Non-lithographic photo-induced patterning of polymers from liquid crystal solvents with spatially modulated director fields
First Claim
1. A method for fabricating a liquid crystal device having polymer micro-structures, the method comprising the steps of:
- preparing a mixture comprising a liquid crystal material and a prepolymer;
providing a first and second cell wall structure, said first and second cell wall structures optionally having electrodes disposed on facing sides of said first and second cell wall structures, and, optionally having an alignment layer disposed on at least one of said electrodes;
disposing said mixture into a space between the first and second cell wall structures;
causing said liquid crystal material to assume a predetermined orientation with a non-uniform spatially distorted director field; and
exposing said mixture to conditions which cause polymerization of the prepolymer and formation of polymer micro-structures between the cell walls, wherein the micro-structures have a shape and spatial location determined by a director field of said liquid crystal material.
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Abstract
A liquid crystal device comprises a first and second cell wall structure; at least one liquid crystal material disposed within a space between the first and second cell wall structures; and polymer micro-structures, wherein the micro-structures are formed by polymerizing a prepolymer, and wherein said micro-structures have a shape and spatial location determined by said liquid crystal material. Permanent polymer micro-structures are formed from a liquid crystal with a non-uniform spatially modulated director field. The polymer structures have the shape and spatial location dictated by the non-uniform director field of the liquid crystal. The micro-structures are a backbone that restores the liquid crystal director field that existed during the polymerization process even when other factors, such as electric field, temperature, or surface anchoring, do not favor this restoration. The polymer micro-structures can be used in optical devices, such as diffraction gratings and deflecting and beam steering devices, and in micro-mechanical and micro-fluidic devices.
38 Citations
13 Claims
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1. A method for fabricating a liquid crystal device having polymer micro-structures, the method comprising the steps of:
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preparing a mixture comprising a liquid crystal material and a prepolymer;
providing a first and second cell wall structure, said first and second cell wall structures optionally having electrodes disposed on facing sides of said first and second cell wall structures, and, optionally having an alignment layer disposed on at least one of said electrodes;
disposing said mixture into a space between the first and second cell wall structures;
causing said liquid crystal material to assume a predetermined orientation with a non-uniform spatially distorted director field; and
exposing said mixture to conditions which cause polymerization of the prepolymer and formation of polymer micro-structures between the cell walls, wherein the micro-structures have a shape and spatial location determined by a director field of said liquid crystal material. - View Dependent Claims (2, 3, 4, 5)
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6. A method for forming polymer micro-structures, the method comprising the steps of:
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preparing a mixture comprising a liquid crystal material and a prepolymer;
providing a first and second cell wall structure;
disposing said mixture into a space between the first and second cell wall structures;
causing said liquid crystal material to assume a predetermined orientation with a non-uniform spatially distorted director field; and
exposing said mixture to conditions which cause polymerization of the prepolymer and formation of polymer micro-structures between the cell walls, wherein the micro-structures have a shape and spatial location determined by a director field of said liquid crystal material. - View Dependent Claims (7, 8, 9, 10, 11, 12, 13)
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Specification