Stable aqueous surfactant compositions

• US 6,897,253 B2
• Filed: 06/23/2003
• Issued: 05/24/2005
• Est. Priority Date: 04/11/2000
• Status: Expired due to Term

• Current Assignee: Lubrizol Advanced Materials Incorporated (Berkshire Hathaway Incorporated)
• Original Assignee: Noveon IP Holdings Corp. (Berkshire Hathaway Incorporated)
• Inventors: Snyder, Marcia, Schmucker-Castner, Julie F., Kotian, Sahira, Weaver, Ashley A., Ambuter, Hal
• Primary Examiner(s): Lipman, Bernard
• Application Number:
  US10/602,956
• Publication Number:
  US 20040087668A1
• Time in Patent Office: 701 Days
• Field of Search: 524/291, 524/321, 524/401, 524/548, 524/555, 524/559
• US Class Current: 524/291
• CPC Class Codes: A61K 2800/436 Interference pigments, e.g. Iridescent, Pearlescent
• CPC Class Codes: A61K 8/365 Hydroxycarboxylic acids; Ketocarboxylic acids
• CPC Class Codes: A61K 8/368 with carboxyl groups directly bound to carbon atoms of aromatic rings
• CPC Class Codes: A61K 8/4933 having sulfur as an exocyclic substituent, e.g. pyridinethione
• CPC Class Codes: A61K 8/8152 Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/86 Polyethers
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/892 modified by a hydroxy group, e.g. dimethiconol
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/006 Antidandruff preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/065 Preparations for temporary colouring the hair, e.g. direct dyes
• CPC Class Codes: A61Q 5/10 Preparations for permanently dyeing the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners
• CPC Class Codes: C11D 3/0089 Pearlescent compositions; Opacifying agents
• CPC Class Codes: C11D 3/3765 in liquid compositions

Abstract

A stable, aqueous composition containing a substantially crosslinked alkali-swellable acrylate copolymer rheology modifier, a surfactant, an alkaline material, and various compounds therein, as for example substantially insoluble materials requiring suspension or stabilization, such as a silicone, an oily material, or a pearlescent material. Additionally, this invention also relates to the formation of a rheologically and phase stable cationic hair dye composition. The invention further relates to the incorporation of an acidic material after the addition of an alkaline material to reduce the pH of the composition without negatively impacting the viscosity of the composition.

Claims

1. A stable, aqueous surfactant containing composition, comprising:

a. at least one anionic, zwitterionic, amphoteric, nonionic, or cationic surfactant, or combinations thereof;

b. at least one substantially crosslinked alkali-swellable acrylate copolymer rheology modifier;

c. water;

d. an effective amount of at least one alkaline material to yield a composition having a pH of from about 5 to about 14; and

e. an effective amount of a subsequently added acidic material to yield a composition having a reduced pH of from about 1 to about 12;

wherein said at least one crosslinked alkali-swellable acrylate copolymer comprises;

f. about 20% to about 80% by weight of at least one carboxylic acid monomer comprising acrylic acid, methacrylic acid, itaconic acid, fumaric acid, crotonic acid, aconitic acid, or maleic acid, or combinations thereof;

g. about 80% to about 15% by weight of at least one α

,β

-ethylenically unsaturated monomer, wherein said monomer has the formula;

CH₂═

CXY, 

 

i)

where X is H and Y is —

COOR, —

C₆H₄R′

, —

CN, —

CONH₂, —

Cl, —

NC₄H₆O, NH(CH₂)₃COOH, —

NHCOCH₃, —

CONHC(CH₃)₃, —

CO—

N(CH₃)₂,

or X is CH₃ and Y is —

COOR, —

C₆H₄R′

, —

CN;

or —

CH═

CH₂;

or X is Cl and Y is Cl, and R is C₁-C₁₈ alkyl, or hydroxy C₂-C₁₈ alkyl,

R′

is H or C₁-C₁₈ alkyl,

or having the formula;

CH₂═

CH (OCOR¹);

 

 

ii)

where R¹ is C₁-C₁₈ alkyl;

or having the formula;

CH₂═

CH₂ or CH₂═

CHCH₃;

 

 

iii)

h. from about 0.01 to about 5% by weight of at least one polyunsaturated compound useful in forming a partially or substantially crosslinked three dimensional network; and

i. at least one substantially insoluble material requiring suspension or stabilization.

