Water filtration using immersed membranes

• US 6,899,812 B2
• Filed: 03/18/2002
• Issued: 05/31/2005
• Est. Priority Date: 11/23/1998
• Status: Expired due to Term

• Current Assignee: Zenon Technology Partnership
• Original Assignee: Zenon Environmental Incorporated
• Inventors: Janson, Arnold, Singh, Manwinder, Cote, Pierre, Adams, Nicholas, Husain, Hadi
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US10/098,365
• Publication Number:
  US 20020130080A1
• Time in Patent Office: 1,170 Days
• Field of Search: 210/321.8, 210/636, 210/650, 210/321.88
• US Class Current: 210/636
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/10 Temperature control
• CPC Class Codes: B01D 2311/14 Pressure control
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 2311/2661 Addition of gas
• CPC Class Codes: B01D 2315/06 Submerged-type; Immersion type
• CPC Class Codes: B01D 2321/04 Backflushing
• CPC Class Codes: B01D 2321/16 Use of chemical agents
• CPC Class Codes: B01D 2321/167 Use of scale inhibitors
• CPC Class Codes: B01D 2321/185 Aeration
• CPC Class Codes: B01D 2321/2066 Pulsated flow
• CPC Class Codes: B01D 2321/2083 By reversing the flow
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B01D 61/146 comprising multiple ultrafiltration steps
• CPC Class Codes: B01D 61/147 Microfiltration
• CPC Class Codes: B01D 61/149 Multistep processes comprising different kinds of membrane processes selected from ultrafiltration or microfiltration
• CPC Class Codes: B01D 61/16 Feed pretreatment
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 61/22 Controlling or regulating
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/031 : Two or more types of hollow fibres within one bundle or within one potting or tube-sheet
• CPC Class Codes: B01D 63/043 : with separate tube sheets
• CPC Class Codes: B01D 65/02 : Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 : Prevention of membrane fouling or of concentration polarisation
• CPC Class Codes: C02F 1/444 : by ultrafiltration or microfiltration
• CPC Class Codes: C02F 3/1273 : Submerged membrane bioreactors
• CPC Class Codes: Y02W 10/10 : Biological treatment of water, waste water, or sewage

Abstract

A process for operating filtering membranes submerged in a tank involves, in one aspect, periodically deconcentrating the tank by at least partially emptying and refilling the tank with fresh water while permeation continues. In another aspect, long trains of membranes modules are placed in series along a flow path in the tank. In one embodiment, constant aeration is provided to prevent tank water from by-passing the membrane modules while proving controlled mixing such that the average concentration of solids in the tank is lower than the concentration of solids in the tank near an outlet for removing retentate from the tank. In another embodiment, the membrane modules are arranged in a series of filtration zones between a feed water inlet and a retentate outlet of a tank. Permeate is withdrawn from the filtration zones by separate means associated with each filtration zone. Tank water containing rejected solids flows in a tank flow through the filtration zones, increasing in concentration from one zone to the next. A preferred membrane module has membranes transverse to the tank flow and fills a substantial portion of each filtration zone. With either embodiment, aeration, backwashing or packing density of membranes varies between filtration zones and the flow pattern in the tank may be periodically reversed.

Claims

1. A process for treating water containing solids to produce a permeate lean in solids comprising:

(a) providing a filter for treating water containing solids to produce a permeate lean in solids comprising;

(i) an open tank defining a generally horizontal flow path between an inlet to supply a feed water containing solids into the tank and an outlet for water rich in solids to leave the tank;

(ii) six or more membrane modules of filtering membranes placed in the tank spaced horizontally consecutively along the flow path, such that

(A) any distance between adjacent membrane modules along the flow path is less than one half of the length of a membrane module measured along the flow path.

(B) the total length of all of the membrane modules measured along the flow path excluding any distance between them along the flow path is at least twice the width of the membrane modules measured perpendicular to the flow path and

(C) the distance from the membrane modules to the walls of the tank measured perpendicular to the flow path is greater than any distance along the flow path between adjacent membrane modules;

(iii) permeate collectors for connecting a permeate side of the filtering membranes to a source of negative pressure; and

,

(iv) agitators below the modules operable when the tank is filled with water containing solids to entrain water containing solids around the membrane modules and flow the water containing solids upwards through the modules substantially throughout permeation;

(b) introducing a feed water containing an initial concentration of solids into the tank through the inlet to immerse the membranes in water containing solids;

(c) producing a filtered permeate with a reduced concentration of solids on a permeate side of the membranes by applying a negative pressure to the permeate collectors;

(d) removing the permeate produced on the permeate side of the membranes from the tank;

(e) withdrawing a retentate having an increased concentration of solids compared to the initial concentration of solids from the tank through the outlet substantially continuously while producing the filtered permeate;

(f) introducing feed water into the tank to replace water removed from the tank to keep the membranes immersed in water during the step of producing the filtered permeate; and

,

(g) operating the agitators to create a localized flow of tank water about each module substantially throughout permeation in which water in the tank flows upwards through the membrane module then downwards and towards the outlet in a space beside the membrane module.

2. The process of claim 1 wherein the agitators are aerators and the aerators are operated to produce more aeration towards the outlet of the tank.

3. The process of claim 1 further comprising backwashing the membrane modules from time to time, the amount of backwashing being biased towards the outlet of the tank.

4. A process for filtering water comprising,

(a) introducing a feed water containing an initial concentration of solids into an open tank to immerse one or more filtering membranes located in the open tank, the feed water contacting a first side of the membranes;

and

(b) in repeated cycles,

(i) applying suction on a second side of the membranes to withdraw a filtered permeate while adding sufficient feed water to keep the membranes submerged and permitting the concentration of solids in the tank water to rise to an increased concentration; and

,

(ii) rapidly flushing the tank while continuing to withdraw filtered permeate by (A) withdrawing a retentate from the tank and (B) adding feed water to keep the membranes submerged, until the concentration of solids in the tank is less than 40% of the increased concentration.

5. The process of claim 4 wherein the concentration of solids in the tank at the end of the steps (b)(ii) is less than 20% of the increased concentration.

6. The process of claim 4 wherein the duration of the repeated cycles is at least about 2 hours and the duration of steps b(ii) is less than about 25 minutes.

7. The process of claim 6 wherein the membranes are aerated at least during steps b(i) and the aeration is biased towards a later part of the steps b(i).

8. The process of claim 6 wherein the duration of steps b(ii) is selected to produce a desired amount of permeate, the desired amount of permeate being at least 90% of the amount of feed water entering the tank.

9. The process of claim 6 wherein the membranes are backwashed from time to time at least during the steps b(i) and the frequency or duration of the backwashing is biased towards a later part of the steps b(i).