Highly efficient OLEDs using doped ambipolar conductive molecular organic thin films

• US 6,900,588 B2
• Filed: 05/30/2003
• Issued: 05/31/2005
• Est. Priority Date: 12/18/2000
• Status: Expired due to Term

• Current Assignee: The Trustees of Princeton University (Princeton University)
• Original Assignee: The Trustees of Princeton University (Princeton University)
• Inventors: Baldo, Marc A., Forrest, Stephen R., Adachi, Chihaya
• Primary Examiner(s): Vo, Tuyet Thi
• Application Number:
  US10/452,659
• Publication Number:
  US 20030197467A1
• Time in Patent Office: 732 Days
• Field of Search: 313/504, 313/506, 313/502, 313/503, 428/690, 428/691, 428/917, 257/40, 257/89, 257/87, 315/169.1, 315/169.3
• US Class Current: 313/504
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/14 Carrier transporting layers
• CPC Class Codes: H10K 50/17 Carrier injection layers
• CPC Class Codes: H10K 85/341 Transition metal complexes, e.g. Ru(II)polypyridine complexes H10K85/331 takes precedence
• CPC Class Codes: H10K 85/60 Organic compounds having low molecular weight H10K85/10 - H10K85/50 take precedence
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

The present invention is directed to simplified OLED structures comprising an anode layer, a hole injecting layer (HIL) in direct contact with the anode layer, an emissive organic electron transporting layer (ETL) in direct contact with the hole injecting layer, and a cathode layer in direct contact with the emissive organic electron transporting layer. The hole injecting material used in the hole injecting layer is characterized, in particular, as being an organic material having an ionization potential that is not more than about 0.7 eV greater than the ionization potential of the material used for the anode layer. The emissive organic electron transporting layer comprises an organic electron transporting material and an organic hole-trapping emissive material, for example, an organic phosphorescent material that produces emission from a triplet excited state of an organic molecule.

Claims

1. An organic light emitting device including:

an anode layer in direct contact with an organic hole injecting layer, wherein the anode layer comprises an anode material having a characteristic ionization potential, and the organic hole injecting layer comprises an organic hole injecting material having a characteristic ionization potential; and

an electron transporting layer in direct contact with the hole injecting layer, wherein the electron transporting layer comprises an organic electron transporting material and an organic hole-trapping emissive material having a characteristic ionization potential;

wherein the characteristic ionization potential of the organic hole injecting material is not more than about 0.7 eV greater than the characteristic ionization potential of the anode material, and wherein the characteristic ionization potential of the organic hole-trapping emissive material is approximately equal to or greater than the characteristic ionization potential of the organic hole injecting material.

2. The organic light emitting device of claim 1, wherein the organic hole-trapping emissive material is a phosphorescent material.

3. The organic light emitting device of claim 2, wherein the characteristic ionization potential of the phosphorescent material is not more than about 0.7 eV greater than the characteristic ionization potential of the organic hole injecting material.

4. The organic light emitting device of claim 2, wherein the characteristic ionization potential of the phosphorescent material is not more than about 0.5 eV greater than the characteristic ionization potential of the organic hole injecting material.

5. The organic light emitting device of claim 2, wherein the characteristic ionization potential of the organic hole injecting material is not more than about 0.5 eV greater than the characteristic ionization potential of the anode material.

6. The organic light emitting device of claim 3, wherein the characteristic ionization potential of the organic hole injecting material is not more than about 0.5 eV greater than the characteristic ionization potential of the anode material.

7. The organic light emitting device of claim 4, wherein the characteristic ionization potential of the organic hole injecting material is not more than about 0.5 eV greater than the characteristic ionization potential of the anode material.

8. The organic light emitting device of claim 2, wherein the organic electron transporting material has a characteristic ionization potential, and the characteristic ionization potential of the phosphorescent material is at least about 0.5 eV less than the characteristic ionization potential of the organic electron transporting material.

9. The organic light emitting device of claim 8, wherein the characteristic ionization potential of the phosphorescent material is at least about 0.7 eV less than the characteristic ionization potential of the organic electron transporting material.

10. The organic light emitting device of claim 7, wherein the organic electron transporting material has a characteristic ionization potential, and the characteristic ionization potential of the phosphorescent material is at least about 0.5 eV less than the characteristic ionization potential of the organic electron transporting material.

11. The organic light emitting device of claim 10, wherein the characteristic ionization potential of the phosphorescent material is at least about 0.7 eV less than the characteristic ionization potential of the organic electron transporting material.

12. The organic light emitting device of claim 2, wherein the anode material comprises indium tin oxide, the organic hole injecting material comprises 4,4′

,4″

-tris(3-methylphenylphenylamino) triphenylamine, the organic electron transporting material comprises 4,4′

-N,N′

-dicarbazole-biphenyl, and the phosphorescent material comprises fac tris(2-phenylpyridine)iridium.

13. An organic light emitting device including:

an organic hole injecting layer in direct contact with an electron transporting layer;

wherein the organic hole injecting layer comprises an organic hole injecting material having a characteristic ionization potential, and the electron transporting layer comprises an organic electron transporting material and an organic hole-trapping emissive material having a characteristic ionization potential;

wherein the characteristic ionization potential of the organic hole-trapping emissive material is approximately equal to or greater than the characteristic ionization potential of the organic hole injecting material.

14. The organic light emitting device of claim 13, wherein the organic hole-trapping emissive material is a phosphorescent material.

15. The organic light emitting device of claim 14, wherein the characteristic ionization potential of the phosphorescent material is not more than about 0.7 eV greater than the characteristic ionization potential of the organic hole injecting material.

16. The organic light emitting device of claim 14, wherein the characteristic ionization potential of the phosphorescent material is not more than about 0.5 eV greater than the characteristic ionization potential of the organic hole injecting material.

17. The organic light emitting device of claim 16, wherein the organic electron transporting material has a characteristic ionization potential, and the characteristic ionization potential of the phosphorescent material is at least about 0.5 eV less than the characteristic ionization potential of the organic electron transporting material.

18. The organic light emitting device of claim 17, wherein the characteristic ionization potential of the phosphorescent material is at least about 0.7 eV less than the characteristic ionization potential of the organic electron transporting material.

19. The organic light emitting device of claim 14, wherein the phosphorescent material has a characteristic electron affinity and the organic electron transporting material has a characteristic electron affinity, wherein the characteristic electron affinity of the organic electron transporting material is equal to or greater than the characteristic electron affinity of the phosphorescent material.

20. The organic light emitting device of claim 14, wherein the organic hole injecting material comprises 4,4′

,4″

-tris(3-methylphenylphenylamino)triphenylamine, the organic electron transporting material comprises 4,4′

N,N′

-dicarbazole-biphenyl, and the phosphorescent material comprises fac tris(2-phenylpyridine)iridium.