones, polyether ketones, polytetrafluoro ethylene, polypropylene, polyamides and mixtures thereof.

6. In alkaline treatment system according to claim 1, wherein said nanofiltration system further comprises one or more pre-filtration units having a screen size ranging from about 400 to 650 mesh.

7. An alkaline treatment system according to claim 1, wherein said nanofiltration system further comprises one or more pre-filtration units selected from bag filters, ribbon filters and self-cleaning filters.

8. An alkaline treatment system according to claim 1, wherein said nanofiltration system further comprises an evaporation system.

9. An alkaline treatment system according to claim 1, wherein said at least one washer is selected from a group consisting of a horizontal belt washer, rotary drum washer, vacuum filter, wash press, compaction baffle washer, atmospheric diffuser and pressure diffuser.

10. An alkaline treatment system according to claim 1, wherein said cellulose slurry supply system further comprises at least one press to increase the consistency of the cellulose slurry selected from a group consisting of a twin roll press and a screw press.

11. An alkaline treatment system according to claim 1, wherein the consistency of the cellulose slurry supplied to the alkaline treatment unit is up to 50%.

12. An alkaline treatment system according to claim 1, wherein said cellulosic fibers are derived from a source selected from the group consisting of wood, cotton, straws, grasses, canes, reeds, bamboos, stalks with bast fibers, leaf fibers and mixtures thereof.

13. An alkaline treatment system according to claim 1, wherein said cellulosic fibers are derived from wood pulp.

14. An alkaline treatment system according to claim 1, wherein said wood pulp is selected from softwood pulp, hardwood pulp and mixtures thereof.

15. An alkaline treatment system according to claim 1, wherein said cellulosic fibers have a hemicellulose content up to 30%.

16. An alkaline treatment system according to claim 1, wherein said cellulosic fibers exhibit a brightness above 45%.

17. An alkaline treatment system according to claim 1, wherein said steeping liquor comprises at least one caustic compound in an amount up to 50 wt %.

18. An alkaline treatment system according to claim 1, wherein said steeping liquor consists essentially of recycled alkaline solution.

19. An alkaline treatment system according to claim 1, wherein said steeping liquor supply system further comprises at least one chiller.

20. An alkaline treatment system according to claim 1, wherein said mixing system comprises one or more mixers selected from a screw conveyor, a rotor/stator mixer, and a hydraulic piston mixer.

21. An alkaline treatment system according to claim 1, wherein said mixing system comprises a screw conveyor in series with either a rotor/stator or hydraulic piston mixer.

22. An alkaline treatment method comprising:

providing cellulosic fibers containing hemicellulose to an alkaline treatment system that includes a mixing system, at least one alkaline treatment unit, at least one treated cellulose washer and a nanofiltration system;

providing a steeping liquor comprising an alkaline solution to the alkaline treatment system;

combining the cellulosic fibers and the steeping liquor into an alkaline cellulose slurry within the mixing system;

steeping the alkaline cellulose slurry for a sufficient amount of time to diffuse an effective amount of the hemicellulose out of the cellulosic fibers and into the steeping liquor within the alkaline treatment unit;

washing the treated cellulose slurry in the treated cellulose washer to remove the spent steeping liquor containing the diffused hemicellulose from the treated cellulosic fibers;

passing the spent steeping liquor through a nanofiltration system comprising at least one nanofiltration unit to remove at least a portion of the hemicellulose from the spent steeping liquor.

23. An alkaline treatment method according to claim 22, wherein said step of providing cellulosic fibers further comprises providing cellulosic fibers having a brightness ranging above 45% and hemicellulose content up to 30%.

24. An alkaline treatment method according to claim 22, wherein said step of providing cellulosic fibers further comprises providing a cellulose slurry having a consistency up to 20%.

25. An alkaline treatment method according to claim 22, wherein said step of providing a steeping liquor further comprises providing a steeping liquor at a temperature ranging from about 20 to 90°

C.

26. An alkaline treatment method according to claim 22, wherein said step of providing a steeping liquor further comprises providing a steeping liquor containing up to 50 wt % caustic.

27. An alkaline treatment method according to claim 22, wherein said step of combining the cellulosic fibers and the steeping liquor further comprises passing the cellulosic fibers and steeping liquor through a screw conveyor in fluid communication with either a rotor/stator or hydraulic piston mixer.

28. An alkaline treatment method according to claim 22, wherein said step of steeping the alkaline cellulose slurry for a sufficient amount of time comprises steeping the alkaline cellulose slurry for a time up to 4 hours.

29. An alkaline treatment method according to claim 22, wherein said step of steeping the alkaline cellulose slurry to diffuse an effective amount of the hemicellulose out of the cellulosic fibers comprises diffusing up to 100% of the hemicellulose out of the cellulosic fibers.

30. An alkaline treatment method according to claim 22, wherein said step of washing the treated cellulose slurry further comprises passing the cellulose slurry through a horizontal belt washer.

31. An alkaline treatment method according to claim 22, wherein said step of passing the spent steeping liquor through a nanofiltration system further comprises passing the spent steeping liquor through a plurality of nanofiltration units.

32. An alkaline treatment method according to claim 22, wherein said step of passing the spent steeping liquor through a nanofiltration system further comprises passing the spent steeping liquor through at least one pre-filtration unit having a mesh size of 400 or greater prior to passing the spent steeping liquor through the nanofiltration unit.

33. An alkaline treatment method according to claim 22, wherein said step of passing the spent steeping liquor through a nanofiltration system comprising at least one nanofiltration unit to remove at least a portion of the hemicellulose from the spent steeping liquor comprises removing up to 100% of the hemicellulose present within the spent steeping liquor.