2. A composition according to claim 1, wherein said substantially insoluble material includes pumice;

calcium carbonate;

talc;

potato starch;

tapioca starch;

jojoba beads;

polyethylene beads;

walnut shells;

loofah;

apricot seeds;

almond meal;

corn meal;

paraffin;

oat bran/oat hulls;

gelatin beads;

alginate beads;

stainless steel fibers;

iron oxide pigments;

air bubbles;

mica coated iron oxides;

kaolin clay;

zinc pyrithione;

salicylic acid;

zinc oxide;

zeolite;

styrofoam beads;

phosphates;

silica, and the like, teatree powder, microsponges, Confetti®

, talc, beeswax, and combinations thereof.

3. A composition according to claim 1, wherein the amount of the said copolymer is from about 0.1% to about 10% by weight based upon the total weight of said stable composition, and wherein the amount of said surfactant is from about 1% to about 80% by weight based upon the total weight of said stable composition.

4. A composition according to claim 3, wherein said acidic material is citric acid, acetic acid, beta-hydroxy acid, salicylic acid, alpha-hydroxy acid, lactic acid, glycolic acid, hydrochloric acid, sulfuric acid, nitric acid, sulfamiic acid, phosphoric acid, or natural fruit acids, or combinations thereof.

5. A composition according to claim 4, wherein the said copolymer is derived from:

a. about 35% to about 65% by weight of acrylic acid or methacrylic acid, or combinations thereof,

b. about 65% to about 35% by weight of ethylacrylate, or methylacrylate, or combinations thereof, and

c. about 0.03% to about 3% by weight of polyalkenyl ethers of sucrose or polyalcohols;

or trimethylolpropane tri(meth)acrylate, glycidyl methacrylate, N-methylolacrylamide, or combinations thereof.

6. A composition according to claim 1, wherein said substantially insoluble material is a “

biologically active”

material having pharmaceutical, veterinary, biocidal, herbicidal, pesticidal, or other biological activity.

7. A composition according to claim 1, wherein said substantially insoluble material is a silicone, or an oily material, or a pearlescent material, or combinations thereof.

8. A composition according to claim 7, wherein said insoluble silicone is polydimethylsiloxane, amodimethicone, amodimethicone macroemulsion or microemulsion, dimethicone, dimethiconol (silicone gum), cyclomethicone, phenyltrimethicone, a dimethicone or dimethiconol microemulsion or macroemulsion, an organo polysiloxane, alkoxysilicone, or any combination thereof, wherein the amount of said silicone is from about 0.1 to about 20% by weight based upon the total weight of said stable composition.

9. A composition according to claim 7, wherein said insoluble pearlescent material is titanium dioxide coated mica, iron oxide coated mica, ethylene glycol monostearate, ethylene glycol distearate, polyethylene glycol distearate, bismuth oxychioride coated mica, myristyl myristate, guanine (fish scales), or glitter (polyester or metallic), or combinations thereof, wherein the amount of said pearlescent material is from about 0.05% to about 10% by weight based upon the total weight of said stable composition.

10. A composition according to claim 8, wherein said composition is substantially free of a fatty acid, a fatty acid ester, a fatty alcohol, or combinations thereof.

11. A composition according to claim 5, wherein said composition is a personal care cleansing composition, wherein said acid is salicylic acid or alpha-hydroxy acid, and wherein the amount of said acid is from about 0.2 to about 6% by weight.

12. A composition according to claim 5, wherein said composition is a personal care emulsion composition, wherein said acid is an alpha-hydroxy acid or beta-hydroxy acid, and wherein the amount of said acid is from about 0.2% to about 15% by weight.

13. A composition according to claim 2, wherein said composition is an anti-dandruff shampoo, wherein said substantially insoluble material requiring suspension or stabilization is zinc pyrithione, and wherein the amount of said zinc pyrithione is from about 0.1% to 5% by weight.